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991.
本文研究无穷凹角区域上一类各向异性问题的自然边界元与有限元耦合法.利用自然边界归化原理,获得圆弧或椭圆弧人工边界上的自然积分方程,给出了耦合的变分形式及其数值方法,以及逼近解的收敛性和误差估计,最后给出了数值例子,以示方法的可行性和有效性. 相似文献
992.
993.
Shengying Qian Jianfeng Huang Weihong Guo 《Journal of Macromolecular Science: Physics》2013,52(3):453-466
A new method was applied to modify the surface activity of virginal carbon black (VCB). LA‐57, one kind of hindered amine light stabilizer, was adsorbed onto the carbon black surface through a strong shear force induced by the screws of a HAAKE internal mixer. The modified carbon black (MCB) was characterized by FT‐IR and thermogravimetric analysis (TGA). The bound rubber content of the natural rubber (NR) compounded with MCB and VCB varied with the fraction of LA‐57 on the MCB surface. The nonlinear effect at small strains, generally referred as the Payne effect, was investigated in the rubber compounds based on the different bound rubber contents. The NR compound containing the lowest bound rubber content had an obvious Payne effect. Based on the bound rubber content, the types of filler network varied from direct contact mode to the joint rubber shell mechanism. 相似文献
994.
995.
Yanfen Lin Anqiang Zhang Jiannan Sun Lianshi Wang 《Journal of Macromolecular Science: Physics》2013,52(11):1494-1507
Using the characteristics of silica sol dispersing well in water and easy formation of silica gel when the silica sol is heated, by mixing a system of concentrated natural rubber latex and silica sol, the silica sol can in-situ generate SiO2 particles when heated. After coagulation of the mixed system, natural rubber/nanosilica composites C(NR/nSiO2) were obtained. The composites C(NR/nSiO2) and their vulcanizates were studied using a rubber processing analyzer (RPA), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). The influence of silica contents on the C(NR/nSiO2) vulcanizates mechanical properties, cross-linking degree, Payne effect, dissipation factor (tanδ), and the particle size and dispersion of SiO2 in NR were investigated. The results obtained were compared with the NR/SiO2 composites based on traditional dry mixing of bale natural rubber and precipitated silica (white carbon black). The results showed that when using a sulfur curing system with a silica coupling agent (Si69) in C(NR/nSiO2), the vulcanizate had better mechanical properties, higher wet resistance, and lower rolling resistance than those without Si69. In the composites C(NR/nSiO2) and their vulcanizates, the SiO2 particles’ average grain diameter was 60 nm, and the good-dispersion of the in-situ generated SiO2 in the rubber matrix were a significant contribution to the satisfactory properties of C(NR/nSiO2) composites and their vulcanizates. 相似文献
996.
Elena Tarabukina Eugenia Fagadar-Cosma Corina Enache Natalia Zakharova Mihaela Birdeanu 《Journal of Macromolecular Science: Physics》2013,52(8):1092-1106
Molecular properties and aggregation behavior of a polysiloxane with grafted side chain groups consisting of asymmetrical hydroxy-functionalized porphyrin were studied in dilute solutions. In order to understand the mechanism of aggregation of the polymeric porphyrin derivatives, several analyses of chloroform solutions were performed permitting comparison of the data obtained by means of different techniques. Molar mass and hydrodynamic size of the macromolecules were obtained using the methods of analytical ultracentrifugation, isothermal translational diffusion, and viscometry. Long distance interactions between macromolecules in dilute solutions were detected with static light scattering. With increasing the concentration of the solutions, the electronic and fluorescence spectra bands assigned to generation of H and J aggregates became apparent. The organization of aggregates, which seemed to be favored by chloroform, was visualized by atomic force microscopy images that displayed sponge-like morphology, small triangular particles, characteristic of H aggregates, and nano or micro-structured ring geometries obtained by the side-by-side J-process, coexisting together. 相似文献
997.
R. Trettin T. Grischek G. Strauch G. Malleean W. Nestler 《Isotopes in environmental and health studies》2013,49(4):331-350
Abstract Flow times and infiltration behaviour are very important for water extraction from riverbank filtration. Both the chloride content and the isotopic composition of oxygen (δ18O) were found to be suitable indicators for the conditions encountered in the middle course of the River Elbe near Torgau. The ranges for Elbe water were measured to be 20–43 mg Cl/l (1995-97) and -11 to -8.5‰ δ18O (1993-97). Both methods permitted flow-time spectra at two adjacent sampling profiles incorporating river and production wells to be obtained, indicating the preferred flow paths and the vertical extension of the riverbank filtrate plume in the aquifer. However, since the differences between the mean values for river water and regional groundwater were too small the percentage of river water abstracted from production wells could not be calculated. 相似文献
998.
R. Bol N. J. Ostle C. Friedrich W. Amelung I. Sanders 《Isotopes in environmental and health studies》2013,49(1-2):97-109
Abstract Understanding the carbon (C) cycle in grassland pasture systems requires more information about the fate of decomposing dung material within the soil. In this soil lysimeter study we successfully applied the natural 13C abundance labelling technique to trace dung-C within a temperate grassland soil. Dung was collected from beef steers fed on either maize (a C4 plant) or perennial ryegrass (a C3 plant) silages, and applied to a freely draining (C3) grassland soil. Leachates were collected from soil lysimeters (0–2.5) and (0–10 cm soil depth) to determine the organic carbon and 13C content of < 0.7 μm filtered solution. Leachates were taken from (i) control, no dung added, (ii) C3 dung and (iii) C4 dung amended soil. Results showed that, (i) the addition of dung resulted in a tenfold increase in C lost from the lysimeters in drainage waters, (ii) up to 50% of the C present in the leachates was ‘native’ soil C and (iii) the application of dung produced a ‘priming’ effect. Further work is required to verify; (i) whether increased leaching of native C following dung application is a ‘true priming’ phenomenon, or merely the result of ‘displacement’ or ‘pool substitution’ of soil C, and (ii) the precise conditions and mechanisms under which organic amendments induce a true ‘priming’ effect in grassland and other agricultural soils. 相似文献
999.
Bogdan P. Onac Kali Pace-Graczyk Viorel Atudirei 《Isotopes in environmental and health studies》2013,49(2):149-161
Stable isotopes of hydrogen and oxygen were used to examine how the isotopic signal of meteoric water is modified as it travels through soil and epikarst into two caves in Florida. Surface and cave water samples were collected every week from February 2006 until March 2007. The isotopic composition of precipitation at the investigated sites is highly variable and shows little seasonal control. The δ18O vs. δ2H plot shows a mixing line having a slope of 5.63, suggesting evaporation effects dominate the isotopic composition of most rainfall events of less than 8 cm/day, as indicated by their low d-excess values. The δ18O values of the drip water show little variability (<0.6‰), which is loosely tied to local variations in the seasonal amount of precipitation. This is only seen during wintertime at the Florida Caverns site. The lag time of over two months and the lack of any relationship between rainfall amount and the increase in drip rate indicate a dominance of matrix flow relative to fracture/conduit flow at each site. The long residence time of the vadose seepage waters allows for an effective isotopic homogenisation of individual and seasonal rainfall events. We find no correlation between rainfall and drip water δ18O at any site. The isotopic composition of drip water in both caves consistently tends to resemble the amount-weighted monthly mean rainfall input. This implies that the δ18O of speleothems from these two caves in Florida cannot record seasonal cycle in rainfall δ18O, but are suitable for paleoclimate reconstructions at inter-annual time scales.? 相似文献
1000.
Selected silty “summer” and argillaceous “winter” layers of profiles of the rhythmically bedded glacio-lacustrine ice-marginal lake sediment of the Dehlitz-Leipzig varved clay (Leipziger Tieflandsbucht, Central Germany) have been examined for isotope composition (18O/16O, 13C/12C) of carbonate and organic fraction. In addition, mineralogical and grain size compositions were determined. The results show 1) a change in source of carbonate sediment (provenance) through time; 2) the oxygen isotope ratios differed between the “summer” and “winter” layers of varves couplets due to different rates of sedimentation; 3) anoxic events occurred in the lake; 4) carbon isotope ratios suggest organics in lake sediments which were derived from land and the primary productivity was low in the lake itself. In the study of cold-climatic lake sediments, isotope investigations can efficiently be used as additional paleosedimentological and facies indicators. 相似文献