Microwave-assisted synthesis of asymmetric thiocarbonohydrazones under solvent-free conditions

Six new asymmetric thiocarbonohydrazones 3a-3f were synthesized from following steps:firstly hydrazine hydrate reacted with carbon disulfide to form thiocarbonohydrazide(1) under microwave irradiation.Then compound(1) reacted with ketone and different aldehydes step by step to give 3a-3f with excellent yields under solvent-free conditions using microwave irradiation.Their structures have been determined by elemental analysis,IR,MS and ~1H NMR data.     

A new method for preparing （2Z, 4Z, 6Z）-diethyl-4,5- oxepinedicarboxylates and some 1H-azepine analogues

A new method for preparing (2Z, 4Z, 6Z)-4,5-diethyloxepinodicarboxylate by one-step is described. The synthesis of several oxepines and azepines derivatives was carried out by the reaction of substituted furans or pyrroles with diethyl acetylenedicarbox-ylate in boiling toluene. The effect factors for this reaction were discussed and reaction condition was optimized.     

Influence of pH value on microstructure and thermal stability of Ni-P electroless coating prepared in acidic condition

Three kinds of Ni-P electroless coatings were prepared in nickel sulphate solution at different pH values of 4.5,5.5 and 6.5 with the purpose of ascertaining the influence of pH value on microstructure,internal stress statue and thermal stability of the coatings.Laser curvature(LC) method was used to measure the residual stress level in the coatings.Scanning electronic microscopy(SEM) and transmission electronic microscopy with energy dispersive spectrum(TEM/EDS) were used to examine the surface morpholo...     

Rapid and efficient synthesis of new chiral aromatic amide molecular tweezers under solvent-free conditions using microwave

An efficient and simple method for the synthesis of new chiral aromatic amide molecular tweezers by irradiation with microwave under solvent-free conditions has been developed.Its main advantages are short reaction times.good conversions and the environmentally friendly nature of the process.     

Covalently anchored sulfonic acid on silica gel （SiO2-R-SO3H） as an efficient and reusable heterogeneous catalyst for the one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions

A highly efficient one-pot synthesis of 1,8-dioxooctahydroxanthenes under solvent-free conditions catalyzed by sulfonic acid covalently anchored onto the surface of silica gel is reported.All types of aldehydes,including aromatic,unsaturated,and heterocyclic,are used.The silica gel/sulfonic acid catalyst (SiO2-R-SO3H) is completely heterogeneous and can be recycled.     

METHOD OF CENTERS ALGORITHM FOR MULTI-OBJECTIVE PROGRAMMING PROBLEMS

In this paper, we consider a method of centers for solving multi-objective programming problems, where the objective functions involved are concave functions and the set of feasible points is convex. The algorithm is defined so that the sub-problems that must be solved during its execution may be solved by finite-step procedures. Conditions are given under which the algorithm generates sequences of feasible points and constraint multiplier vectors that have accumulation points satisfying the KKT conditions. Finally, we establish convergence of the proposed method of centers algorithm for solving multiobjective programming problems.     

自然电位测井数学模型的一类求解方法

针对自然电位测井的数学模型,利用双层位势给出了对其数值求解的一种有效的方法.     

一类具非齐次项的非线性Schr(o)dinger方程整体解存在的最佳条件

本文讨论具非齐次项的非线性Schrodinger方程.根据基态的特征,运用势井理论和凹方法,我们获得了该方程整体解存在的-个最佳条件,同时也给出了当初值多小时,方程的整体解存在.     

FINITE ELEMENTS WITH LOCAL PROJECTION STABILIZATION FOR INCOMPRESSIBLE FLOW PROBLEMS

In this paper we review recent developments in the analysis of finite element methods for incompressible flow problems with local projection stabilization （LPS）. These methods preserve the favourable stability and approximation properties of classical residual-based stabilization （RBS） techniques but avoid the strong coupling of velocity and pressure in the stabilization terms. LPS-methods belong to the class of symmetric stabilization techniques and may be characterized as variational multiscale methods. In this work we summarize the most important a priori estimates of this class of stabilization schemes developed in the past 6 years. We consider the Stokes equations, the Oseen linearization and the NavierStokes equations. Furthermore, we apply it to optimal control problems with linear（ized） flow problems, since the symmetry of the stabilization leads to the nice feature that the operations ＂discretize＂ and ＂optimize＂ commute.     

非线性参数规划问题$\varepsilon$-最优解集集值映射的连续性

对非线性参数规划问题$\varepsilon$-最优解集集值映射的连续性条件进行了研究.首先在可行集集值映射局部有界且正则的条件下,讨论了非线性参数规划问题最优值函数的连续性,然后针对$\varepsilon$-最优解集集值映射的结构特征并利用此结果和集值分析理论,给出了非线性参数规划问题$\varepsilon$-最优解集集值映射连续的一个充分条件.