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61.
《Physics and Chemistry of Liquids》2012,50(3):249-262
The apparent molal volumes (φ v ) of NaCl, NaNO3, NH4Cl, CuCl2, CuSO4, CoSO4 and MgSO4 in water and in water-SDS (Sodium dodecyl sulphate) solutions were determined from density measurements at 308.15, 313.15 and 323.15 K respectively. The limiting apparent molal volume at infinite dilution φ o v which is practically equal to the partial molal volume V o 2) of these electrolytes were found to be higher in water-SDS solution systems than those in water solutions. Viscosity coefficients (A and B) for these systems were also determined by Jones-Dole equation. All these electrolytes, except NH4Cl exhibit structure making behaviour in water and in water-SDS solutions. Ammonium chloride showed structure breaking properties in water and in 0.01 molar water-SDS solutions. In 0.1 molar SDS solution, it showed structure making behaviour at the temperature range studied. The properties of these electrolytes in water and in water-SDS solution systems have been discussed in terms of the charge, size and hydrogen bonding effect. 相似文献
62.
An integro-differential diffusion equation with linear force, based on the continuous time random walk model, is considered. The equation generalizes the ordinary and fractional diffusion equations, which includes short, intermediate and long-time memory effects described by the waiting time probability density function. Analytical expression for the correlation function is obtained and analyzed, which can be used to describe, for instance, internal motions of proteins. The result shows that the generalized diffusion equation has a broad application and it may be used to describe different kinds of systems. 相似文献
63.
64.
Zhi-Gang Feng 《Journal of Dispersion Science and Technology》2013,34(7):968-974
The hydrodynamics of a sphere with interface slip has been numerically investigated for flows of Reynolds number ranging 0 < Re ≤ 75. A simple correlation of the drag force coefficient in the present of interface slip has been derived based on our numerical simulations. The correlation takes the slip coefficient and Reynolds number as two input parameters. By comparing results found in the literature, we believe that the present correlation is more accurate; it provides a source for future experiment study and for numerical simulations of large multi-particle system where the interface slip is important. 相似文献
65.
66.
Coiled polymer actuators are a type of artificial muscles that are a promising development in the field of smart materials. The coefficient of thermal expansion of monofilament polyamide fibers is a crucial parameter for understanding the actuation of coiled fibers. The main purpose of this work is to develop a new methodology for estimating the coefficient of thermal expansion and the transition temperature of monofilament polymer fibers. In the experimental procedure, axial deformations of monofilament polyamide fiber samples were induced by temperature variations using a controlled thermal system. These deformations were determined from images of polyamide samples using the digital image correlation method. Two different approaches based on distinct temperature conditions were conducted. An alternative model with three parameters, including the coefficient of thermal expansion, was introduced to describe the thermal-mechanical behavior of monofilament polyamide fibers. Moreover, polyamide samples were also characterized using four conventional methodologies. Results indicated that the coefficient of thermal expansion changed of a modest negative value to a large negative value and this transition occurred around the glass transition temperature of the polyamide. The thermal expansion curves demonstrate good repeatability and all estimated parameters were in accordance with literature, indicating that the proposed approach can be suitable for the proposed study. This investigation may help in understanding of the intrinsic thermal-mechanical behavior of polymeric monofilaments employed as actuators. 相似文献
67.
《Physics and Chemistry of Liquids》2012,50(2):177-188
Two and three-body correlation entropies of model fluids, in which particles interact each other through the 4th, 6th, 9th and 12th-inverse-power potentials, were calculated from their atomic configurations obtained by molecular dynamics simulations at their freezing points. Besides the soft-core fluid model with the inverse-power potentials, hard-sphere and classical one-component plasma models were employed to provide a comparison with the entropies of the soft-core model. The correlation entropies were plotted as a function of the softness of the potential. These values were also compared with the excess entropies of the hard-sphere and the one-component plasma models at their freezing points. 相似文献
68.
Amogh Deshpande Srikanth K. Iyer 《Central European Journal of Operations Research》2009,17(2):219-228
We consider an enhancement of the credit risk+ model to incorporate correlations between sectors. We model the sector default rates as linear combinations of a common set
of independent variables that represent macro-economic variables or risk factors. We also derive the formula for exact VaR contributions at the obligor level. 相似文献
69.
The Atomic Force Microscopy (AFM) helps in evaluating parameters like amplitude or height parameters, functional or statistical parameters and spatial parameters which describe the surface topography or the roughness. In this paper, we have evaluated the roughness parameters for the native poly (vinyl alcohol) (PVA), monomer diaminonaphthalene (DAN) doped PVA, and poly (diaminonaphthalene) (PDAN) doped PVA films prepared in different solvents. In addition, distribution of heights, skewness and Kurtosis moments which describe surface asymmetry and flatness properties of a film were also determined. At the same time line profiles, 3D and 2D images of the surface structures at different scanning areas i.e. 5 × 5 μm2 and 10 × 10 μm2 were also investigated. From the roughness analysis and the surface skewness and coefficient of Kurtosis parameters, it was concluded that for PVA film the surface contains more peaks than valleys and the PDAN doped PVA film has more valleys than peaks. It was also found that the PDAN doped PVA film with acetonitrile solvent was used for substrate in electronics applications because the film gives less fractal morphology. Thus, the AFM analysis with different parameters suggested that the PDAN doped PVA films are smooth at the sub-nanometer scale. 相似文献
70.
V.I. Vasyuchka V.A. Moiseienko A.N. Slavin 《Journal of magnetism and magnetic materials》2009,321(20):3498-3501
A correlation receiver capable of receiving pulsed microwave signals having amplitudes substantially below the noise level is proposed and experimentally realized. The device is based on the parametric interaction of two contra-propagating spin waves excited by the received microwave signal and the reference pulsed signal, containing information about the received signal shape, in a ferrite film waveguide. The output nonlinear correlation signal having the doubled carrier frequency and the signal-to-noise ratio enhanced by several orders of magnitude is received by a dielectric resonator coupled to an output microwave transmission line. 相似文献