全文获取类型
收费全文 | 9979篇 |
免费 | 892篇 |
国内免费 | 1064篇 |
专业分类
化学 | 7857篇 |
晶体学 | 79篇 |
力学 | 1657篇 |
综合类 | 124篇 |
数学 | 722篇 |
物理学 | 1496篇 |
出版年
2024年 | 16篇 |
2023年 | 116篇 |
2022年 | 266篇 |
2021年 | 279篇 |
2020年 | 369篇 |
2019年 | 339篇 |
2018年 | 352篇 |
2017年 | 537篇 |
2016年 | 583篇 |
2015年 | 491篇 |
2014年 | 527篇 |
2013年 | 687篇 |
2012年 | 646篇 |
2011年 | 629篇 |
2010年 | 545篇 |
2009年 | 539篇 |
2008年 | 464篇 |
2007年 | 548篇 |
2006年 | 510篇 |
2005年 | 435篇 |
2004年 | 406篇 |
2003年 | 322篇 |
2002年 | 309篇 |
2001年 | 247篇 |
2000年 | 253篇 |
1999年 | 214篇 |
1998年 | 186篇 |
1997年 | 191篇 |
1996年 | 206篇 |
1995年 | 142篇 |
1994年 | 128篇 |
1993年 | 66篇 |
1992年 | 54篇 |
1991年 | 47篇 |
1990年 | 48篇 |
1989年 | 32篇 |
1988年 | 21篇 |
1987年 | 21篇 |
1986年 | 27篇 |
1985年 | 23篇 |
1984年 | 20篇 |
1983年 | 12篇 |
1982年 | 31篇 |
1981年 | 14篇 |
1980年 | 11篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1959年 | 4篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
51.
52.
Mindlin板几何非线性分析的附加内部剪应变法 总被引:1,自引:0,他引:1
本文在几何非线性分析的Mindlin板元中引入单元附加内部剪应变,有效地解决了薄板情况下的剪切自锁问题.文中导出了相应的能量相容条件,给出了有限元非线性列式的全过程及有关簿板及中厚板大挠度问题的数值结果. 相似文献
53.
54.
Analytical expressions for the stresses near a circular hole in a transversely isotropic shallow spherical shell under uniform pressure are derived. The form of the solution depends on the range of change in the compliance to transverse shear. The influence of the relative radius of the hole and the compliance to transverse shear on the stress concentration is analyzed.__________Translated from Prikladnaya Mekhanika, Vol. 40, No. 12, pp. 99–106, December 2004. 相似文献
55.
Yoshitomo Ono Naoyuki Kawashima Hiroto Kudo Tadatomi Nishikubo Takabumi Nagai 《Journal of polymer science. Part A, Polymer chemistry》2007,45(14):2978-2988
The ring‐opening copolymerization of a glycidyl ester derivative having a benzophenone group and the donor–acceptor norbornadiene (D‐A NBD) dicarboxylic acid, 5‐(4‐methoxyphenyl)‐1,4,6,7,7‐pentamethyl‐2,5‐norbornadiene‐2,3‐dicarboxylic acid, monoglycidyl ester derivatives with D‐A NBD dicarboxylic anhydride using tetraphenylphosphonium bromide as a catalyst proceeded smoothly to give novel self‐photosensitizing NBD polymers in good yields. The molecular weight of these polyesters was about 4,000, and lower than that of analogous NBD polymers having no benzophenone group. All the synthesized NBD polymers isomerized smoothly to the corresponding quadricyclane (QC) polymers upon UV irradiation in tetrahydrofuran (THF) solution and in the film state. The rate of the photoisomerization of the D‐A NBD moieties in these polymers was higher than that of the D‐A NBD moieties in the polymer having no photosensitizing group. Furthermore, the rate of the photoisomerization of the D‐A NBD moieties in these polymers was also higher than that of the NBD polymer with low molecular weight photosensitizer in dilute solution. The photo‐irradiated polymers having QC moieties released thermal energies of 146–180 J/g. The D‐A NBD moieties contained in these NBD polymers possessed fair to good fatigue resistance. The degradation of the NBD moieties in these polymers was 15–30% after 50 repeated cycles of interconversion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2978–2988, 2007 相似文献
56.
冲击载荷下剪切断裂研究 总被引:1,自引:0,他引:1
利用Hopkinson压杆技术对单边平行双裂纹试样倒向加载,在较大的加载率范围,对Ti6Al4V钛合金和40CrNiMoA两种材料的动态剪切断裂行为进行了研究.实验结果表明:存在两类韧性剪切断裂模式,即常规的韧性剪切型断裂和绝热剪切断裂.常规剪切型断裂模式的断裂韧性KⅡd随加载率的提高而增大,而绝热剪切型的断裂韧性KⅡd则随加载率的提高而减小,并且,当加载率增大至某一临界值时,常规的韧性剪切断裂模式将转变为绝热剪切断裂破坏模式. 相似文献
57.
D. Kaneko T. Narita J. P. Gong Y. Osada J. Ando K. Yamamoto S. Ohnishi V. V. Yaminsky 《Journal of Polymer Science.Polymer Physics》2003,41(22):2808-2815
The effect of the shear flow on the thickness change of a polyelectrolyte membrane grafted onto a glass substrate was directly investigated with a flow cell combined with a confocal laser scanning microscope. The membrane thickness decreased proportionally to an increase in the shear stress of the flow when the shear rate exceeded a critical value of 1 s?1. The higher the ionic strength was of the fluid, the greater the thinning effect was. The correlation between the critical shear rate and the relaxation of the polymer in the gel membrane was examined. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2808–2815, 2003 相似文献
58.
Guey‐Sheng Liou Hung‐Yi Lin Yu‐Lun Hsieh Yi‐Lung Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4921-4932
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007 相似文献
59.
We study the vessel arrival process in bulk ports handling either cargo containers or minerals. Then we introduce the SHIP/G/1 queue to be able to study the queueing behavior at the port. We present approximations for the asymptotic probabilities of delay and the number of vessels at the port. Numerical examples show the accuracy of the approximations. In appendices, we provide details of the analysis of the number of vessels at the port and the correlation properties of the vessel arrival process. 相似文献
60.
This paper deals with the analysis of an M/M/c queueing system with setup times. This queueing model captures the major characteristics of phenomena occurring in production
when the system consists in a set of machines monitored by a single operator. We carry out an extensive analysis of the system
including limiting distribution of the system state, waiting time analysis, busy period and maximum queue length.
AMS subject classification: 90B22, 60K25 相似文献