全文获取类型
收费全文 | 166572篇 |
免费 | 13625篇 |
国内免费 | 17773篇 |
专业分类
化学 | 94781篇 |
晶体学 | 2218篇 |
力学 | 15745篇 |
综合类 | 2075篇 |
数学 | 39670篇 |
物理学 | 43481篇 |
出版年
2024年 | 198篇 |
2023年 | 1345篇 |
2022年 | 2185篇 |
2021年 | 4008篇 |
2020年 | 4080篇 |
2019年 | 3978篇 |
2018年 | 3492篇 |
2017年 | 4832篇 |
2016年 | 5268篇 |
2015年 | 4483篇 |
2014年 | 6823篇 |
2013年 | 11864篇 |
2012年 | 10107篇 |
2011年 | 9723篇 |
2010年 | 8346篇 |
2009年 | 10646篇 |
2008年 | 10854篇 |
2007年 | 11136篇 |
2006年 | 9825篇 |
2005年 | 8201篇 |
2004年 | 7514篇 |
2003年 | 6583篇 |
2002年 | 8779篇 |
2001年 | 5356篇 |
2000年 | 4723篇 |
1999年 | 4324篇 |
1998年 | 3869篇 |
1997年 | 3159篇 |
1996年 | 2762篇 |
1995年 | 2522篇 |
1994年 | 2248篇 |
1993年 | 1893篇 |
1992年 | 1854篇 |
1991年 | 1303篇 |
1990年 | 1071篇 |
1989年 | 915篇 |
1988年 | 751篇 |
1987年 | 620篇 |
1986年 | 552篇 |
1985年 | 671篇 |
1984年 | 569篇 |
1983年 | 343篇 |
1982年 | 540篇 |
1981年 | 657篇 |
1980年 | 586篇 |
1979年 | 625篇 |
1978年 | 506篇 |
1977年 | 392篇 |
1976年 | 312篇 |
1973年 | 185篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
11.
12.
移动加热器法(THM)生长碲锌镉晶体时,界面稳定性对晶体生长的质量有很大影响。本文基于多物理场有限元仿真软件Comsol建立了THM生长碲锌镉晶体的数值模拟模型,讨论了Te边界层与组分过冷区之间的关系,对不同生长阶段的物理场、Te边界层与组分过冷区进行仿真研究,最后讨论了微重力对物理场分布的影响,并对比了微重力与正常重力下的生长界面形貌。模拟结果表明,Te边界层与组分过冷区的分布趋势是一致的,在不同生长阶段,流场中次生涡旋的位置会发生移动,从而导致生长界面的形貌随着生长的进行发生变化,同时微重力条件下形成的生长界面形貌最有利于单晶生长。因此,在晶体生长的中前期,对次生涡旋位置的控制和对组分过冷的削弱,是THM生长高质量晶体的有效方案。 相似文献
13.
14.
Sol-gel method has been used for the synthesis of biocompatible superparamagnetic nanoferrites of AFeO2 (A = Li, Na, K, Ca). Structural study of the nanoferrites reveals that LiFeO2 exhibits cubic phase on the other hand NaFeO2, KFeO2, CaFeO2 nanoparticles possess orthorhombic phase. Transmission electron microscopy (TEM) suggests that synthesized nanoferrites are nano-sized with spherical morphology. Optical properties confirm that nanoferrites emit and absorb light in a visible range of the electromagnetic spectrum. International Commission on Illumination (CIE) study discloses that the nanoparticles can be used to produce light of various colors. Magnetic study reveals that the nanoferrites exhibit superparamagnetic nature with high values of saturation magnetization 40.26 emu/g, 41.69 emu/g, 57.16 emu/g, and 43.66 emu/g, respectively for LiFeO2, NaFeO2, KFeO2, and CaFeO2. Biocompatibility study of the nanoferrites has been performed using Sulforhodamine B (SRB) and 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. The reason behind the observed properties and behavior has been discussed. 相似文献
15.
In this article, we construct and analyze a residual-based a posteriori error estimator for a quadratic finite volume method (FVM) for solving nonlinear elliptic partial differential equations with homogeneous Dirichlet boundary conditions. We shall prove that the a posteriori error estimator yields the global upper and local lower bounds for the norm error of the FVM. So that the a posteriori error estimator is equivalent to the true error in a certain sense. Numerical experiments are performed to illustrate the theoretical results. 相似文献
16.
A nonlinear time-domain simulation model for predicting two-dimensional vortex-induced vibration (VIV) of a flexibly mounted circular cylinder in planar and oscillatory flow is presented. This model is based on the utilization of van der Pol wake oscillators, being unconventional since wake oscillators have typically been applied to steady flow VIV predictions. The time-varying relative flow–cylinder velocities and accelerations are accounted for in deriving the coupled hydrodynamic lift, drag and inertia forces leading to the cylinder cross-flow and in-line oscillations. The system fluid–structure interaction equations explicitly contain the time-dependent and hybrid trigonometric terms. Depending on the Keulegan–Carpenter number (KC) incorporating the flow maximum velocity and excitation frequency, the model calibration is performed, entailing a set of empirical coefficients and expressions as a function of KC and mass ratio. Parametric investigations in cases of varying KC, reduced flow velocity, cylinder-to-flow frequency ratio and mass ratio are carried out, capturing some qualitative features of oscillatory flow VIV and exploring the effects of system parameters on response prediction characteristics. The model dependence of hydrodynamic coefficients on the Reynolds number is studied. Discrepancies and limitations versus advantages of the present model with different feasible solution scenarios are illuminated to inform the implementation of wake oscillators as a computationally efficient prediction model for VIV in oscillatory flows. 相似文献
17.
18.
In this work, a vanillin complex is immobilized onto MCM-41 and characterized by FT-IR, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, thermogravimetric analysis, and BET techniques. This supported Schiff base complex was found to be an efficient and recoverable catalyst for the chemoselective oxidation of sulfides into sulfoxides and thiols into their corresponding disulfides (using hydrogen peroxide as a green oxidant) and also a suitable catalyst for the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives in water at 90°C. Using this protocol, we show that a variety of disulfides, sulfoxides, and 2,3-dihydroquinazolin-4(1H)-one derivatives can be synthesized in green conditions. The catalyst can be recovered and recycled for further reactions without appreciable loss of catalytic performance. 相似文献
19.
20.
应用互补集成经验模态分解(CEEMD)方法对香港1997―2018年的住宅价格月度数据进行了分解,将经过重构后的数据分成高频序列、低频序列与残差项。将BP多断点检测应用于低频序列,并结合样本时段内的重大事件进行实证分析。结果表明:1997年亚洲金融风暴对房价的影响大于2008年金融危机;外部经济体的救市政策间接地影响香港房价;在经济不景气的大环境下“孙九招”政策没有立即见效;资本投资者入境计划、住房供给调整与按揭贷款调整对房价的影响较为显著;税收调整对房价影响不显著、对交易量影响显著;SARS爆发使住宅价格下降约1%。 相似文献