全文获取类型
收费全文 | 2583篇 |
免费 | 370篇 |
国内免费 | 96篇 |
专业分类
化学 | 972篇 |
晶体学 | 5篇 |
力学 | 151篇 |
综合类 | 83篇 |
数学 | 817篇 |
物理学 | 1021篇 |
出版年
2024年 | 20篇 |
2023年 | 143篇 |
2022年 | 330篇 |
2021年 | 451篇 |
2020年 | 269篇 |
2019年 | 180篇 |
2018年 | 146篇 |
2017年 | 134篇 |
2016年 | 155篇 |
2015年 | 97篇 |
2014年 | 116篇 |
2013年 | 191篇 |
2012年 | 70篇 |
2011年 | 71篇 |
2010年 | 81篇 |
2009年 | 78篇 |
2008年 | 59篇 |
2007年 | 69篇 |
2006年 | 51篇 |
2005年 | 38篇 |
2004年 | 36篇 |
2003年 | 26篇 |
2002年 | 28篇 |
2001年 | 20篇 |
2000年 | 23篇 |
1999年 | 20篇 |
1998年 | 15篇 |
1997年 | 20篇 |
1996年 | 15篇 |
1995年 | 20篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 9篇 |
1985年 | 4篇 |
1984年 | 3篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 2篇 |
1969年 | 1篇 |
1959年 | 5篇 |
排序方式: 共有3049条查询结果,搜索用时 145 毫秒
41.
为了研究AlGaN量子阱层和垒层中Al组分不同对AlGaN基深紫外发光二极管(LED)光电性能的影响,本文利用MOCVD生长、光刻和干法刻蚀工艺制备了AlGaN量子阱层和垒层具有不同Al组分的270/290/330nm深紫外LED,通过实验和数值模拟计算方法发现,量子阱层和垒层中具有低Al组分紫外LED的AlGaN材料具有较低的位错密度、较高的光输出功率和外量子效率。通过电流-电压(I-V)曲线拟合出的较大的理想因子(3.5)和能带结构图表明,AlGaN深紫外LED的电流产生是隧穿机制占据主导作用,这是因为高Al组分AlGaN量子阱中强极化场造成了有源层区域较大的能带弯曲和电势降。 相似文献
42.
《International journal of quantum chemistry》2018,118(2)
We investigate the success of the quantum chemical electron impact mass spectrum (QCEIMS) method in predicting the electron impact mass spectra of a diverse test set of 61 small molecules selected to be representative of common fragmentations and reactions in electron impact mass spectra. Comparison with experimental spectra is performed using the standard matching algorithms, and the relative ranking position of the actual molecule matching the spectra within the NIST‐11 library is examined. We find that the correct spectrum is ranked in the top two matches from structural isomers in more than 50% of the cases. QCEIMS, thus, reproduces the distribution of peaks sufficiently well to identify the compounds, with the RMSD and mean absolute difference between appropriately normalized predicted and experimental spectra being at most 9% and 3% respectively, even though the most intense peaks are often qualitatively poorly reproduced. We also compare the QCEIMS method to competitive fragmentation modeling for electron ionization, a training‐based mass spectrum prediction method, and remarkably we find the QCEIMS performs equivalently or better. We conclude that QCEIMS will be very useful for those who wish to identify new compounds which are not well represented in the mass spectral databases. 相似文献
43.
44.
Soo Chung Christian M. Jennings Prof. Jeong-Yeol Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(57):13070-13077
In recent years, there has been high interest in paper-based microfluidic sensors or microfluidic paper-based analytical devices (μPADs) towards low-cost, portable, and easy-to-use sensing for chemical and biological targets. μPAD allows spontaneous liquid flow without any external or internal pumping, as well as an innate filtration capability. Although both optical (colorimetric and fluorescent) and electrochemical detection have been demonstrated on μPADs, several limitations still remain, such as the need for additional equipment, vulnerability to ambient lighting perturbation, and inferior sensitivity. Herein, alternative detection methods on μPADs are reviewed to resolve these issues, including relatively well studied distance-based measurements and the newer capillary flow dynamics-based method. Detection principles, assay performance, strengths, and weaknesses are explained for these methods, along with their potential future applications towards point-of-care medical diagnostics and other field-based applications. 相似文献
45.
《Journal of computational chemistry》2017,38(13):1005-1014
The fully polarizable, multipolar, and atomistic force field protein FFLUX is being built from machine learning (i.e., kriging) models, each of which predicts an atomic property. Each atom of a given protein geometry needs to be assigned such a kriging model. Such a knowledgeable atom needs to be informed about a sufficiently large environment around it. The resulting complexity can be tackled by collecting the 20 natural amino acids into a few groups. Using substituted deca‐alanines, we present the proof‐of‐concept that a given atom's charge can be modeled by a few kriging models only. © 2017 Wiley Periodicals, Inc. 相似文献
46.
47.
A picosecond widely tunable deep-ultraviolet laser for angle-resolved photoemission spectroscopy 下载免费PDF全文
We develop a picosecond widely tunable laser in a deep-ultraviolet region from 175 nm to 210 nm,generated by two stages of frequency doubling of a 80-MHz mode-locked picosecond Ti:sapphire laser.A β-BaB2O4 walk-off compensation configuration and a KBe2BO3F2 prism-coupled device are adopted for the generation of second harmonic and fourth harmonics,respectively.The highest power is 3.72 mW at 193 nm,and the fluctuation at 2.85 mW in 130 min is less than ±2%. 相似文献
48.
Complex dynamics in equilibrium asset pricing models with boundedly rational,heterogeneous agents 下载免费PDF全文
We study a simple model based upon the Lucas framework where heterogeneous agents behave rationally in a fully intertemporal setting but do not know other investors' personal preferences, wealth or investment portfolios. As a consequence, agents initially do not know the equilibrium asset pricing function and must make guesses, which they update via adaptive learning with constant gain. We demonstrate that even in this simple environment the economy can, depending on parameters, exhibit either stable convergence to equilibrium, or chaotic dynamical behavior of asset prices and trading volume without converging to the rational expectations equilibrium of the Lucas model. This contradicts the assertion that the Lucas model is stable in the face of modest deviations from the strong assumptions required to compute the equilibrium. © 2013 Wiley Periodicals, Inc. Complexity 19: 38–55, 2014 相似文献
49.
In this paper we consider data from a study in which students shift from linear to quadratic equations in ways that do not conform to established theoretical frameworks. In solving linear equations, the students did not exhibit the ‘didactic cut’ of Filloy and Rojano (1989) or the subtleties arising from conceiving an equation as a balance (Vlassis, 2002). Instead they used ‘procedural embodiments’, shifting terms around with added ‘rules’ to obtain the correct answer (Lima & Tall, 2008). Faced with quadratic equations, the students learn to apply the formula with little success. The interpretation of this data requires earlier theories to be seen within a more comprehensive framework that places them in an evolving context. We use the developing framework of three worlds of mathematics (Tall, 2004, Tall, 2013), based fundamentally on human perceptions and actions and their consequences, at each stage taking into account the experiences that students have ‘met-before’ (Lima and Tall, 2008, McGowen and Tall, 2010). These experiences may be supportive in new contexts, encouraging pleasurable generalization, or problematic, causing confusion and even mathematical anxiety. We consider how this framework explains and predicts the observed data, how it evolves from earlier theories, and how it gives insights that have both theoretical and practical consequences. 相似文献
50.
Dahui Luo JinRong Wang Dong Shen 《Mathematical Methods in the Applied Sciences》2019,42(13):4543-4553
This paper considers the consensus tacking problem for nonlinear fractional‐order multiagent systems by presenting a PDα‐type iterative learning control update law with initial learning mechanisms. The asymptotical convergence of the proposed distributed learning algorithm is strictly proved by using the properties of fractional calculus. A sufficient condition is derived to guarantee the whole multiagent system achieving an asymptotic output consensus. An illustrative example is given to verify the theoretical results. 相似文献