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91.
92.
S. F. Shkirman N. A. Sokolov V. K. Konstantinova K. N. Solov'ev 《Journal of Applied Spectroscopy》2001,68(3):410-414
Quasiline electronicvibrational spectra of fluorescence and absorption (excitation of fluorescence in selective recording) of the molecules of phthalocyanine deuterated around the periphery of benzene rings (H2Phcd
16) and the center of the macrocycle (D2Phc) are obtained. The vibrational frequencies of the ground state are almost insensitive to this deuteration (except for vibrations with the participation of angular deformations). In excitation spectra, changes in deuteration are more pronounced due to the effects of nonadiabatic vibronic interaction of the vibrational sublevels of the S
1 state and of the purely electronic level S
2. 相似文献
93.
94.
基于单幅数字散斑投影及图像相关的离面振动测量 总被引:1,自引:0,他引:1
采用单幅数字散斑图投影及高速数字图像采集技术,研究了动态离面位移的测量。采用商用液晶投影仪将计算机产生的模拟散斑图投影到待测动态变形物体表面,由高速数字图像采集设备摄取并保存变形散斑图,采用时间序列数字图像相关软件计算出物体表面各点随时间变化的离面位移。这种方法用于振动分析时不仅可以获得振型分布,而且还可以获得各点的振幅值。与现有的激光频闪照相测振及激光多普勒测振等方法相比,具有光学系统简单,可全场定量测量。悬臂梁振动实验结果证实了该方法的有效性。 相似文献
95.
基于Polytec激光测振仪的光存储设备振动测试分析系统 总被引:2,自引:0,他引:2
针对光存储设备振动频率高的特点,采用Polytec激光测振仪拾取振动信号,并给出了基于Polytec激光测振仪的光存储设备振动测试分析系统。可用于硬盘盘片、磁头滑块、折臂组件、光盘盘片等振动测试,为光存储设备动态特性的测试和分析建立了良好的实验基础。 相似文献
96.
97.
V. M. Andrianov 《Journal of Applied Spectroscopy》2007,74(1):1-12
A theoretical conformational analysis has been carried out for the side substituents of a fragment of the molecule for 2,6-carboxymethyl
cellulose (a water-soluble cellulose ether), and the frequencies and the potential energy distribution of the normal vibrations
have been calculated for the most stable conformers of the ether groups of this fragment in the approximation of the molecular
mechanics method. It has been shown that the most stable conformers are those that have the conformations gg, t, g−, g−, g−-for the groups of atoms on the bonds C5-C6, C6-O6, C13-O6, C10-C13, C10-O9 and the conformations g+g−, g+, g−, g−; g+g−, g−, g−, g−; g+g−, g−, g+, t for the groups of atoms on the bonds C2-O2, C11-O2, C7-C11, C7-O8. Comparative analysis of the calculated frequencies
and the potential energy distribution of the normal vibrations for 13 of the most stable conformers showed, as in the case
of the 2,6-hydroxyethyl cellulose molecule, that the frequencies and modes of the normal vibrations are highly sensitive to
conformational transitions in the analyzed spectral region (800–1500 cm−1). The characteristic patterns for the change in the frequencies and modes of the normal vibrations have been established
in connection with conformational transitions within both side substituents. The observed conformational lability of the bulky
substituents in the cellulose ether molecules and its manifestations in the vibrational spectrum provide a basis for hypothesizing
that one of the major mechanisms for the process of their thermal gelation in aqueous solutions is conformational transitions
within these substituents.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 1, pp. 5–15, January–February, 2007. 相似文献
98.
This paper describes measurements of a vibrating object with rough surface by the time-averaged method of holography using a newly designed optically addressed liquid crystal spatial light modulator with a resolution of 102 lp/mm and a diffraction efficiency of 16%. An object vibrating faster than several tens of Hz could be visualized. The pattern obtained by the method provides the locus of vibrating nodes. The advantage of this method is that a high contrast pattern of a vibrating object can be imaged in near-real-time, although the sensitivity of vibration is decreased. 相似文献
99.
In the frame of a more complete study on the tautomery of the pyrazolines-5-ones, the authors determined the normal vibration modes of pyrazole. They calculate the interatomic force constants by means of a “simplex” optimisation procedure (1). 相似文献
100.
Norio Kondo 《国际流体数值方法杂志》2012,70(2):158-185
We present numerical results for in‐line and cross‐flow vibrations of a circular cylinder, which is immersed in a uniform flow and is elastically supported by damper‐spring systems to compute vibrations of a rigid cylinder. In the case of a circular cylinder with a low Scruton number, it is well‐known that two types of self‐excited vibrations appear in the in‐line direction in the range of low reduced velocities. On the other hand, a cross‐flow vibration of the circular cylinder can be excited in the range of high reduced velocities. Therefore, we compute the flow‐induced vibrations of the circular cylinder in the wide range of the reduced velocities at low and high Scruton numbers and discuss about excitation mechanisms in the in‐line and cross‐flow directions. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献