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161.
We proposed a novel kinetic energy decomposition analysis based on information theory. Since the Hirshfeld partitioning for electron densities can be formulated in terms of Kullback–Leibler information deficiency in information theory, a similar partitioning for kinetic energy densities was newly proposed. The numerical assessments confirm that the current kinetic energy decomposition scheme provides reasonable chemical pictures for ionic and covalent molecules, and can also estimate atomic energies using a correction with viral ratios. 相似文献
162.
H. DagistanliR.H. Mutlu 《Radiation Physics and Chemistry》2012,81(3):240-241
The occupation numbers of the 3d transition metals are calculated as a function of pressure by means of the linear muffin-tin-orbital method. This data is used with the multiconfiguration Dirac-Fock (MCDF) X-ray intensity ratios (R) to estimate the variation of the intensity ratios of 3d metals with pressure. It is found that R decreases with pressure for the early 3d metals whereas it increases for the heavier 3d transition metals. 相似文献
163.
There is no universal method to perform dynamic analysis on solid rubber anti-vibration systems. In this article, an equivalent damping ratio is introduced to account for rubber hysteresis using a resilience experiment. A new concept, NFR (Natural Frequency Region), is defined for dynamic evaluation based on natural characteristics of a rubber anti-vibration system itself. Two typical industrial products were selected to verify the proposed NFR approach. The verification procedure involves three parts: natural frequencies, harmonic spectra and impact responses. The dynamic responses from both simulation and experiment have been compared and have not only demonstrated that the proposed approach is reliable but that it could also be used to guide the design of rubber anti-vibration systems in industry. The key points for applying this approach are also presented through the verification procedure. 相似文献
164.
Merlin A. Fox Fang-Jie Zhao Steve P. McGrath 《International journal of environmental analytical chemistry》2013,93(5):323-329
A new method for the determination of the 34S/32S ratio of water-extractable sulphate in soil is described. Soils are extracted directly with deionized water, which is evaporated down. The remaining residue is then rehydrated and transferred to tin cups containing an adsorbent and mixed with an oxygen donor (V2O5). Samples are then analysed using a continuous flow isotope ratio mass spectrometer. The new method requires around 10?g soil per determination, compared to much larger amounts (up to kilograms) of soil required for the previous methods. Sample preparation and subsequent analysis is quick and efficient. The method is demonstrated using a number of soils collected from around the world to provide a range of determined δ34S values. The δ34S values of water-extractable sulphur were broadly similar to those of the soil total sulphur. 相似文献
165.
Materials with a negative Poisson's ratio(PR)are called auxetics;they are characterized by expansion/contraction when tensioned/compressed.Given this counterintuitive behavior,they present very particular characteristics and mechanical behavior.Geometrical models have been developed to justify and artificiall reproduce such materials' auxetic behavior.The focus of this study is the exploration of a reentrant model by analyzing the variation in the PR of reentrant structures as a function of geometrical and base material parameters.It is shown that,even in the presence of protruding ribs,there may not be auxetic behavior,and this depends on the geometry of each reentrant structure.Values determined for these parameters can be helpful as approximate reference data in the design and fabrication of auxetic lattices using reentrant geometries. 相似文献
166.
K. Ahrens A. Kramer 《International Journal of Mathematical Education in Science & Technology》2013,44(4):618-624
This paper proves that the ratios of consecutive terms of the m-bonacci sequence converge to a limit φm < 2 and, as m → ∞, these φm converge to 2. Further, it is shown that the generating functions for the m-bonacci sequences converge pointwise to the geometric series. 相似文献
167.
F. Buzek 《Isotopes in environmental and health studies》2013,49(3):70-72
An equipment for the speed δ18O analysis of water samples is described. It used the equilibrium isotopic exchange reaction between water and CO2 gas. Outgasing of samples through capillary without freezing down the samples, together with shaking during the equilibrium time, reduced considerably time for sample preparation. Apparatus is air termostated with hand valves. Measured δ values are not very sensitive to precision of preparation work and reaction conditions, except of temperature. With good temperature control the standard reproducibility of single measurement is better than 0,1‰ 相似文献
168.
In this paper, the extension of an upwind least‐square based meshless solver to high Reynolds number flow is explored, and the properties of the meshless solver are analyzed both theoretically and numerically. Existing works have verified the meshless solver mostly with inviscid flows and low Reynolds number flows, and in this work, we are interested in the behavior of the meshless solver for high Reynolds number flow, especially in the near‐wall region. With both theoretical and numerical analysis, the effects of two parameters on the meshless solver are identified. The first one is the misalignment effect caused by the significantly skewed supporting points, and it is found that the meshless solver still yields accurate prediction. It is a very interesting property and is opposite to the median‐dual control volume based vertex‐centered finite volume method, which is known to give degraded result with stretched triangular/tetrahedral cells in the near‐wall region. The second parameter is the curvature, and according to theoretical analysis, it is found in the region with both large aspect ratio and curvature, and the streamwise residual is less affected; however, the wall‐normal counterpart suffers from accuracy degradation. In this paper, an improved method that uses a meshless solver for the streamwise residual and finite difference for wall‐normal residual is developed. This method is proved to be less sensitive to the curvature and provides improved accuracy. This work presents an understanding of the meshless solver for high Reynolds number flow computation, and the analysis in this paper is verified with a series of numerical experiments. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
169.
Predicting unsteady flows and aerodynamic forces for large displacement motion of microstructures requires transient solution of Boltzmann equation with moving boundaries. For the inclusion of moving complex boundaries for these problems, three immersed boundary method flux formulations (interpolation, relaxation, and interrelaxation) are presented. These formulations are implemented in a 2‐D finite volume method solver for ellipsoidal‐statistical (ES)‐Bhatnagar‐Gross‐Krook (BGK) equations using unstructured meshes. For the verification, a transient analytical solution for free molecular 1‐D flow is derived, and results are compared with the immersed boundary (IB)‐ES‐BGK methods. In 2‐D, methods are verified with the conformal, non‐moving finite volume method, and it is shown that the interrelaxation flux formulation gives an error less than the interpolation and relaxation methods for a given mesh size. Furthermore, formulations applied to a thermally induced flow for a heated beam near a cold substrate show that interrelaxation formulation gives more accurate solution in terms of heat flux. As a 2‐D unsteady application, IB/ES‐BGK methods are used to determine flow properties and damping forces for impulsive motion of microbeam due to high inertial forces. IB/ES‐BGK methods are compared with Navier–Stokes solution at low Knudsen numbers, and it is shown that velocity slip in the transitional rarefied regime reduces the unsteady damping force. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
170.
PurposeStatistical process control (SPC) has been shown to be a suitable tool for medical physicists to monitor quality and keep variability low and within specifications. We report our findings regarding ionisation chamber stability in our department when using a radioactive stability check device (RSCD) and we compare them with similar previously published records, including calibration results.MethodsWe retrospectively studied the stability of a PPC 40 parallel-plate chamber, and two Farmer chambers (FC65-G and FC65-P) by checking them with dedicated RSCDs. We analysed the data following SPC methodology which includes plotting I-MR control charts, monitoring out-of-control observations, calculating process capability ratios (Cp), and estimating conformance to specifications. We also estimated the Cp and adherence to specifications of previously published data.ResultsThe PPC40 chamber hardly went out of the control limits over the whole six-year period assessed. However, Farmer chamber verifications drifted in opposite directions in phase II, and the deviations observed did not agree with their calibration records, which only increased by a maximum of 0.5%. In phase I the most unstable chamber was the FC65-P with a Cp equal to 0.9 at a specification level of ±1%. The PPC40 chamber was stable to within a maximum Cp of 1.3. Several sets of analysed data, including ours and those from other authors, fitted well within these limits: within ±1.9% and ±1.5% for a Cp of 1.5 and 1.33 respectively.ConclusionsSPC with constant long-term RSCD checking gave us a meaningful plot of the instability of our ionisation chambers. Although a period of two years between calibrations should not be surpassed, in the interim this check can conform to specifications of ±1.5%. 相似文献