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91.
Gao-Yuan Chen John A. Cuculo Paul A. Tucker 《Journal of Polymer Science.Polymer Physics》1992,30(6):557-561
Nozzle profiles capable of generating constant extensional strain rates are termed hyperbolic dies. When used in polymer extrusion, they exhibit greater potential in inducing and retaining polymer molecular orientation than conventional capillary dies. Most mathematical expressions found in the literature involve several processing variables in describing and designing such nozzle profiles. This report reveals that a hyperbolic die profile, although rather complicated, can be expressed with equations in terms of two ordinary geometrical parameters—the exit diameter and the hyperbolic length. This finding greatly simplifies the design procedure of hyperbolic dies. The extensional strain rate of a hyperbolic die can be related to the length-to-diameter ratio for any given exit diameter. Examples of various types of die profiles are presented and their constant extensional strain-rate characteristics are discussed. 相似文献
92.
Ulf Ryde 《Journal of computer-aided molecular design》1996,10(2):153-164
Summary The coordination number of the catalytic zinc ion in alcohol dehydrogenase has been studied by integrated ab initio quantum-chemical and molecular mechanics geometry optimisations involving the whole enzyme. A four-coordinate active-site zinc ion is 100–200 kJ/mol more stable than a five-coordinate one, depending on the ligands. The only stable binding site for a fifth ligand at the zinc ion is opposite to the normal substrate site, in a small cavity buried behind the zinc ion. The zinc coordination sphere has to be strongly distorted to accommodate a ligand in this site, and the ligand makes awkward contacts with surrounding atoms. Thus, the results do not support proposals attributing an important role to five-coordinate zinc complexes in the catalytic mechanism of alcohol dehydrogenase. The present approach makes it possible also to quantify the strain induced by the enzyme onto the zinc ion and its ligands; it amounts to 42–87 kJ/mol for four-coordinate active-site zinc ion complexes and 131–172 kJ/mol for five-coordinate ones. The four-coordinate structure with a water molecule bound to the zinc ion is about 20 kJ/mol less strained than the corresponding structure with a hydroxide ion, indicating that the enzyme does not speed up the reaction by forcing the zinc coordination sphere into a structure similar to the reaction intermediates. 相似文献
93.
R. J. Emrich 《Shock Waves》1996,5(6):327-339
Recollections of activities in the Physics Department of Princeton University leading to the construction and use of the SHOCK
TUBE are recorded. Walker Bleakney was the leader of these activities from 1940 to 1979, and his methods and attitude are
described. Original interferograms made at Princeton show some results obtained. 相似文献
94.
A procedure for numerical investigation of nonaxisymmetric temperature fields and the elastic stress-strain state of laminated rotational bodies of cylindrically and rectilinearly orthotropic materials under nonisothermal loading is proposed. The deformation of orthotropic materials is described by the equations of anisotropic elasticity theory. The equations of state are written in the form of Hookes law for homogeneous materials, with additional terms which take into account the thermal deformation, changes in the mechanical properties of materials in the circumferential direction, and their dependence on temperature. A semianalytic finite-element method in combination with the method of successive approximations is used. An algorithm for numerical solution of the corresponding nonlinear boundary problem is elaborated, which is realized as a package of applied FORTRAN programs. Some numerical results are presented.Translated from Mekhanika Kompozitnykh Materialov, Vol. 40, No. 6, pp. 731–752, November–December, 2004. 相似文献
95.
96.
97.
针对光纤光栅应变传感器接收信号弱且信噪比低这一问题,提出了应用DSP技术来抑制噪声,提高Bragg峰值波长检测精度的方法.实验结果表明所设计的498阶Kaiser窗低通FIR数字滤波器能够显著提高光纤光栅应变传感器的信号检测精度.采用DSP技术可以较好地解决光纤光栅传感器的波长解调这一技术难题. 相似文献
98.
Alena Juríková Kornel Csach Jozef Miškuf Václav Ocelík 《Central European Journal of Physics》2007,5(2):177-187
Creep strain recovery and structural relaxation of the amorphous metallic glass Fe40Ni41B19 after longtime loading at different annealing temperatures below the glass transition temperature have been studied using
anisothermal differential scanning calorimetry (DSC) and dilatometry (TMA). It has been demonstrated that structural relaxation
effects depend on the stress-annealing temperature of the amorphous ribbon. The structural relaxation states of the amorphous
ribbon annealed at different temperatures under and without applied stress have been compared. The activation energy spectra
were calculated from the anisothermal dilatometric measurements using the modern method based on the Fourier transformation
technique. The influence of the annealing temperature on the shape of creep strain recovery spectra has been analyzed.
相似文献
99.
100.
Xianghua Li Chunsheng Zhao Jun Lin Shenfang Yuan 《Optics and Lasers in Engineering》2007,45(7):819-826
The performance analysis of three-dimensional (3-D) braided composites is made difficult by their complex and interlacing structure, and is still under development. To get complete first-hand data on the material parameters of these composites, co-braided optical fiber sensors (OFS) can be used to measure the internal strain. This information is helpful for subsequent stiffness predictions and failure analysis. This paper introduces a method of incorporating OFS into braided composites, and establishes a constitutive theoretical model for the hybrid material. Experiments are conducted to measure the internal strain of specimens under tension, and the results are compared to theoretical predictions. 相似文献