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41.
MA En CHEN Da-Qin HU Zhong-Jian LIU Feng HUANG Zi-Xiang BAO Feng WANG Yuan-Sheng ② 《结构化学》2007,26(3):303-308
The distribution characteristics of Er3+ ions doped in the oxyfluoride glass ceramics containing LaF3 nanocrystals heat-treated at 650 ℃ for different durations were investigated. The results of the integral absorption cross-section analysis demonstrated that the partition fraction of Er3+ in LaF3 nanocrystals increases with prolonging of heating time. The anomalous phenomena of Er3+ emissions in the up-and the down-conversion fluorescence spectra are well explained based on the calculated results. 相似文献
42.
Trace analysis of rapamycin in human blood by micellar electrokinetic chromatography 总被引:1,自引:0,他引:1
A capillary electrophoretic method with UV detection at 278 nm has been developed for analysis of the immunosuppressant rapamycin (sirolimus) in human blood at low microgram per liter levels. Separation has been achieved in an acidic carrier electrolyte containing sodium dodecylsulfate and 30% (v/v) acetonitrile. For sample clean-up and preconcentration, an off-line solid-phase extraction step using a silica-based reversed-phase material and an on-capillary focussing technique were employed. The latter allows the injection of increased sample volumes without excessive band broadening. Although this new method is less sensitive than existing liquid chromatographic procedures combined with mass spectrometry, it is fully suited to routine analysis of rapamycin in blood from patients treated with this drug. Last but not least the low costs make it an attractive alternative to established methods. 相似文献
43.
Study of urinary nucleosides as biological marker in cancer patients analyzed by micellar electrokinetic capillary chromatography 总被引:10,自引:0,他引:10
Thirteen normal and modified nucleosides, primarily degradation products of transfer ribonucleic acid (tRNA), were evaluated as potential tumor markers for cancer patients. Their urinary concentrations were determined by means of micellar electrokinetic capillary chromatography (MEKC) in the urine from 54 healthy adults and 70 cancer patients, then quantitatively expressed as a function of creatinine excretion. It was found that urinary nucleosides for cancer patients were on the average significantly higher than those for healthy controls, however, no significant differences were found between male and female or between different ages. Based on 13 urinary nucleoside concentrations, principal component analysis (PCA) could be used to classify 72% of cancer patients from the healthy controls. The present study shows that the precise measurement of urinary nucleosides by MEKC in combining with PCA technique may provide a clinically useful approach for diagnosis of cancer. 相似文献
44.
V. A. Livshits B. G. Dzikovskii V. P. Tsybyshev B. B. Meshkov 《Russian Chemical Bulletin》1996,45(7):1563-1571
Isotherms of the binding of dodecyl sulfate anions (DDS–)and Na+ counterions during their coadsorption with a nonionic polymer. proxanol (PR). at the interface of dodecane-water emulsions have been measured by conductometry and Na-selective potentiometry. The adsorption of DDS– and PR is concurrent. The affinity constant of PR to the interface determined by the Langmuir model decreases as the concentration of PR increases, and the surface concentration of DDS– tends to a nonzero limiting value at high concentrations of PR. The surface (o) and electrokinetic () potentials at the interface have been determined at various polymer concentrations by the spin probe and electrophoresis methods. The average dielectric permeability and density of polymer segments in We adsorption layer have been determined by ESR. The lower boundary of the hydrodynamic thickness of the polymer adsorption layer at the interface has been estimated from the dependences of o and on the ionic strength.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1653–1661, July, 1996. 相似文献
45.
Using Gawedzki and Kupiainen's rigorous block spin transformation method, we study critical phenomena in 4 spin systems in four dimensions. In Part I of this work we investigate in detail the renormalization group trajectory of the system not exactly at the critical point. 相似文献
46.
The lattice model for equilibrium polymerization in a solvent proposed by Wheeler and Pfeuty is solved exactly on a Bethe lattice (core of a Caylay tree) with general coordination numberq. Earlier mean-field results are reobtained in the limitq, but the phase diagrams show deviations from them for finiteq. Whenq=2, our results turn into the solution of the one-dimensional problem. Although the model is solved directly, without the use of the correspondence between the equilibrium polymerization model and the diluten0 model, we verified that the latter model may also be solved on the Bethe lattice, its solution being identical to the direct solution in all parameter space. As observed in earlier studies of the puren0 vector model, the free energy is not always convex. We obtain the region of negative susceptibility for our solution and compare this result with mean field and renormalization group (-expansion) calculations. 相似文献
47.
Summary Seasonal dependence of 20-hydroxyecdysone content ofSerratula tinctoria andSerratula wolffii (Asteraceae) was investigated by micellar electrokinetic chromatography (MEKC). Samples were collected each month through the vegetation
period. The leaves were dried, milled and extracted with methanol. Clean-up of the extracts was by solid-phase extraction
using a polyamide micro-column to remove flavonoids and other plant phenolics which can interfere with the analysis. This
work deals with the separation of 20-hydroxyecdysone from polypodine B and the seasonal variation of 20-hydroxyecdysone concentration.
Determinations have been performed by both thin-layer chromatography and capillary electrophoresis using micellar electrokinetic
chromatography.
Presented at: Balaton Symposium on High-Performance Separation Methods, Siófok, Hungary, September 3–5, 1997. 相似文献
48.
Summary The general objective is to provide an alternative methodology based on capillary electrophoresis (CE) to characterize flavonoids from honey and hence determine its botanical origin. The specific objective is to compare the separation of flavonoids by CE with those achieved by HPLC to assess CE as an alternative technique for the determination of honey flavonoids. Fourteen different flavonoids isolated from honey were analysed by MECC and compared to the HPLC separations. It was difficult to find specific experimental conditions to separate all the flavonoids from honey in a single MEKC run. Three chromatographic conditions are optimized and, depending on the flavonoid markers sought in honey, the appropriate detection method should be chosen. Compared to the HPLC results, it is clear that CE could be an alternative technique in honey flavonoids analysis and particularly in the study of its geographical and floral origin. 相似文献
49.
在胶束电动色谱模式下考察了影响生物胺分离的几个因素(如缓冲溶液及SDS浓度、pH、表面活性剂、分离温度及外加电压等)并优化了分离条件,建立了一种简单快速的利用毛细管胶束电动色谱DAD检测器分离分析生物胺的新方法。当缓冲溶液为40mmol/L硼酸缓冲液(pH8.5)、68mmol/LSDS,分离电压为25kV、分离温度为25℃时,5种生物胺在7min内实现了令人满意的基线分离。在优化的条件下,对其线性范围、检出限和重现性进行了测定。结果表明,生物胺的迁移时间的重现性<0.8%,面积的重现性<4%。 相似文献
50.
Summary In this paper, polymeric hollow fibers prepared from pH-stable polypropylene were used as columns for micellar electrokinetic
capillary chromatography (MECC). The electroosmotic flow (EOF) for polypropylene hollow fibers was evaluated in the pH range
of 5.0–12.0. With untreated polypropylene hollow fibers a stabilized but enhanced EOF was achieved when SDS was used in the
buffer, decreasing the separation window for uncharged substances in MECC to impractical levels. Uncharged acrylamide and
charged 2-acryloylamido-2-methylpropane sulfonic acid surface modifications were used to lower the strength of the EOF, increase
the separation window and prevent local overheating that could melt the column wall. 相似文献