一类新型的“三块板”式卟咻化合物的合成及光物理性质初探

在光合作用原初过程中,太阳能转化成电能的关键步骤为:在光引发下,电子从一个叶绿素给体 D 转移到泛醌受体 A,从而产生D~ 和 A~-。光合作用原初过程及其人工模拟是受到世界各国普遍重视的一个研究领域。特别是近年来。卟啉(D)-醌(A)类化合物引起了人们的广泛兴趣,其中三块板式化合物是目前最接近     

染料激光泵浦Nd：S－VAP晶体激光特性研究

实验测定了Ｎｄ：Ｓｒ５（ＶＯ４）３Ｆ（简称Ｎｄ：Ｓ－ＶＡＰ）晶体的吸收光谱特性；在５８３．０ｎｍ和８０９．０ｎｍ处有强的吸收峰。用可调谐染料激光作泵浦源，实现了低阈值、高效率的激光运转。在透射率１５％的平面平行腔情况下，斜率效率为５０％，阈值为２ｍＪ。倍频光中心波长为５３６．０ｎｍ，线宽为１．４ｍｍ。本文还对Ｎｄ：Ｓ－ＶＡＰ晶体可作为ＬＤ泵浦的小型激光器的工作物质等问题进行了讨论。     

Optical characteristics of uniaxial polyester films with the optical axis perpendicular to the surface

The functions of the main indices of refraction n(ν) and absorption κ(ν) of uniaxial thin polyethylene terephthalate films have been calculated by the experimental spectra of frustrated total reflection of s-and p-polarized radiation in the 700–760-cm⁻¹ range. The κ_o(ν) maximum falls at the the 727-cm⁻¹ frequency and the maximum of κ_e(ν) falls at the the 724-and 732-cm^{− 1} frequencies. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 756–759, November–December, 2005.     

Propagation Characteristics of a High-Power Microwave in Waveguide Filled with Plasma

Analytical theory of high-power microwave propagation in waveguide filled with plasma is presented in this paper. The ponderomotive force effect of high power microwave is taken into consideration and preliminary numerical calculations are carried out, the propagation characteristics of the high-power microwave and the influence of microwave power on the distribution of plasma density are calculated and discussed.     

Solving the Problem of Gravitational Compression of a Layered Sphere (by the Example of the Earth)

The problem of spherically symmetric, gravitational compression of an isotropic hyperelastic layered sphere which modeling the region of the Earth below the Mohorovii boundary is solved. The known mechanical characteristics of the Earth in the compressed state are used to find its characteristics in the unstrained state obtained by adiabatic or isothermal stress relief. The stress state differs significantly from the state of purely hydrostatic compression. The minimum bulk compression and maximum radial tension occur not on the boundary of the sphere but in depth at certain distances from the boundary.     

The Hodge Structure on a Filtered Boolean Algebra

Let (B _n) be the order complex of the Boolean algebra and let B(n, k) be the part of (B _n) where all chains have a gap at most k between each set. We give an action of the symmetric group S _l on the l-chains that gives B(n, k) a Hodge structure and decomposes the homology under the action of the Eulerian idempontents. The S _n action on the chains induces an action on the Hodge pieces and we derive a generating function for the cycle indicator of the Hodge pieces. The Euler characteristic is given as a corollary.We then exploit the connection between chains and tabloids to give various special cases of the homology. Also an upper bound is obtained using spectral sequence methods.Finally we present some data on the homology of B(n, k).     

Steady-State and Time-Resolved Spectroscopic Characteristics of Novel Silicon-Containing Organopolymers

The spectroscopic characteristics of novel -conjugated polymers containing four-coordinated silicon, acetylene groups and either 1,4-biphenylene or 2,7-fluorene in the main chain were investigated by steady-state and picosecond laser spectroscopy. The spectral features of absorption, fluorescence excitation spectra, fluorescence lifetime, and fluorescence polarization were explained by the existence of two kinds of inhomogeneously broadened electronic states formed in the disordered polymeric chain. The dynamics of photoinduced absorption was measured in the 400–900 nm spectral range with picosecond time resolution. The long-wavelength band with _max 710 nm was ascribed to excited-state absorption from higher-lying electronic states created in short polymeric segments with essential conformational distortion of the subunits. The short-wavelength band with _max 580 nm and a shoulder at 500 nm was interpreted as photoinduced absorption from a lower-lying state arisen in more planar, longer -conjugated segments populated via direct excitation and energy migration between disordered segments of the polymeric chain. For the fluorene-containing polymer, the smaller Stokes shift and the greater degree of fluorescence polarization are consistent with more extensive electron delocalization along the backbone.     

Oxiranyl β-Aminovinyl Ketones. 7. Synthesis of 5-Hydroxy-3-(1-oxo-2,3-epoxyalkyl)benzofurans

5-Hydroxy-3-(1-oxo-2,3-epoxyalkyl)benzofurans were obtained with yields of up to 81% by the reaction of p-benzoquinone with oxiranyl -dimethylaminovinyl ketones in acetic acid.     

Reaction of Epichlorohydrin with 2-Aminobenzothiazole and Its Derivatives

We have shown that 2-aminobenzothiazoles when reacted with epichlorohydrin form 3-hydroxytetrahydropyrimido[2,1-b]benzothiazolium chlorides, while 2-iminobenzothiazolines form 2-(-chloro--hydroxypropyl)iminobenzothiazolines.