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81.
Seventeen 1-aryl-2,2-dichlorocyclopropanes were examined by using IR, 13C NMR, and mass spectrometry. The data obtained from IR and 13C NMR spectra indicate that the bond strength of carbon-chlorine on the cyclopropane ring and the electron density of that carbon depend on the substituent. The mass fragmentation patterns of compounds in this series resemble those of the dibromo analogues. The fragmentation mechanism is proposed to involve the formation of indenium ion through an electrocyclization. 相似文献
82.
一维Au/MgF2光子晶体的透射性质 总被引:13,自引:11,他引:2
理论上研究了一维金属/电介质光子晶体的透射率性质,用传输矩阵方法数值计算了Au/MgF2光子带隙晶体的透射率.发现周期性结构产生的透射共振会大幅度增加光通过层状金属的透射率.通过调节一维Au/MgF2光子晶体中金和氟化镁的厚度以及周期数,得到了可见波段的高透射允带,透射率在0.4以上,而对于可见波段以外的频率几乎是完全不能传输的.这种结构在保持了高透射率的前提下还具有金属的优点,这在传感器、护目装置、反射窗、液晶显示等诸多领域都有很大的实用价值. 相似文献
83.
T. González-Lezana G. Delgado-Barrio P. Villarreal F.X. Gadéa 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):227-232
The stabilization method is applied to the case of interacting resonances in the photo-dissociation of van der Waals clusters
composed by a rare gas atom bound to a dihalogen molecule. The study of an illustrative two-dimensional model consisting in
a T-shaped NeI2 molecule shows the adequacy of the method whenever the projection of the stabilization wave functions on the assumed prepared
initial state is accounted for. The agreement of the fragmentation cross-sections with some previous results using the effective
resolvent method and accurate close-coupling calculations is excellent. The method reveals its utility as a complementary
tool since allows, through the analysis of the stabilization wave function in terms of zero-order levels, a precise characterization
of the resonant states involved.
Received 5 April 2002 / Received in final form 24 May 2002 Published online 19 July 2002 相似文献
84.
N.P. Somasiri W.K. Toh X. Chen I.D. Robertson A.A. Rezazadeh 《International Journal of Infrared and Millimeter Waves》2002,23(12):1777-1785
This paper describes numerical modelling of a dual band multi-layered microstrip patch antenna operating at 35GHz on an in-house semi-insulating GaAs substrate. The simulated and measured resonant frequencies at both lower and upper resonant frequencies will be compared to check the accuracy of the different numerical modelling techniques. 相似文献
85.
At the ISOLDE on-line isotope separation facility, the resonance ionisation laser ion source (RILIS) can be used to ionise
reaction products as they effuse from the target. The RILIS process of laser step-wise resonance ionisation of atoms in a
hot metal cavity provides a highly element selective stage in the preparation of the radioactive ion beam. As a result, the
ISOLDE mass separators can provide beams of a chosen isotope with greatly reduced isobaric contamination. With the addition
of a new three-step ionisation scheme for gold, the RILIS is now capable of ionising 26 of the elements. The optimal scheme
was determined during an extensive study of the atomic energy levels and auto-ionising states of gold, carried out by means
of in-source resonance ionisation spectroscopy. Details of the ionisation scheme and a summary of the spectroscopy study are
presented. 相似文献
86.
低密度聚乙烯光引发交联机理——Ⅱ.BNB自旋捕捉ESR研究 总被引:6,自引:4,他引:2
在光引发剂二苯甲酮(BP)存在下,紫外光辐照低密度聚乙烯(LDPE)所形成的自由基中间体已被自旋捕捉剂2,4,6-三特丁基亚硝基苯(BNB)所捕捉,其自旋加合物自由基已为电子自旋共振(ESR)所特征。现已检测和鉴定到二种自旋加合物:一种是叔碳自由基;另一种是仲碳自由基。它们分别是由BP的激发三重态从LDPE链的支化点和亚甲基团上夺氢所形成的自由基中间体同自旋捕捉剂BNB反应生成的。上述的证据表明:LDPE的光引发交联点主要发生在叔碳和仲碳原子上,且H-型交联点占主导地位。 相似文献
87.
研究了采用低场脉冲核磁共振(NMR)测定二醋酸纤维素丝束油剂的新方法,给出NMR法测定二醋酸纤维素丝束油荆含量的标准曲线。同时对NMR法测量二醋酸纤维素丝束油荆不确定度进行了评估。结果表明,NMR法具有分析速度快、无污染、无损伤和准确度高的优点,适合于二醋酸纤维素丝束油荆的分析。 相似文献
88.
A. A. Vertiy A. V. Golik A. P. Korolyuk S. I. Tarapov V. P. Shestopalov 《International Journal of Infrared and Millimeter Waves》1989,10(12):1451-1456
The research technique of amorphous magnetics is described. The paper gives the experimental data obtained by a multifunctional low-temperature radiospectrometer Buran in the mm radiowave range and presents their analysis. 相似文献
89.
Multinuclear magnetic resonance data for the title compounds are presented and discussed. The intramolecular coordination observed in the solid state is shown to be retained in solution. The best probes for the presence or absence of pentacoordination at tin are provided by the various tin-element coupling constants, although chemical shifts are in some cases also informative. A selenium-proton correlated spectrum indicated that the coupling constant 1J(Sn,Se) has a positive sign. 相似文献
90.
I. L. Fedushkin A. N. Lukoyanov G. K. Fukin M. Hummert H. Schumann 《Russian Chemical Bulletin》2006,55(7):1177-1183
Reduction of benzophenone and 4,4′-bis(methoxy)benzophenone with the aluminum complex (dpp-BIAN)AlI(Et2O) (1) containing the dianionic dpp-BIAN ligand (dpp-BIAN is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) affords the pinacolate
complexes [(dpp-BIAN)AlI]2[μ-O2C2Ph4] (2) and [(dpp-BIAN)AlI]2[μ-O2C2(C6H4OMe)4] (3), respectively, which undergo the pinacolone rearrangement upon prolonged storage in diethyl ether to form [(dpp-BIAN)AlI]2O (4). The reaction of 1 with fluoren-9-one produces stable pinacolate (dpp-BIAN)Al[μ-O2(C13H8)2] (7) and the (dpp-BIAN)AlI2 complex (8). Compounds 2—4, 7, and 8 were characterized by ESR spectroscopy. Hydrolysis products of compounds 2 and 3 were characterized by 1H NMR spectroscopy. The structures of complexes 4 and 7 were established by X-ray diffraction.
dpp-BIAN is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1134–1140, July, 2006. 相似文献