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981.
Shan‐Ci Chen Qingdong Zheng Qikai Zhang Dongdong Cai Jinyun Wang Zhigang Yin Changquan Tang 《Journal of polymer science. Part A, Polymer chemistry》2013,51(9):1999-2005
An angular‐shaped naphthalene tetracarboxylic diimide (NDI) was designed and synthesized as a new building block for n‐type conjugated polymers to tune their energy levels. Three n‐type copolymers incorporating this angular‐shaped NDI as the acceptor moiety were obtained by Stille coupling reactions and had number average molecular weights of 18.7–73.0 kDa. All‐polymer bulk‐heterojunction solar cells made from blends of these polymers with poly(3‐hexylthiophene) gave a power conversion efficiency up to 0.32% and exhibited an open‐circuit voltage (Voc) up to 0.94 V due to their relative high‐lying lowest unoccupied molecular orbital energy levels. The high Voc of 0.94 V is higher than that of solar cells based on linear‐shaped NDI‐containing polymers (<0.6 V). The results indicate that the angular‐shaped NDI is a promising building block for constructing nonfullerene polymer acceptors for solar cells with high open‐circuit voltages. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
982.
Accurate modeling of interfacial flows requires a realistic representation of interface topology. To reduce the computational effort from the complexity of the interface topological changes, the level set method is widely used for solving two‐phase flow problems. This paper presents an explicit characteristic‐based finite volume element method for solving the two‐dimensional level set equation. The method is applicable for the case of non‐divergence‐free velocity field. Accuracy and performance of the proposed method are evaluated via test cases with prescribed velocity fields on structured grids. By given a velocity field, the motion of interface in the normal direction and the mean curvature, examples are presented to demonstrate the performance of the proposed method for calculating interface evolutions in time. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
983.
This paper presents a new high‐order approach to the numerical solution of the incompressible Stokes and Navier–Stokes equations. The class of schemes developed is based upon a velocity–pressure–pressure gradient formulation, which allows: (i) high‐order finite difference stencils to be applied on non‐staggered grids; (ii) high‐order pressure gradient approximations to be made using standard Padé schemes, and (iii) a variety of boundary conditions to be incorporated in a natural manner. Results are presented in detail for a selection of two‐dimensional steady‐state test problems, using the fourth‐order scheme to demonstrate the accuracy and the robustness of the proposed methods. Furthermore, extensions to higher orders and time‐dependent problems are illustrated, whereas the extension to three‐dimensional problems is also discussed. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
984.
985.
《Analytical letters》2012,45(12):2067-2076
Abstract Sensitive and reproducible analyses were developed for assaying tamoxifen, desmethyltamoxifen, didesmethyltamoxifen and hydroxytamoxifen in human liver microsomes by high performance liquid chromatography (H.P.L.C.) following protein precipitation. Detection was by fluorimetry of phenanthrene derivatives formed by on-stream U.V. irradiation with a photochemical reactor enhanced detection (P.H.R.E.D.) for post-column irradiation of the H.P.L.C. stream. The method is highly sensitive (1 ng/ml). A C8,5 μm column (4.6 x 150 mm) was used, with a mobile phase of acetonitrile / 100 mM ammonium acetate (1:1) pH 5. Precipitation of the microsomal protein was carried out by adding methanol and concentrated chloric acid to the reaction mixture, and extraction efficiencies were approximately 100 % for tamoxifen and its metabolites. The assay has been optimised for the identification and quantitation of the 4-hydroxylated metabolite, as well as the two metabolites formed by N-oxidative demethylation of the side chain. The latter catalytic activity involves cytochrome P450 3A enzymes. 相似文献
986.
An interior penalty method and a compact discontinuous Galerkin method are proposed and compared for the solution of the steady incompressible Navier–Stokes equations. Both compact formulations can be easily applied using high‐order piecewise divergence‐free approximations, leading to two uncoupled problems: one associated with velocity and hybrid pressure, and the other one only concerned with the computation of pressures in the elements interior. Numerical examples compare the efficiency and the accuracy of both proposed methods. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
987.
988.
In the paper, a cross‐flow fan in refrigerant operating condition is systematically simulated using user‐defined functions. Three‐dimensional simulations are acquired with Navier–Stokes equations coupled with k–ε turbulence model, and internal flow characteristics of an indoor split‐type air conditioner are obtained, which is mainly composed of cross‐flow fan and heat exchanger. It has systematically been simulated in the isothermal flow condition that the performance of cross‐flow fan may be reduced easily with dry or humid air, and in the refrigerant operating condition in which user‐defined functions are applied to the humid air, considered as a mixture of dry air and vapor. A density‐modulated function is adopted to deal with the condensation of the vapor at the heat‐transfer region approximately. The results show flow mechanism of the two gas‐phase flow, including phase‐vary process. The distribution of the parameters is not uniform at the inlet of the machine, the intensity and position of pressure and velocity vary along the axial direction of the fan, the distribution of vapor volume fraction and turbulent intensity in heat‐transfer region is obtained, and the external characteristic data of the indoor machine are obtained and analyzed. Compared with the experimental data, the calculated characteristic curves and designed parameters are on target. © British Crown Copyright 2010/MOD. Reproduced with permission. Published by John Wiley & Sons, Ltd. 相似文献
989.
Cuauhtémoc Pozos vázquez Russell Tayouo Christine Joly‐Duhamel Bernard Boutevin 《Journal of polymer science. Part A, Polymer chemistry》2010,48(10):2123-2134
The synthesis and characterization of poly(dimethylsiloxanes) bearing maleimides end‐groups (PDMSM) were carried out through imidization of maleic anhydride with three poly(dimethylsiloxanes) diamines of different molecular weights. Self‐photopolymerization of PDMSM was studied by Real‐Time Fourier Transform infrared spectroscopy (RT‐FTIR) and was possible even without photoinitiator (Darocur 1173). The reaction was found to proceed within seconds upon exposure to ultraviolet (UV) radiation to generate highly crosslinked polymer networks. The results indicated that these polymerizations were less sensitive to oxygen inhibition than the radical processes carried out on conventional UV‐curable acrylate resins. The thermal and mechanical properties of these resulting materials were studied starting from PDMS precursors with different molecular weights. These materials exhibit a low glass transition temperature (100 °C) and a high degradation temperature (400 °C) depending on the density of crosslinking points. These PDMSM are suitable as hydrophobic additives in a coating formulation based on a UV cured polypropylene glycol bismaleimide. Only a very small amount of silicone additives (0.3 wt %) is needed to change the wettability on the surface of the films. The migration of the additive was clearly shown before irradiation by scanning electron microscopy EDX and surface energy measurements. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2123–2134, 2010 相似文献
990.
High‐density polyethylene/expanded graphite nanocomposites produced by polymerization‐filling technique using an industrial heterogeneous catalyst 下载免费PDF全文
Kátia Z. C da Cruz Adriana C. A. Casagrande Osvaldo L. Casagrande Jr 《Journal of polymer science. Part A, Polymer chemistry》2017,55(7):1260-1267
High‐density polyethylene nanocomposites with different expanded graphite (EG) contents (0.34–1.80 wt %) were prepared by polymerization‐filling technique using an industrial heterogeneous catalyst ( cat K ), and characterized using a range techniques: melting flow index (MFI), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and transmission electron microscopy (TEM). The MFI data showed that EG acts as a plasticizer decreasing melt viscosity in comparison to neat HDPE produced exclusively by cat K . DSC results showed that EG nucleated the HDPE crystallization as established by the increased crystallization temperature, and the degree of crystallinity. HDPE/EG nanocomposites displayed a significant improvement in the flexural (increased from 1458 to 1831 MPa), and storage modulus (increased from 122 to 1627 MPa) at only 1.80 wt % EG content. TEM images confirmed a homogeneous distribution of EG into the polymer matrix with the presence of dispersed, intercalated and aggregated EG nanofillers. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 55, 1260–1267 相似文献