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71.
Martin G Banwell Alison J Edwards Gwion J Harfoot Katrina A Jolliffe 《Tetrahedron》2004,60(3):535-547
An enantiomerically pure cis-1,2-dihydrocatechol, which is readily obtained via a toluene dioxygenase-mediated dihydroxylation of toluene in a whole-cell biotransformation process, has been converted over 17 steps into the linear triquinane (−)-hirsutene. Since the enantiomer of the starting material is also available this work constitutes a formal total synthesis of the naturally occurring (+)-form of hirsutene. Furthermore, minor modifications of the route used here offer the possibility of accessing (+)-hirsutene from the original starting material. 相似文献
72.
Zh. D. Chaplanova Yu. K. Mikhailovskii V. E. Agabekov V. K. Ol’khovik N. A. Galinovskii E. A. Gracheva 《Journal of Applied Spectroscopy》2007,74(3):333-337
We have studied the spectral properties and morphology of thin films (TVD films) formed by thermal vacuum deposition of 4,4′-bis[(E)-1-(1,3-benzoxazol-2-yl)-2-ethenyl]-1,1′-biphenyl
and its substituted derivatives. We have shown that introducing bulky 2,2′-oxyhexyl substituents into the biphenyl units leads
to a shift of the fluorescence maximum for the TVD films toward shorter wavelengths, a decrease in their photostability, and
aggregation of the films during storage.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 3, pp. 300–303, May–June, 2007. 相似文献
73.
我们对多电子束契伦柯夫自由电子激光进行了首次实验研究。280A,500kV的电子束被引入一多介质矩形谐振腔,在频率为33.4GHz处产生了1.7MW的契伦柯夫相干受激辐射。互作用效率为1.2%。 相似文献
74.
研究了乘积空间中严格集压缩减算子不动点存在唯一性问题,在弱连续的条件下,得到了不动点的存在唯一性和迭代收敛性.并给出了它的应用. 相似文献
75.
用共沉淀法制备了Mg2 + 掺杂的In2 O3 纳米粉 ,研究了镁掺杂对In2 O3 电导和气敏性能的影响 .结果表明 :MgO和In2 O3 间可形成有限固溶体In2 -xMgxO3 (0≤x≤ 0 .40 ) ;MgIn× 电离的空穴对材料导带电子的湮灭 ,使掺镁纳米粉的电导变得很小 ;n(Mg2 + )∶n(In3 + ) =1∶2共沉淀物于 90 0℃下热处理 4h ,用所得的纳米粉制作的传感器在 32 0~ 370℃下 ,对 45 μmol/LC2 H5OH的灵敏度达 10 2 .5 ,为相同浓度干扰气体Petrol的 12倍多 . 相似文献
76.
A. Hansen M.H. Jensen K. Sneppen G. Zocchi 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(1):157-161
We present a statistical mechanics treatment of the stability of globular proteins which takes explicitly into account the
coupling between the protein and water degrees of freedom. This allows us to describe both the cold and the warm unfolding,
thus qualitatively reproducing the known thermodynamics of proteins.
Received: 19 March 1998 / Revised and Accepted: 25 May 1998 相似文献
77.
M. Stenger S. Baumhoff J.-Y. Prieur J. Joffrin J.-P. Contour 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):177-182
We present measurements of the attenuation and phase velocity of surface acoustic waves in thin YBa2Cu3O films as a function of temperature, in magnetic fields up to 3.6 T applied parallel to the c-axis of the films. We have observed anomalies in both, the attenuation and the phase velocity in the vicinity of the superconducting
critical temperature which do not depend on the magnetic field. Possible origins of these anomalies, observed, to our knowledge,
for the first time in YBa2Cu3O thin films, are discussed and compared to bulk acoustic wave experiments. We present a kind of feedback technique for surface
acoustic waves which improves the sensitivity of this type of measurement. The actual sensitivity limits are mentioned.
Received: 7 August 1997 / Revised: 7 November 1997 / Accepted: 17 November 1997 相似文献
78.
C. Ruyer-Quil P. Manneville 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,6(2):277-292
A new model of film flow down an inclined plane is derived by a method combining results of the classical long wavelength
expansion to a weighted-residuals technique. It can be expressed as a set of three coupled evolution equations for three slowly
varying fields, the thickness h, the flow-rate q, and a new variable that measures the departure of the wall shear from the shear predicted by a parabolic velocity profile. Results of a preliminary
study are in good agreement with theoretical asymptotic properties close to the instability threshold, laboratory experiments
beyond threshold and numerical simulations of the full Navier-Stokes equations.
Received: 16 April 1998 / Revised: 29 June 1998 / Accepted: 2 July 1998 相似文献
79.
A. Barnabé A. Maignan M. Hervieu B. Raveau 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(2):145-150
Doping of Mn-site by chromium, cobalt and nickel has been investigated in the calcium rich manganites and
. Whatever the nature of the doping element, a rapid disappearance of the charge ordered (CO) state is observed, decreasing as the doping rate increases. But the most important result concerns the Cr-doped compounds for which a re-entrant insulator to metal transition at 90-120 K is observed for x
=0.10-0.12, in a zero magnetic field. The possibility to induce colossal magnetoresistance (CMR) properties for high (IV) contents ((IV)/) for x
=0.07-0.12 is shown for the first time, the resistance ratios reaching at 30 K. This study also shows differently that the small size of the A-site cation (Pr, Ca) is not a redhibitory obstacle
to the appearance of CMR properties in manganites, in contrast with previously established phase diagrams.
Received: 18 June 1997 / Revised: 4 August 1997 / Accepted: 10 November 1997 相似文献
80.
M. Reuhl P. Nielaba K. Binder 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,2(2):225-232
,Static and dynamic properties of the Potts model on the simple cubic lattice with nearest neighbor -interaction are obtained from Monte Carlo simulations in a temperature range where full thermal equilibrium still can be
achieved (). For a lattice size L
= 16, in this range finite size effects are still negligible, but the data for the spin glass susceptibility agree with previous
extrapolations based on finite size scaling of very small lattices. While the static properties are compatible with a zero
temperature transition, they certainly do not prove it. Unlike the Ising spin glass, the decay of the time-dependent order
parameter is compatible with a simple Kohlrausch function, , while a power law prefactor cannot be distinguished. The Kohlrausch exponent y
(
T
) decreases from at [0pt] to at [0pt] however. The relaxation time is compatible with the exponential divergence postulated by McMillan for spin glasses at their lower critical dimension,
but the exponent that can be extracted still differs significantly from the theoretical value, . Thus the present results support the conclusion that the Potts spin glass in d
= 3 dimensions differs qualitatively from the Ising spin glass.
Received: 8 October 1997 / Accepted: 27 November 1997 相似文献