首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2668篇
  免费   72篇
  国内免费   144篇
化学   980篇
晶体学   8篇
力学   134篇
综合类   10篇
数学   920篇
物理学   832篇
  2024年   4篇
  2023年   90篇
  2022年   64篇
  2021年   62篇
  2020年   62篇
  2019年   57篇
  2018年   43篇
  2017年   72篇
  2016年   72篇
  2015年   73篇
  2014年   131篇
  2013年   177篇
  2012年   131篇
  2011年   156篇
  2010年   165篇
  2009年   191篇
  2008年   175篇
  2007年   191篇
  2006年   146篇
  2005年   98篇
  2004年   95篇
  2003年   84篇
  2002年   63篇
  2001年   45篇
  2000年   47篇
  1999年   45篇
  1998年   39篇
  1997年   50篇
  1996年   55篇
  1995年   27篇
  1994年   36篇
  1993年   22篇
  1992年   19篇
  1991年   14篇
  1990年   10篇
  1989年   10篇
  1988年   12篇
  1987年   8篇
  1986年   4篇
  1985年   6篇
  1984年   8篇
  1983年   7篇
  1982年   3篇
  1981年   5篇
  1980年   1篇
  1978年   5篇
  1977年   2篇
  1972年   1篇
  1969年   1篇
排序方式: 共有2884条查询结果,搜索用时 15 毫秒
101.
We consider the Robust Network Design problem, i.e. the problem of dimensioning the capacities on the edges of a graph to serve point-to-point traffic demands subject to uncertainty. The scope of the paper is to investigate when the cut condition is sufficient to guarantee the feasibility for such problem.  相似文献   
102.
Infrastructure systems such as power and water supplies make up the cornerstone of modern society which is essential for the functioning of a society and its economy. They become more and more interconnected and interdependent with the development of scientific technology and social economy. Risk and vulnerability analysis of interdependent infrastructures for security considerations has become an important subject, and some achievements have been made in this area. Since different infrastructure systems have different structural and functional properties, there is no universal all-encompassing ‘silver bullet solution’ to the problem of analyzing the vulnerability associated with interdependent infrastructure systems. So a framework of analysis is required. This paper takes the power and water systems of a major city in China as an example and develops a framework for the analysis of the vulnerability of interdependent infrastructure systems. Four interface design strategies based on distance, betweenness, degree, and clustering coefficient are constructed. Then two types of vulnerability (long-term vulnerability and focused vulnerability) are illustrated and analyzed. Finally, a method for ranking critical components in interdependent infrastructures is given for protection purposes. It is concluded that the framework proposed here is useful for vulnerability analysis of interdependent systems and it will be helpful for the system owners to make better decisions on infrastructure design and protection.  相似文献   
103.
Motivated by recent physics papers describing rules for natural network formation, we study an elliptic-parabolic system of partial differential equations proposed by Hu and Cai [13 Hu , D. (2013). Optimization, Adaptation, and Initialization of Biological Transport Networks. Workshop on multiscale problems from physics, biology and material sciences. May 28–31st, 2014, Shanghai. Available at: http://math.sjtu.edu.cn/conference/multiscale2014/ (accessed 6 January 2015). [Google Scholar], 15 Hu , D. , Cai , D. ( 2013 ). Adaptation and optimization of biological transport networks . Phys. Rev. Lett. 111 : 138701 .[Crossref], [PubMed], [Web of Science ®] [Google Scholar]]. The model describes the pressure field thanks to Darcy's type equation and the dynamics of the conductance network under pressure force effects with a diffusion rate D ≥ 0 representing randomness in the material structure. We prove the existence of global weak solutions and of local mild solutions and study their long term behavior. It turns out that, by energy dissipation, steady states play a central role to understand the network formation capacity of the system. We show that for a large diffusion coefficient D, the zero steady state is stable, while network formation occurs for small values of D due to the instability of the zero steady state, and the borderline case D = 0 exhibits a large class of dynamically stable (in the linearized sense) steady states.  相似文献   
104.
An artificial neural network model of supported liquid membrane extraction process with a stagnant acceptor phase is proposed. Triazine herbicides and phenolic compounds were used as model compounds. The model is able to predict the compound extraction efficiency within the same family based on the octanol–water partition coefficient, water solubility, molecular mass and ionisation constant of the compound. The network uses the back‐propagation algorithm for evaluating the connection strengths representing the correlations between inputs (octanol–water partition coefficients logP, acid dissociation constant pKa, water solubility and molecular weight) and outputs (extraction efficiency in dihexyl ether and undecane as organic solvents). The model predicted results in good agreement with the experimental data and the average deviations for all the cases are found to be smaller than ±3%. Moreover, standard statistical methods were applied for exploration of relationships between studied parameters.  相似文献   
105.
This work presents an automatic system, based on an electronic tongue, for resolution of mixtures of three pesticides. Inhibition detections were performed during the steady state of biosensors response. Three biosensors were built using two enzymes, electric eel (EE), genetically-modified Drosophila melanogaster (B131), and electric eel co-immobilized with drosophila melanogaster (BH). Calibrations curves for paraoxon, dichorlvos, and carbofuran were performed in the ranges 0.4–50.4 µM, 0.01–1.01 µM, 0.01–0.41 µM with LOD of 3.91 × 10?8, 6.30 × 10?11, and 5.84 × 10?10, respectively. An artificial neural network (ANN) was used to model the combined response of three pesticides. A set of 19 mixtures were prepared in order to train the artificial neural network, the modeling was validated with a set of 6 spiked samples of river water. The error and recovery yields were found in consistent with expected values.  相似文献   
106.
The effect of Fe (II) metallomicelle as a model of catalase, which was formed by adding surfactants (CTAB, SDS, LSS, Brij35) in Fe (II) -trien complex of molar ratios 1: 500 on the decomposition of hydrogen peroxide was investigated at 20°C and 30°C in pH 10 using KI-color and UV Spectrophotometry. A kinetic model for metallomicellar catalysis was proposed. The association constant of the ternary complex K and the rate constant of the decomposition of hydrogen peroxide k3 were obtained. The results indicate that the metallomicelles making up of Fe (II) metal complex and cationic or nonionic surfactants have obvious catalysis on the decomposition of hydrogen peroxide, but the metallomicelles making up of Fe (II) metal complex and anionic or zwitterionic surfactants have inhibition on this reaction.  相似文献   
107.
Linear and crosslinked copolymers with different compositions of 1-hexadecene and trimethylolpropane distearate monoacrylate monomers were synthesized and evaluated for oil-absorbency application. Different concentrations of ethylene glycol diacrylate (EGDA) and ethylene glycol dimethacrylate (EGDMA) crosslinkers were used. The concentration of both crosslinkers was varied from 0.5% to 2%. Copolymer compositions were determined from 1H NMR spectroscopy. Monomer reactivity ratios were calculated using Fineman-Ross and Kelen-Tudos techniques at low conversions. The oil absorbency and swelling rate constant were measured and influenced mainly by the degree of crosslinking and the hydrophobicity of copolymer units. The final equilibrium oil content, volume fraction of polymer and swelling capacity were determined at 298 K. The effective crosslinking density Ve, theoretical crosslink density Vt, the average molecular weight between the crosslinks Mc and the polymer-toluene interaction parameter χ were determined from swelling measurements. The efficiencies of EGDA and EGDMA crosslinking agents toward copolymers were determined.  相似文献   
108.
A molecular dynamics simulation method is presented and used in the study of the formation of polymer networks. We study the formation of networks representing the methylene repeating units as united atoms. The network formation is accomplished by cross-linking polymer chains with dedicated functional end groups. The simulations reveal that during the cross-linking process, initially branched molecules are formed before the gel point; approaching the gel point, larger branched entities are formed through integration of smaller branched molecules, and at the gel point a network spanning the simulation box is obtained; beyond the gel point the network continues to grow through the addition of the remaining molecules of the sol phase onto the gel (the network); the final completion of the reaction occurs by intra-network connection of dangling ends onto unsaturated cross-linkers. The conformational properties of the strands in the undeformed network are found to be very similar with the conformational properties of the chains before cross-linking. The uniaxial deformation of the formed networks is investigated and the modulus determined from the stress-strain curves shows reciprocal scaling with the precursor chain length for networks formed from sufficiently large precursor chains (N ≥ 20).  相似文献   
109.
网络舆情危机应对评价是企业在新的舆论背景下研究危机应对的重点.采用定量和定性分析有机结合的层次分析法确定指标体系及权重,给出了企业网络舆情危机应对评价的步骤,并进行了评价验证.该评价体系为相关单位网络舆情危机应对评价提供一定的参考和指导.  相似文献   
110.
In 1991,Hornik proved that the collection of single hidden layer feedforward neural networks(SLFNs)with continuous,bounded,and non-constant activation functionσis dense in C(K)where K is a compact set in R~s(see Neural Networks,4(2),251-257(1991)).Meanwhile,he pointed out"Whether or not the continuity assumption can entirely be dropped is still an open quite challenging problem".This paper replies in the affirmative to the problem and proves that for bounded and continuous almost everywhere(a.e.)activation functionσon R,the collection of SLFNs is dense in C(K)if and only ifσis un-constant a.e..  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号