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101.
Chun-Chun Lin 《Applied Surface Science》2007,253(11):5011-5016
The formation of chromium carbide-based hard-coatings on steels using a 90°-bend filtered cathodic vacuum arc (FCVA) has extensive industrial applications; such coatings are free of macroparticles and exhibit excellent characteristics. In this investigation, a working pressure of C2H2/Ar was adopted to synthesize amorphous chromium carbide film (a-C:Cr) and crystalline chromium carbide film (cryst-Cr3C2) from a Cr target (99.95%) at 500 °C under a substrate voltage of −50 V. The corrosion behavior of a-C:Cr coated on steel (a-C:Cr/steel) and cryst-Cr3C2 coated on steel (cryst-Cr3C2/steel) were compared in terms of open-circuit potentials (OCP) and polarization resistance (Rp) in an aerated 3.5 wt% NaCl aqueous solution, as determined by electrochemical impedance spectroscopy (EIS). The XRD results indicated that the transformation of a-C:Cr to cryst-Cr3C2 is distinct as the working pressure declines from 1.2 × 10−2 to 2.9 × 10−3 Torr. The OCP of a-C:Cr/steel and cryst-Cr3C2/steel resemble each other and both assembly are nobler than uncoated steel. The Rp of the coatings exceeds that of the uncoated steel. The SEM observation and the EIS results demonstrate that the cryst-Cr3C2/steel more effectively isolates the defects than dose a-C:Cr/steel. 相似文献
102.
建立了S波段相对论速调管放大器双间隙输出腔开放腔的3维模型。采用时域有限差分法,通过监测激励电流源的响应计算了该双间隙输出腔的谐振频率、有载Q值、场分布以及特性阻抗,并分析了腔体结构尺寸对谐振频率、有载Q值和特性阻抗的影响。研究表明:腔体半径对开放腔的谐振频率影响很大,耦合孔尺寸对腔体谐振频率的影响较小;随着耦合孔张角增加,有载Q值逐渐减小;随着腔体半径增大、间隙的减小,腔体特性阻抗降低。研究结果可为S波段强流相对论速调管放大器双间隙输出腔的设计提供理论依据。 相似文献
103.
104.
电阻抗成像是一类椭圆方程反问题,本文在三维区域上对其进行数值模拟和分析.对于椭圆方程Neumann边值正问题,本文提出了四面体单元上的一类对称体积元格式,并证明了格式的半正定性及解的存在性;引入单元形状矩阵的概念,简化了系数矩阵的计算;提出了对电阻率进行拼接逼近的方法来降低反问题求解规模,使之与正问题的求解规模相匹配;导出了误差泛函的Jacobi矩阵的计算公式,利用体积元格式的对称性和特殊的电流基向量,将每次迭代中需要求解的正问题的个数降到最低.一系列数值实验的结果验证了数学模型的可靠性和算法的可行性.本文所提出的这些方法,已成功应用于三维电阻抗成像的实际数值模拟. 相似文献
105.
导电聚苯胺/MnO2空气阴极氧还原动力学 总被引:1,自引:0,他引:1
采用动电位扫描、交流阻抗技术研究了导电聚苯胺/MnO2复合阴极上氧还原反应动力学.动电位扫描表明氧在该复合阴极上还原的极化曲线服从Butler-Volmer公式,表观标准活化能为184.9 kJ/mol,反应为电化学步骤控制;交流阻抗谱观察到氧阴极还原由3个明显的线圈组成,表明氧阴极还原分3步进行,第1个圆弧随过电位的增大而显著减小,表明第1步电荷转移过程的确为氧还原反应的速率控制步骤;导电聚苯胺的高比表面积与MnO2的多微毛细管结构使氧在该复合电极上还原变得容易. 相似文献
106.
Xiaoli Cui Dianlu Jiang Peng Diao Junxin Li Zhenbin Jia Ruting Tong Xinkui Wang 《中国化学会会志》1999,46(4):571-576
The electrochemical behavior of the gold electrode modified by hybrid bilayer membranes in different concentrations of Fe(CN)63?/Fe(CN)64? was investigated by electrochemical impedance spectroscopy and cyclic voltammetry technology. The electron transfer between gold and the redox species separated by the hybrid bilayers assembly was completed by an electron tunneling process. A detailed equivalent circuit for electron transport across the HBMs is proposed. It was found that the apparent effective thickness of the hybrid bilayer membranes was lower than that of the sum of the chain length of octadecanethiol and phospholipid so some possible collapsed sites might exist at the hybrid bilayer membranes. 相似文献
107.
This work deals with the numerical localization of small electromagnetic inhomogeneities. The underlying inverse problem considers, in a three-dimensional bounded domain, the time-harmonic Maxwell equations formulated in electric field. Typically, the domain contains a finite number of unknown inhomogeneities of small volume and the inverse problem attempts to localize these inhomogeneities from a finite number of boundary measurements. Our localization approach is based on a recent framework that uses an asymptotic expansion for the perturbations in the tangential boundary trace of the curl of the electric field. We present three numerical localization procedures resulting from the combination of this asymptotic expansion with each of the following inversion algorithms: the Current Projection method, the MUltiple Signal Classification (MUSIC) algorithm, and an Inverse Fourier method. We perform a numerical study of the asymptotic expansion and compare the numerical results obtained from the three localization procedures in different settings. 相似文献
108.
Yves Van Ingelgem Els Tourwé Orlin Blajiev Rik Pintelon Annick Hubin 《Electroanalysis》2009,21(6):730-739
Electrochemical impedance spectroscopy (EIS) is a powerful technique to study electrochemical processes and to perform screening tasks. Recently an integrated measuring and modeling methodology for EIS based on a multisine excitation signal was developed. A key issue in this methodology is the data analysis, allowing us to rapidly quantify the reliability of the measured data. In this paper, a comparison is made between classical single‐sine and the proposed multisine measurements on the same system. The fitting of the impedance data obtained by single‐or multisine excitation and using different weighting factors is also discussed. In addition to the advantages reported in earlier work, it is concluded that, of all investigated frequencies, the odd random phase multisine excitation yields the highest quality data in the shortest measurement time. 相似文献
109.
110.
J. H. Sluyters 《Russian Journal of Electrochemistry》2009,45(1):25-28
Conditions for obtaining high precision impedance data on electrochemical metal/electrolyte interfaces are discussed and some
results pertaining to several electrode reactions presented. The importance of the dropping mercury electrode is stressed.
Published in Elektrokhimiya in Russian, 2009, vol. 45, No. 1, pp. 28–31.
Dedicated to Professor B.V. Ershler on the occasion of the Centenary of his birth.
The text was submitted by author in English. 相似文献