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81.
K. Yanada M. Sakairi T. Kikuchi Y. Oya Y. Kojima 《Surface and interface analysis : SIA》2010,42(4):189-193
An in situ artificial micro‐pit fabrication method with an area selective electrochemical measurement technique was applied to investigate the effect of the geometry of artificially formed pits on their localized corrosion behavior in anodized 1000 series aluminum. This technique enables the fabrication of artificial micro‐pits with different aspect ratios (pit depth/pit diameter) in solutions. The aspect ratios of the fabricated artificial micro‐pits in this experiment could be varied from 0.13 to 1.83 by controlling the irradiation time of the focused pulsed YAG laser beam. By applying a constant potential to the final laser‐beam‐irradiated spot in chloride environments, localized dissolution occurred only at the laser beam irradiated area, because the anodic oxide film acted as an insulator. The corrosion current and charge increase with increasing aspect ratio at any applied potential. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Z.H. Zhang X.L. Zhong H. Liao F. Wang J.B. Wang Y.C. Zhou 《Applied Surface Science》2011,257(17):7461-7465
In the present work, X-ray photoelectron spectroscopy (XPS) was used to investigate the composition depth profiles of Bi3.15Nd0.85Ti3O12 (BNT) ferroelectric thin film, which was prepared on Pt(1 1 1)/Ti/SiO2/Si(1 0 0) substrates by chemical solution deposition (CSD). It is shown that there are three distinct regions formed in BNT film, which are surface layer, bulk film and interface layer. The surface of film is found to consist of one outermost Bi-rich region. High resolution spectra of the O 1s peak in the surface can be decomposed into two components of metallic oxide oxygen and surface adsorbed oxygen. The distribution of component elements is nearly uniform within the bulk film. In the bulk film, high resolution XPS spectra of O 1s, Bi 4f, Nd 3d, Ti 2p are in agreement with the element chemical states of the BNT system. The interfacial layer is formed through the interdiffusion between the BNT film and Pt electrode. In addition, the Ar+-ion sputtering changes lots of Bi3+ ions into Bi0 due to weak Bi-O bond and high etching energy. 相似文献
84.
《Surface and interface analysis : SIA》2003,35(3):251-255
From large‐scale production, two monocrystalline silicon solar cells of different quality, i.e. ISC = 3.0 A (good cell) and ISC = 1.6 A (bad cell), have been studied by XPS combined with 4 keV Ar+ depth profiling. Depth profiling was carried out through the anti‐reflection coating (TiO2), the passivation layer (SiO2) and up into the phosphorus‐doped silicon bulk. At the solar cell surface the elemental composition is similar for both cells, although the bad one presents slightly more carbon, phosphorus and lead but less silver than the good one. During profiling, carbon and silver could be followed by XPS. It was found that the carbon content is distinguishably higher in the bad cell than in the good one. Furthermore, it was found that silver atoms have not diffused in the same way in both cells. Only the good cell presents silver atoms up into the silicon bulk. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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为探索钨合金柱形弹超高速撞击水泥砂浆靶的侵彻深度随撞击速度变化规律,利用二级轻气炮开展了?3.45 mm×10.5 mm的克级93 W钨合金柱形弹以1.82~3.66 km/s的速度撞击水泥砂浆靶的实验,利用CT图像诊断技术获得了侵彻深度和残余弹长随撞击速度的变化规律,对超高速撞击过程进行了数值模拟,结合数值模拟结果进一步分析了超高速撞击物理过程。结果表明:(1)超高速撞击条件下成坑是弹坑+弹洞型;(2)侵深-速度曲线呈现先增大后减小的现象,在弹速2.6 km/s附近存在侵彻深度极大值,约为8.5倍弹长,相对于中低速侵彻的深度并没有显著优势。(3)通过基于数值模拟得到的弹靶界面压力时程曲线将侵彻过程分为4个阶段,其中准定常侵彻阶段和第三侵彻阶段是决定总侵深的主要阶段。(4)随撞击速度增加,弹体侵蚀逐渐剧烈,此时准定常侵彻阶段的侵深变化不大,而第三侵彻阶段中的刚体侵彻部分大幅降低,导致总侵深大幅降低,使总侵深曲线呈现先增大后减小的现象。 相似文献
88.
气固射流床射流深度的研究 总被引:7,自引:2,他引:7
在300×51×2600mm的二维射流床中,采用多路毕托管测试系统,对包括三种双组份混合物在内的五种物料的射流深度进行了考察。结果表明,射流管径、射流气速对射流深度都有影响,本文尤其考察了环隙气量与射流深度的关系,发现在同样的射流气速下,环隙气速增大则射流深度降低,得出了综合各种影响因素的关联式。 相似文献
89.
Effects of some parameters on the divertor plasma sheath characteristics and fuel retention in castellated tungsten tile gaps 下载免费PDF全文
Castellation of plasma facing components is foreseen as the best solution for ensuring the lifetime of future fusion devices. However, the gaps between the resulting surface elements can increase fuel retention and complicate fuel removal issues. To know how the fuel is retained inside the gaps, the plasma sheath around the gaps needs to be understood first. In this work, a kinetic model is used to study plasma characteristics around the divertor gaps with the focus on the H+ penetration depth inside the poloidal gaps, and a rate-theory model is coupled to simulate the hydrogen retention inside the tungsten gaps. By varying the magnetic field strength and plasma temperature, we find that the H+ cyclotron radius has a significant effect on the penetration depth. Besides, the increase of magnetic field inclination angle can also increase the penetration depth. It is found in this work that parameters as well as the penetration depth strongly affect fuel retention in tungsten gaps. 相似文献
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