火焰原子吸收法测定人体胆结石中的铜、锌、钙、镁

本文介绍了火焰原子吸收法测定人体胆结石中铜、锌、钙、镁元素含量的测试条件及介质的影响，测试结果表明该方法具有较好的准确度和精密度，适合于医学临床应用。     

Atomic scale properties of interior interfaces of semiconductor heterostructures as determined by quasi-digital highly selective etching and atomic force microscopy

We report on first experiments combining quasi-digital highly selective etching and atomic force microscopy (AFM) to examine the interior interfaces of semiconductor heterostructures. Lattice matched (GaIn)As/InP heterostructures grown by metalorganic vapour-phase epitaxy (MOVPE) are taken as a model system to check the capabilities of this new method. Standard selective etchants for different material systems have been optimized in selectivity and etch rate to achieve a quasi-digital etching behaviour. In this way, the real structure of interior interfaces can be determined by AFM. We find a significant difference between the surface of the heterostructure and the interior interfaces.     

电热蒸发进样微波等离子体炬原子发射光谱法中共存元素的影响

本文考察了以微波等离子体炬（MPT）为光源，电热钽丝环进样时，溶液中共存元素对发射信号的影响。     

Identification of chlorinated sulfur compounds in pulp mill effluents by GC-MS and GC-AED

Summary Three chlorinated dimethyl sulfones and five chlorinated thiophenes have been identified in the alkaline extraction liquor from a bleach plant by gas chromatography with atomic emission detection (GC-AED) and with mass spectrometry (GC-MS). The information on elemental content obtained by GC-AED enabled a rapid screening of the sulfur compounds and provided important structural information complementary to the mass spectral data. Quantitation was accomplished by GC-AED based on universal calibration.     

原子吸收光谱法测定铬基合金中钒

本文研究了用原子吸收光谱法，在笑气－乙炔火焰中，测定钒的最佳条件，不用任何分离手段，以铝盐做干扰抑制剂，消除铬，镍对测定钒的干扰，西方法用于铬基合金中钒的测定，方法简单准确，具有实用意义。     

电感耦合等离子体原子发射光谱分析中不同电离电位元素基体效应的比较研究

选择不同电离电位的基体元素K、Na、La、Y和Mg,比较研究了它们对分析元素谱线强度的影响,其影响程度与谱线激发电位及基体元素电离电位有定量的相关关系。碱金属基体(K、Na)和非碱金属基体(La、Y和Mg)对分析元素检出限、背景强度及其相对标准偏差的影响显著不同,后者的记忆效应也大于前者。La的电离电位与Na相差不大。但其基体效应与Y相似,表明墓体效应与基体元素的化学性质有关。     

Characterization of Ultrathin Films of Cellulose Esters

The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified in order to evaluate the possibility of applying such films as selective support for biomolecules.     

Dynamic imaging of single DNA-protein interactions using atomic force microscopy

Atomic force microscopy (AFM) imaging of static DNA-protein complexes, in air and in liquid, can be used to directly obtain quantitative and qualitative information on the structure of different complexes. For example, DNA length, the location of preferential binding sites for proteins and bending of DNA as a result of the complexation can all be measured. Recording consecutive AFM images of DNA and protein molecules under conditions that they are still able to move and interact, or dynamic AFM imaging, however, can reveal information on the dynamic aspects of the interactions between these molecules. Here, an overview is given of the technical challenges that need to be considered for successful dynamic AFM imaging studies of individual DNA-protein interactions. Necessary technical improvements to the AFM set-up and the development of new sample preparation methods are described in this paper.     

火花激发原子发射光谱分析不锈钢线材

火花激发原子发射光谱法应用于直径小于8mm的不锈钢线材的分析，对此类试样应用了一种特制的夹具，用块状标准样品制作工作曲线。由于线状试样和块状标准样品之间的形状差异所产生的系统不确定度借采用同类型标样作校正，对共存元素的相互干扰也采用了相应的校正方法。其它分析条件，包括严格的制样工序，氩气的纯度要求及其流量控制，以及光源的最佳条件等，作了深入的试验。按所提出的方法测定了不锈钢线材试样中碳、硅、锰、磷、硫、铬、镍及钛等8个元素。经校正后的结果与化学法测得结果相符。     

ANN原子参数法预报合金相晶型及晶格常数

运用人工神经网络方法，以二元合金组成元素的电子结构为基本特征，对二元合金相晶型作了区分，进一步对其晶格常数作了预报，结果令人满意。