全文获取类型
收费全文 | 502篇 |
免费 | 55篇 |
国内免费 | 30篇 |
专业分类
化学 | 82篇 |
晶体学 | 2篇 |
力学 | 109篇 |
综合类 | 8篇 |
数学 | 156篇 |
物理学 | 230篇 |
出版年
2023年 | 5篇 |
2022年 | 4篇 |
2021年 | 15篇 |
2020年 | 18篇 |
2019年 | 8篇 |
2018年 | 18篇 |
2017年 | 12篇 |
2016年 | 18篇 |
2015年 | 17篇 |
2014年 | 17篇 |
2013年 | 32篇 |
2012年 | 27篇 |
2011年 | 32篇 |
2010年 | 21篇 |
2009年 | 32篇 |
2008年 | 35篇 |
2007年 | 24篇 |
2006年 | 28篇 |
2005年 | 26篇 |
2004年 | 15篇 |
2003年 | 20篇 |
2002年 | 13篇 |
2001年 | 12篇 |
2000年 | 9篇 |
1999年 | 15篇 |
1998年 | 7篇 |
1997年 | 10篇 |
1996年 | 13篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 5篇 |
1991年 | 12篇 |
1990年 | 2篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有587条查询结果,搜索用时 12 毫秒
581.
液滴在润湿梯度表面运动的分子动力学模拟 总被引:1,自引:0,他引:1
本文进行了液滴在不同润湿梯度表面运动的分子动力学模拟,通过改变Lennard-Jones(LJ)势参数来实现表面的不同润湿性。模拟结果表明在润湿梯度差为10°的界面上,疏水表面的液滴运动更快,达到最终界面所需时间最短,并且液滴运动方向距离最远。当润湿梯度差为20°和30°时,液滴在疏水表面工况的运动速度与从疏水跨越到亲水的工况之间的差距越来越小,并且液滴在从疏水跨越到亲水的工况达到了最远的运动距离。同时,润湿梯度差的增加也引起了液滴运动速度的增大。 相似文献
582.
Qizhen Hong Massimiliano Bartolomei Cecilia Coletti Andrea Lombardi Quanhua Sun Fernando Pirani 《Molecules (Basel, Switzerland)》2021,26(23)
Knowledge of energy exchange rate constants in inelastic collisions is critically required for accurate characterization and simulation of several processes in gaseous environments, including planetary atmospheres, plasma, combustion, etc. Determination of these rate constants requires accurate potential energy surfaces (PESs) that describe in detail the full interaction region space and the use of collision dynamics methods capable of including the most relevant quantum effects. In this work, we produce an extensive collection of vibration-to-vibration (V–V) and vibration-to-translation/rotation (V–T/R) energy transfer rate coefficients for collisions between CO and N molecules using a mixed quantum-classical method and a recently introduced (A. Lombardi, F. Pirani, M. Bartolomei, C. Coletti, and A. Laganà, Frontiers in chemistry, 7, 309 (2019)) analytical PES, critically revised to improve its performance against ab initio and experimental data of different sources. The present database gives a good agreement with available experimental values of V–V rate coefficients and covers an unprecedented number of transitions and a wide range of temperatures. Furthermore, this is the first database of V–T/R rate coefficients for the title collisions. These processes are shown to often be the most probable ones at high temperatures and/or for highly excited molecules, such conditions being relevant in the modeling of hypersonic flows, plasma, and aerospace applications. 相似文献
583.
Time‐dependent wave packet resonant scattering for the double square barrier has been studied in terms of Bohm quantum trajectories. The high transmission probability for the wave packet with a resonant energy can be explained by the behavior of the quantum trajectories under the influence of the relatively slow formation of a node within the first barrier. This node splits the trajectories into reflected and transmitted components. During this stage, many particle trajectories pass through the double‐barrier region and contribute to the transmitted part of the wave packet. Due to the transient nature of the nodes, trajectories in the reflected wave packet bunch together between the nodes for a finite period of time so that temporary structure (localization of particles and accompanying increase in the probability density) develops on small length scales. These calculations also show that the particles gain high momentum near the nodal points, and they reach a uniform momentum distribution after transmitting the barrier region. We have found that the presence of a node between the two barriers influences the different lifetimes of the quasi‐bound states. © 2001 John Wiley & Sons, Inc. Int J Quant Chem 81: 206–213, 2001 相似文献
584.
Recent progress in the field of single‐ and two‐photon nanofabrication, both 2‐ and 3‐dimensional, in photopolymerizable resins and in films of photoisomerizable azopolymers are reviewed. The basic processes as well as technological advances and applications of nanofabrication by light are discussed. Recent advances and achievements in polymer photomechanics and light‐activated molecular movement in azopolymers are also reviewed. 相似文献
585.
学历案是关于学习经历或过程的方案,利用学历案构建一个“以学为主、以教促学”的教学模式,改变了教师的主导地位,凸显了学生的主体地位。笔者尝试借助学历案,以花青素为载体,通过生活化的化学实验,将化学平衡常数K作为分析工具,进行证据推理,以外界条件使花青素溶液颜色变化,到花青素的工业合成为明线;以化学平衡移动的本质到化学平衡移动原理的应用为暗线,双线结合,学生自主建构“化学平衡移动”的认知模型,从而促进深度学习的发生。 相似文献
586.
In this paper, the cavitation bubble dynamics near two spherical particles of the same size are investigated theoretically and experimentally. According to the Weiss theorem, the flow characteristics and the Kelvin impulse are obtained and supported by the sufficient experimental data. In terms of the initial bubble position, the bubble size and the distance between the two particles, the collapse morphology and the movement characteristics of the bubble are revealed in detail. The main findings include: (1) Based on a large number of experimental results, it is found that the Kelvin impulse theoretical model established in this paper can effectively predict the movement characteristics of the cavitation bubble near two particles of the same size. (2) When the initial bubble position is gradually away from the particles along the horizontal symmetry axis near two particles of the same size, the movement distance of the bubble centroid in the first period increases first and then decreases. (3) When the initial position of the bubble centroid is at the asymmetric position near the two particles, the movement direction of the bubble centroid is biased towards the particle closer to the bubble, but not towards the center of this particle. 相似文献
587.
Exploring affordances and limitations of between-group movement in elementary mathematics classrooms
In this exploratory study, we examine how between-group movement, as an autonomy-promoting practice, might incentivize or disincentivize sixth-grade students’ engagement in two mathematical practices: (1) making sense of problems and persevering in solving them; and (2) constructing viable arguments and critiquing the reasoning of others. Between-group movement refers to a pedagogical strategy wherein teachers allow groups to physically move within the classroom while problem-solving to discuss strategies, ask for help, or check their work with other groups. Exploring both the affordances and limitations of between-group movement, we found that between-group movement supported groups to construct viable justifications, among other sense-making mathematical practices. However, we also found that some groups over-scaffolded during between-group conversations which disincentivized meaningful engagement in mathematical practices. Furthermore, between-group movement revealed some equity concerns in relation to status-based privileges. The findings imply that between-group movement can be a constructive pedagogical practice under specific conditions. 相似文献