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991.
在磷酸、硼酸及乙酸组成的缓冲介质中,齐墩果酸与β-环糊精反应生成包合络合物,其包合摩尔比为1比1。包合物的激发波长及发射波长的峰分别位于355nm及404nm处,在25℃条件下的结合常数为71L.mol-1,还测定了反应的热力学参数。测得ΔH0与ΔS0均大于0,说明此包合反应为吸热反应。测得ΔG0值小于0,且随反应温度升高而变得更负,说明此反应在试验条件下能自发进行,而随反应温度的升高,反应的自发性增强。 相似文献
992.
Mohamed Mahmoud Nasef Ezzatollah ShamsaeiPayman Ghassemi Amgad Ahmed AlyAbdul Hamid Yahaya 《Radiation Physics and Chemistry》2012,81(4):437-444
The radiation induced grafting of 4-vinylpyridine (4-VP) onto poly(ethylene-co-tetrafluoroethene) (ETFE) was optimized using the Box-Behnken factorial design available in the response surface method (RSM). The optimized grafting parameters; absorbed dose, monomer concentration, grafting time and reaction temperature were varied in four levels to quantify their effect on the grafting yield (GY). The validity of the statistical model was supported by the small deviation between the predicted (GY=61%) and experimental (GY=57%) values. The optimum conditions for enhancing GY were determined at the following values: monomer concentration of 48 vol%, absorbed dose of 64 kGy, reaction time of 4 h and temperature of 68 °C. A comparison was made between the optimization model developed for the present grafting system and that for grafting of 1-vinylimidazole (1-VIm) onto ETFE to confirm the validly and reliability of the Box-Behnken for the optimization of various radiation induced grafting reactions. Fourier transform infrared (FTIR), thermogravimetric analysis (TGA) and X-ray diffraction (XRD) were used to investigate the properties of the obtained films and provide evidence for grafting. 相似文献
993.
994.
Kumar Brajesh A.K. Himanshu Himanshu Sharma Kiran KumariRajeev Ranjan S.K. BandhopadhyayT.P. Sinha 《Physica B: Condensed Matter》2012,407(4):635-641
Pyrochlore phase free [Pb0.94Sr0.06] [(Mn1/3Sb2/3)0.05(Zr0.53Ti0.47)0.95] O3 ceramics has been synthesized with pure Perovskite phase by semi-wet route using the columbite precursor method. The field dependences of the dielectric response and the conductivity have been measured in a frequency range from 50 Hz to 1 MHz and in a temperature range from 303 K to 773 K. An analysis of the real and imaginary parts of the dielectric permittivity with frequency has been performed, assuming a distribution of relaxation times. The scaling behavior of the dielectric loss spectra suggests that the distribution of the relaxation times is temperature independent. The SEM photographs of the sintered specimens present the homogenous structures and well-grown grains with a sharp grain boundary. The material exhibits tetragonal structure. When measured at frequency (100 Hz), the polarization shows a strong field dependence. Different piezoelectric figures of merit (kp, d33 and Qm) of the material have also been measured obtaining their values as 0.53, 271 pC/N and 1115, respectively, which are even higher than those of pure PZT with morphotropic phase boundary (MPB) composition. Thus the present ceramics have the optimal overall performance and are promising candidates for the various high power piezoelectric applications. 相似文献
995.
Y.N.Ch. Ravi BabuP. Sree Ram Naik K. Vijaya KumarS.V.G.V.A. Prasad A. Suresh Kumar 《Physica B: Condensed Matter》2012,407(4):705-711
The ternary lead bismuth magnesium borophosphate glass system (LBMBPE) with molar concentrations of (50-x) PbO-xBi2O3-25MgHPO4-24B2O3-1Er2O3 (x=10, 20, 30 and 40) was prepared using Melt quenching technique. The amorphous nature of these glass samples were confirmed with XRD studies, The spectral data from the optical absorption studies was employed to compute the spectroscopic parameters such as Racah coefficients (E1, E2 and E3), spin-orbit coupling (ξ4f), configuration interaction factor (α) and Judd-Ofelt intensity parameters (Ωλ, λ=2, 4 and 6). The IR spectra exhibit the presence of vibrational modes of phosphates, borate radicals, bismuth, lead and magnesium ions. The Judd-Ofelt parameterization indicates the covalency and vibrationonic frequencies of the ligands with rare earth ions. The radiative parameters such as radiative transition probabilities (A), the total radiative transitional probabilities (AT), radiative life times (τR), branching ratios (β) and absorption cross sections (∑) were computed for certain lasing levels. The effect of compositional changes on the optical band gap is also reported. The glass systems thus developed indicate their potential lasing candidature. 相似文献
996.
B.A. Butler E.E. van Dyk F.J. Vorster W. Okullo M.K. Munji P. Booysen 《Physica B: Condensed Matter》2012,407(10):1501-1504
Low concentration photovoltaic (LCPV) systems have the potential to reduce the cost per kWh of electricity compared to conventional flat-plate photovoltaics (PV) by up to 50%. The cost-savings are realised by replacing expensive PV cells with relatively cheaper optical components to concentrate incident solar irradiance onto a receiver and by tracking the sun along either 1 axis or 2 axes. A LCPV module consists of three interrelated subsystems, viz., the optical, electrical and the thermal subsystems, which must be considered for optimal module design and performance. Successful integration of these subsystems requires the balancing of cost, performance and reliability. In this study LCPV experimental prototype modules were designed, built and evaluated with respect to optimisation of the three subsystems and overall performance. This paper reports on the optical and electrical evaluation of a prototype LCPV module. 相似文献
997.
In this paper, we consider the Cauchy problems for compressible Euler equations with damping. In terms of the Littlewood–Paley decomposition and Bony's para‐product formula, we prove the global existence, uniqueness and asymptotic behavior of the solution in the critical Besov space comparing with previous results. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
998.
This work investigates the adaptive Q–S synchronization of coupled chaotic (or hyper-chaotic) systems with stochastic perturbation, delay and unknown parameters. The sufficient conditions for achieving Q–S synchronization of two stochastic chaotic systems are derived based on the invariance principle of stochastic differential equation. By the adaptive control technique, the control laws and the corresponding parameter update laws are proposed such that the stochastic Q–S synchronization of non-identical chaotic (or hyper-chaotic) systems is to be obtained. Finally, two illustrative numerical simulations are also given to demonstrate the effectiveness of the proposed scheme. 相似文献
999.
Hongyinping Feng Shengjia Li 《Nonlinear Analysis: Theory, Methods & Applications》2012,75(4):2273-2280
In this paper we consider the wave equation with nonlinear damping and source terms. We are interested in the interaction between the boundary damping −|yt(L,t)|m−1yt(L,t) and the interior source |y(t)|p−1y(t). We find a sufficient condition for obtaining the blow-up solution of the problem. Furthermore, we also obtain that the solution may blow up even if m≥p. 相似文献
1000.
基于可信性理论,将提出一类带有模糊参数的运输期望值模型.然后,讨论模糊运输期望值模型的基本性质.最后,给出一个数值例子来表明所设计模型的实用性. 相似文献