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71.
《中国物理 B》2021,30(6):66301-066301
Dynamics of hydrogen doped Cu_(50) Zr_(50) glass-forming liquids are investigated by using the newly developed modified embedded atomic method(MEAM) potential based on molecular dynamics simulations. We find that the doping of hydrogen atoms slows down the relaxation dynamics, reduces the fragility of supercooled melts, and promotes the occurrence of glass transitions. The dynamic slowdown is suggested to be closely related to the effect of hydrogen atoms on locally ordered structure of melts. With increasing concentration of hydrogen, the five-fold symmetry associated with Cu-and Zr-centered polyhedrons is lowered, on the other hand, the local order featuring metal hydrides is enhanced. The latter dominates the dynamic behaviors of glass-forming liquids, especially for Zr atoms, and results in the dynamic slowdown. 相似文献
72.
Jongmin Park Dr. Sangmi Oh Prof. Seung Bum Park 《Angewandte Chemie (International ed. in English)》2012,51(22):5259-5259
73.
Abstract The relative toxicity of selected industrial organic chemicals was secured from the literature for the static 48-h Tetrahymena pyriformis 50% population growth impairment and the flow-through 96-h Pimephales promelas 50% mortality endpoints. Chemicals were selected to represent the nonpolar narcosis (aliphatic alcohols and aliphatic ketones) and polar narcosis (anilines and phenols) mechanisms of toxic action. molar volume (MV) and 1-octanol/water partition coefficient (log K ow) data were generated for each chemical. High-quality, log K ow dependent quantitative structure-activity relationships were observed for each chemical class and mechanism of action for both endpoints. The volume fraction (V t) for each chemical in the target phase was determined from the toxicant concentration in the water (toxicity data), the MV, and the target/water partition coefficient (K tw) with K tw considered equal to K ow (1-a). Analyses of target sites, by way of “a” revealed that “a” was constant for a mechanism of action regardless of chemical class, but distinct for a given test system. Mean V t was constant for each mechanism of action regardless of chemical class or test system. These results suggest, at least for reversible physical mechanisms, that volume fraction analyses are significant in determining the mechanism of toxic action of a chemical. 相似文献
74.
75.
Yoshio Kobayashi Tsukasa Shirochi Takafumi Maeda Yusuke Yasuda Toshiaki Morita 《Surface and interface analysis : SIA》2013,45(9):1424-1428
This paper describes a metal–metal bonding technique using metallic Cu nanoparticles prepared in aqueous solution. A colloid solution of metallic Cu particles with a size of 54 ± 15 nm was prepared by reducing Cu2+ (0.01 M (CH3COO)2Cu) with hydrazine (0.6 M) in the presence of stabilizers (5 × 10?4 M citric acid and 5 × 10?3 M cetyltrimethylammonium bromide) in water at room temperature in air. Discs made of metallic materials (Cu, Ni/Cu, or Ag/Ni/Cu) were successfully bonded under annealing at 400 °C and pressurizing at 1.2 MPa for 5 min in H2 gas with help of the metallic Cu particle powder. Shear strength required for separating the bonded discs was 27.9 ± 3.9 for Cu discs, 28.1 ± 4.1 for Ni/Cu discs, and 13.8 ± 2.6 MPa for Ag/Ni/Cu discs. Epitaxial crystal growth promotes on the discs with a good matching for the lattice constants between metallic nanoparticles and metallic disc surfaces, which leads to strong bonding. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
76.
为提高目标强度测量过程中的抗噪声、混响以及浅海多途干扰性能,从军标文件中的目标强度测量方法以及主动式时间反转镜的基本原理出发,经过研究和推演,发现可将基于单阵元的主动式时间反转镜与相关器结合应用于目标强度测量过程,提出了一种新的目标强度测量方法。该方法利用了主动式时间反转镜的抗多途特性,使得测量具有抗多途的性能;利用噪声与信号的不相关特性,算法结合相关器起到了很好的抗随机噪声效果;混响中的体积混响是随机的,算法具有抗体积混响的性能。论文分别从理论仿真和水池实验验证了算法的有效性和正确性。 相似文献
77.
Rapid analysis of phthalic acid esters in environmental water using fast elution gas chromatography with mass spectrometry and adaptive library spectra 下载免费PDF全文
A method for the fast determination of the components in a complex sample by using gas chromatography with mass spectrometry was developed and used for the quantitative analysis of phthalic acid esters in environmental water. In the method, the adaptively corrected mass spectra were used to compensate for the differences between the library spectra and the measured ones in the experiment. The correction was obtained by the iterative transformation of the library spectra using iterative target transformation factor analysis, and the resolution was performed by non‐negative immune algorithm using the corrected spectra. Rapid analysis of 16 phthalic acid esters in water samples was achieved using fast elution gas chromatography with mass spectrometry measurements. The results show that the mass spectra and chromatographic profiles of the phthalic acid esters can be obtained from the overlapping signal of 13 min elution, and accurate quantitative analysis can be obtained. The recoveries of the phthalic acid esters obtained by standard addition are between 90.3 and 107.4%, and the relative standard deviations obtained in repeated measurements are less than 9%. 相似文献
78.
电化学合成氨近年来受到较多关注, 直接的电化学固氮法(NRR)存在产氨来源不明的问题, 而间接的锂式合成氨(LiNR)被认为是一种可行的固氮方案. LiNR的研究多为电沉积锂, 本工作以Li-N2电池体系为基础, 利用电池的放电反应固定N2, 质子源H2O同时参与反应, 理论上提高了Li-N2电池的放电电压. 结合充电反应锂盐分解, 构成了清晰的锂循环方案. 研究发现, 当N2和H2O共同通入电池, 可以实现连续式的NH3生产, 且放电电位与理论值接近. 充放电循环显示, 每个循环均可以产生NH3, 产氨量随循环次数而增加. 该方案可循环利用锂, 对于开发新型的固氮方式有较大的研究与利用价值. 相似文献
79.
Dr. Weihui Ou Junda Shen Dr. Fucong Lyu Xufen Xiao Dr. Binbin Zhou Prof. Jian Lu Dr. Yang Yang Li 《化学:亚洲杂志》2021,16(16):2249-2252
Morphologically and dimensionally controlled growth of Ag nanocrystals has long been plagued by surfactants or capping agents that complicate downstream applications, unstable Ag salts that impaired the reproducibility, and multistep seed injection that is troublesome and time-consuming. Here, we report a one-pot electro-chemical method to fast (∼2 min) produce Ag nanoparticles from commercial bulk Ag materials in a nitric acid solution, eliminating any need for surfactants or capping agents. Their size can be easily manipulated in an unprecedentedly wide range from 35 to 660 nm. Furthermore, the Ag nanoparticles are directly grown on the Ag substrate, highly desirable for promising applications such as catalysis and plasmonics. The mechanistic studies reveal that the concentration of Ag+ in the diffusion layer nearby the surface, controlled by the magnitude and duration of voltage, is critical in governing the nanoparticle formation (<1.3 mM) and its dimensional adjustability. 相似文献
80.
Fanchen Jing Guiliang Li Yingsa Wang Shangbin Zhu Rundong Liu Jing He Jiandu Lei 《先进技术聚合物》2021,32(1):343-354
Carboxymethyl chitosan (CMCS), as a water‐soluble, biocompatible, and biodegradable polymer, is an excellent carrier for a sustained drug delivery system. In this study, a amphiphilic carboxymethyl chitosan‐ursolic acid nano‐drug carrier modified by folic acid (FPCU) were prepared, and then the nano‐drug carrier wrapped another anticancer drug 10‐hydroxycamptothecin were self‐assembled into nanoparticles (FPCU/HCPT NPs). The FPCU/HCPT NPs had a suitable size, high drug loading efficiency of ursolic acid (6.4%) and 10‐hydroxycamptothecin (14.1%). The drug release study in vitro indicated that the nanoparticles have obviously sustained effect and pH sensitive behaviors, the drug release amount was higher at pH 5.5 than at pH 7.4. in vitro and in vivo study showed that the nanoparticles displayed a high antitumor efficiency to tumor cells compared with free drug. The nano delivery system as a carrier for ursolic acid (UA) and 10‐hydroxycamptothecin (HCPT) has good application prospects in cancer treatment. 相似文献