‘‘Soggy sand＇＇ polymer composite nanofber membrane electrolytes for lithium ion batteries

A kind of octanol-modifded silica nanoparticle was fabricated and employed as a framework to form‘‘soggy sand’’electrolyte along with 1-butyl-3-methylimidazolium tetrafluoroborate.‘‘Soggy sand’’and poly（vinylidene fluoride-hexafluoropropylene）composite electrolyte membranes were electrospun for the frst time.The properties of this membrane electrolyte have been evaluated by the mechanical test and electrochemical test.The Young’s modulus increased by 275%from 6.8 MPa to 25.5 MPa and the electrical conductivity increased to 7.6 10à5S/cm at 290.15 K when compared to pristine P（VdF-HFP）membrane electrolyte.The conductivity is 3.1 10à4S/cm at 323.15 K.     

层间接触对沥青路面粘弹性动力响应影响研究

为分析沥青面层材料粘弹特性及路面各层间接触条件对沥青路面动力响应的影响,基于解析的方法,开展了层间非完全连续沥青路面粘弹性动力响应的求解工作．采用修正的Burgers模型定义沥青面层材料的粘弹性本构关系,考虑沥青路面层间接触条件,在车辆荷载作用下,建立沥青路面的理论计算模型;通过Laplace-Hankel积分变换将偏微分方程组转化为常微分方程组并对问题进行求解;采用转换矩阵表征层间接触条件,求得层间非完全连续沥青路面粘弹性动力响应的解析表达式．从沥青路面实例计算结果发现：修正的Burgers模型中的瞬时弹性模量参数是对弯沉计算结果影响最大的因素之一,路表弯沉随的增大呈下降趋势,特别是当较小时,这种趋势尤为明显;沥青混合料本构模型中的粘弹性修正系数B和黏性参数是影响路面路表弯沉计算结果的另两个重要因素,并且B和对弯沉峰值出现时间的影响具有相反的趋势;层间的非完全连续条件对沥青路面动态弯沉计算结果影响较大,并以面层与基层间的非完全连续对弯沉计算结果影响最为显著．     

A semi‐quantitative approach for the rapid screening and mass profiling of naphthenic acids directly in contaminated aqueous samples

We report the use of a direct sampling, online analytical approach for the determination of acid extractable naphthenic acids in complex aqueous samples, known as condensed phase membrane introduction mass spectrometry (CP‐MIMS). The technique employs a capillary hollow fibre semi‐permeable membrane probe configured for immersion into a pH adjusted sample. A continuously flowing methanol acceptor phase transfers naphthenic acids to an electrospray ionization source, operated in negative ion mode, whereupon they are analysed by mass spectrometry as [M–H]^? ions. High‐resolution mass spectrometry is used to characterize the influence of sample pH on membrane transport of multiple components of complex naphthenic acid mixtures. We demonstrate the use of CP‐MIMS for semi‐quantitative analysis of real‐world samples using selected ion monitoring and full scan mass spectra at unit mass resolution. The technique has also been employed to continuously monitor the temporal evolution in the mass profile and concentrations of individual naphthenic acid isomer classes in heterogeneous solutions during adsorption processes. Copyright © 2015 John Wiley & Sons, Ltd.     

沙尘大气电磁波多重散射及衰减

为了使干旱沙漠地区的电子系统能够全天候的工作, 必须开展沙尘大气的电磁波多重散射及衰减特性研究. 根据Mie理论、沙尘大气粒子尺寸分布和能见度的关系得到了电磁波沙尘大气传播衰减的计算方法, 计算了不同沙尘大气能见度的37 GHz电磁波的衰减, 与其他经验公式及文献中的实验结果进行比较, 文中方法得到的结果更接近于测量结果. 为了研究较低能见度沙尘暴中电磁波的传播特性, 需研究沙尘大气的多重散射效应. 应用Monte Carlo模拟方法, 在沙尘粒子为干燥和5%水含量时, 模拟了37 GHz和93 GHz电磁波在沙尘大气中传播时考虑多重散射效应的衰减, 并与基于Mie理论的计算结果进行比较, 结果显示, 在37 GHz时, 沙尘大气的多重散射对衰减的影响小, 在93 GHz时多重散射显著, 沙尘大气能见度越低, 多重散射的影响越显著. 粒子水含量增加使电磁波的衰减显著增大, 对多重散射的影响不明显. 因此, 在相同大气能见度下, 沙尘天气越干燥, 多重散射影响越大, 电磁波衰减减小越显著.     

DCLR与TLA共混改性沥青的性能对比

以SK-90沥青为基质沥青,分别加入相同掺量(与沥青质量比为5%、10%、15%和20%)的DCLR和TLA,利用SHRP PG、针入度分级体系、红外光谱仪和凝胶色谱仪对比分析DCLR和TLA共混改性沥青的宏观性能和微观结构的变化。结果表明,DCLR和TLA的加入均可以改善沥青的高温性能,但对沥青的低温性能和疲劳性能产生一定的不利影响。同时,根据DCLR和TLA共混改性沥青的官能团和分子量分布的变化可以判断DCLR和TLA对沥青的改性作用主要为物理改性,在某种程度上,DCLR不能完全替代TLA。     

Transparent,Ultrahigh‐Gas‐Barrier Films with a Brick–Mortar–Sand Structure

Transparent and flexible gas‐barrier materials have shown broad applications in electronics, food, and pharmaceutical preservation. Herein, we report ultrahigh‐gas‐barrier films with a brick–mortar–sand structure fabricated by layer‐by‐layer (LBL) assembly of XAl‐layered double hydroxide (LDH, X=Mg, Ni, Zn, Co) nanoplatelets and polyacrylic acid (PAA) followed by CO₂ infilling, denoted as (XAl‐LDH/PAA)_n‐CO₂. The near‐perfectly parallel orientation of the LDH “brick” creates a long diffusion length to hinder the transmission of gas molecules in the PAA “mortar”. Most significantly, both the experimental studies and theoretical simulations reveal that the chemically adsorbed CO₂ acts like “sand” to fill the free volume at the organic–inorganic interface, which further depresses the diffusion of permeating gas. The strategy presented here provides a new insight into the perception of barrier mechanism, and the (XAl‐LDH/PAA)_n‐CO₂ film is among the best gas barrier films ever reported.     

风沙运动研究中的若干关键力学问题

针对沙漠化（严重时导致沙尘暴发生）这一国家关注的重大环境的问题,在简要介绍风沙运动力学机理研究的主要发展阶段和部分最新研究进展的基础上,提出了风沙运动研究中值得关注的若干关键力学问题。     

Dependence of effective screening length in granular columns on bead and silo sizes and their ratio

Apparent mass measurements at the bottom of silos have been carried out. An important parameter in the Janssen model known as the effective screening length has been investigated for different bead and silo diameters as well as of their ratios. It is found that the effective screening length augments with the grain diameter d in addition to the granular column size. It is also revealed that λ exhibits stronger correlation with the bead diameter than that of the silo. This phenomenon is attributed to the reduced-shielding of the vertical stresses to the horizontal ones.