NMR study of products of thermal transformation of substituted N-aryl-o-quinoneimines

Products of thermal transformation of substituted N-aryl-o-quinoneimines were studied using NMR spectroscopy. The formation of 4aH-phenoxazine, which was further dimerized by the Diels—Alder reaction, was established.     

Trace norm estimates for products of integral operators and diffusion semigroups

We give trace norm estimates for products of integral operators and for diffusion semigroups. These are applied to differences of heat semigroups. A natural example of an integral operator with finite trace which is not trace class is given.     

Calculus of functors and model categories

The category of small covariant functors from simplicial sets to simplicial sets supports the projective model structure [B. Chorny, W.G. Dwyer, Homotopy theory of small diagrams over large categories, preprint, 2005]. In this paper we construct various localizations of the projective model structure and also give a variant for functors from simplicial sets to spectra. We apply these model categories in the study of calculus of functors, namely for a classification of polynomial and homogeneous functors. In the n-homogeneous model structure, the nth derivative is a Quillen functor to the category of spectra with Σn-action. After taking into account only finitary functors—which may be done in two different ways—the above Quillen map becomes a Quillen equivalence. This improves the classification of finitary homogeneous functors by T.G. Goodwillie [T.G. Goodwillie, Calculus. III. Taylor series, Geom. Topol. 7 (2003) 645-711 (electronic)].     

The Riesz decomposition of finely superharmonic functions

This paper answers a question of Fuglede about minimal positive harmonic functions associated with irregular boundary points. As a consequence, an old and central problem of fine potential theory, concerning the Riesz decomposition, is resolved. Namely, it is shown that, on certain fine domains, there exist positive finely superharmonic functions which do not admit any positive finely harmonic minorant and yet are not fine potentials.     

Realization of 2-solvable nilpotent groups as groups of classes of homotopy self-equivalences

Let X be a 1-connected CW-complex of finite type and ε_?(X) be the group of homotopy classes of self-equivalences of X which induce the identity on homotopy groups. In this paper, we prove that every finitely generated 2-solvable rational nilpotent group is realizable as ε_?(X) where X is the rationalization of a 1-connected CW-complex of finite type.     

Symmetrisation of n-operads and compactification of real configuration spaces

It is well known that the forgetful functor from symmetric operads to nonsymmetric operads has a left adjoint Sym₁ given by product with the symmetric group operad. It is also well known that this functor does not affect the category of algebras of the operad. From the point of view of the author's theory of higher operads, the nonsymmetric operads are 1-operads and Sym₁ is the first term of the infinite series of left adjoint functors Symn, called symmetrisation functors, from n-operads to symmetric operads with the property that the category of one object, one arrow, …, one (n−1)-arrow algebras of an n-operad A is isomorphic to the category of algebras of Symn(A).In this paper we consider some geometrical and homotopical aspects of the symmetrisation of n-operads. We follow Getzler and Jones and consider their decomposition of the Fulton-Macpherson operad of compactified real configuration spaces. We construct an n-operadic counterpart of this compactification which we call the Getzler-Jones operad. We study the properties of Getzler-Jones operad and find that it is contractible and cofibrant in an appropriate model category. The symmetrisation of the Getzler-Jones operad turns out to be exactly the operad of Fulton and Macpherson. These results should be considered as an extension of Stasheff's theory of 1-fold loop spaces to n-fold loop spaces n?2. We also show that a space X with an action of a contractible n-operad has a natural structure of an algebra over an operad weakly equivalent to the little n-disks operad. A similar result holds for chain operads. These results generalise the classical Eckman-Hilton argument to arbitrary dimension.Finally, we apply the techniques to the Swiss-Cheese type operads introduced by Voronov and prove analogous results in this case.     

Li2O-B2O3-P2O5系统非晶态混合骨架效应的NMR研究

用核磁共振对非晶态中B³⁺离子的微观结构进行了测定,结合Raman光谱的研究,对Li₂O-B₂O₃-P₂O₅系统非晶态的性能(电导率、密度等)在P₂O₅/B₂O₃比约等于1时产生极值的原因从理论上作了阐明。     

丙烯腈γ辐射聚合的NMR研究

用¹H NMR、¹³C NMR谱、自旋-晶格弛豫时间（T₁）和自旋-自旋弛豫时间（T₂）研究了丙烯腈在⁶⁰Co γ射线辐射聚合后的大分子结构变化与大分子链的运动. 结果表明随着辐射剂量增大，在单体形成聚合物的过程中，聚合物主链上出现了少量的-OH基团，继续增大辐射剂量， -OH部分被氧化. 对聚合物溶液的变温氢谱的研究表明，溶剂中的残余水与上述-OH形成氢键，且随着温度升高氢键被破坏，同时H₂O与-OH之间还存在着质子交换. 利用¹³C NMR谱对丙烯腈辐射聚合的产物进行了序列结构分析. 对T₁和T₂的研究表明，辐射剂量的增大并未影响到聚丙烯腈的链运动，证明了在丙烯腈的辐射聚合过程交联反应未发生.     

Markov processes associated with L p -resolvents and applications to stochastic differential equations on Hilbert space

We give general conditions on a generator of a C₀-semigroup (resp. of a C₀-resolvent) on L^p(E,μ), p ≥ 1, where E is an arbitrary (Lusin) topological space and μ a σ-finite measure on its Borel σ-algebra, so that it generates a sufficiently regular Markov process on E. We present a general method how these conditions can be checked in many situations. Applications to solve stochastic differential equations on Hilbert space in the sense of a martingale problem are given. Dedicated to Giuseppe Da Prato on the occasion of his 70th birthday