The electron transport characters in a nanostructure with the periodic magnetic-electric barriers

This paper detailedly studies the transmission probability, the spin polarization and the conductance of the ballistic electron in a nanostructure with the periodic magnetic-electric barriers. These observable quantities are found to be strongly dependent not only on the magnetic configuration, the incident electron energy and the incident wave vector, but also on the number of the periodic magnetic-electric barriers. The transmission coefficient and the spin polarization show a periodic pattern with the increase of the separation between two adjacent magnetic fields, and the resonance splitting increases as the number of periods increases. Surprisingly, it is found that a polarization can be achieved by spin-dependent resonant tunnelling in this structure, although the average magnetic field of the structure is zero.     

非线性光学腔中的相位调制光机械动力学

研究了Fabry-Perot光学腔中包含一个光学参量放大器来增强腔场与机械振子之间的耦合的光机械动力学行为.在解析边带机制下用量子郞之万方程具体研究了振子的涨落光谱、光学多稳态行为、机械阻尼与修正共振频移和基态冷却.通过数值解讨论了辐射压力诱导机械振子和腔场的稳态振幅所展现的光学多稳态行为,同时也分析了辐射压力引起的修正共振频移和机械阻尼与参量增益、输入激光功率和参量相位这三个因素的关系.此外,随着调节泵浦场的参量相位,振子的涨落光谱呈现简正模式分裂.通过精确求解最终有效声子数论证了基态冷却.结果表明,机械振子的冷却由初始浴温度、机械品质因数和参量相位这个三个因素控制.参量相提供一个新的方法来操控非线性光机械动力学.     

Splitting of coupled bright solitons in two-component Bose-Einstein condensates under parametric perturbation

We analyze the dynamics of bright-bright solitons in two-component Bose-Einstein condensates (BECs) subject to parametric perturbations using the variational approach and direct numerical simulations. The system is described by a vector nonlinear Schrödinger equation (NLSE) appropriate to coupled multi-component BECs. A periodic variation of the inter-component coupling coefficient is used to explore nonlinear resonances and splitting of the coupled bright solitons. The analytical predictions are confirmed by direct numerical simulations of the vector NLSE.     

Radially polarized hyperbolic-cosine-Gaussian beam

Vector beams have attracted much interest recently. In this paper, focusing properties of the radially polarized hyperbolic-cosine-Gaussian beam are investigated. Simulation results show that the focal depth increases with increasing cosine parameter in the cosine term of the beam, while focal spot decreases simultaneously, namely, superresolution occurs. Focal depth increase velocity is quicker for larger cosine parameter, while the transverse focal spot shrinks more quickly for smaller cosine parameter. In addition, for two-portion concentric piecewise radially polarized hyperbolic-cosine-Gaussian beam with π phase shift in center circle portion, focal pattern evolves considerably with increasing cosine parameter, and the evolution principle differs for different radius of the center circle portion. Focal splitting and novel focal spots may appear. This kind of vector beam can be used in optical storage, optical manipulation, and lithography.     

Facile deposition of cobalt oxide based electrocatalyst on low-cost and tin-free electrode for water splitting

Facile deposition of a water-splitting catalyst on low-cost electrode materials could be attractive for hydrogen production from water and solar energy conversion. Herein we describe fast electrodeposition of cobalt-based water oxidation catalyst(Co-WOC) on simple graphite electrode for water splitting. The deposition process is quite fast, which reaches a plateau in less than 75 min and the final current density is～1.8 mA/cm2under the applied potential of 1.31 V at pH = 7.0. The scanning electron microscopy(SEM) study shows the formation of nanometer-sized particles(10-100 nm) on the surface of the electrode after only 2 min and micrometer-sized particles(2-5 μm) after 90 min of electrolysis. X-ray photoelectron spectroscopy(XPS) data demonstrate the as-synthesized ex-situ catalyst mainly contains Co2+and Co3+species incorporating a substantial amount of phosphate anions. These experiments suggest that cost-efficient cobalt oxide materials on graphite exhibit alluring ability for water splitting, which might provide a novel method to fabricate low-cost devices for electrochemical energy storage.     

3D ordered macro-/mesoporous Ni_xCo_(100-x) alloys as high-performance bifunctional electrocatalysts for overall water splitting

Electrochemical water splitting is a facile and effective route to generate pure hydrogen and oxygen.However,the sluggish kinetics of hydrogen evolution reaction(HER) and especially oxygen evolution reaction(OER) hinder the water splitting efficiency.Meanwhile,the high-cost of noble-metal catalysts limit their actual application.It is thus highly urgent to exploit an economical and earthabundant bifunctional HER and OER electrocatalyst to simplify procedure and reduce cost.Herein,we synthesize the three-dimensionally ordered macro-/mesoporous(3 DOM/m) Ni_xCo_(100-x) alloys with distinctive structure and large surface area via a dual-templating technique.Among them,the3 DOM/m Ni_(61)Co_(39) shows the lowest overpotentials of 121 mV and 241 mV at 10 mA/cm~2 for HER and OER,respectively.Furthermore,when employed for water splitting,the Ni_(61)Co_(39) only requires 1.60 V to approach 10 mA/cm2 and presents excellent stability.These encouraging performances of the Ni_(61)Co_(39)render it a promising bifunctional catalyst for overall water splitting.     

A Doping Technique that Suppresses Undesirable H2 Evolution Derived from Overall Water Splitting in the Highly Selective Photocatalytic Conversion of CO2 in and by Water

Photocatalytic conversion of CO₂ to reduction products, such as CO, HCOOH, HCHO, CH₃OH, and CH₄, is one of the most attractive propositions for producing green energy by artificial photosynthesis. Herein, we found that Ga₂O₃ photocatalysts exhibit high conversion of CO₂. Doping of Zn species into Ga₂O₃ suppresses the H₂ evolution derived from overall water splitting and, consequently, Zn‐doped, Ag‐modified Ga₂O₃ exhibits higher selectivity toward CO evolution than bare, Ag‐modified Ga₂O₃. We observed stoichiometric amounts of evolved O₂ together with CO. Mass spectrometry clarified that the carbon source of the evolved CO is not the residual carbon species on the photocatalyst surface, but the CO₂ introduced in the gas phase. Doping of the photocatalyst with Zn is expected to ease the adsorption of CO₂ on the catalyst surface.     

Optical and fluorescence spectroscopy of Eu2O3-doped P2O5-K2O-KF-MO-Al2O3 (M = Mg, Sr and Ba) glasses

Fluorophosphate glasses of composition, P₂O₅ + K₂O + KF + MO + Al₂O₃ + xEu₂O₃ (M = Mg, Sr and Ba; x = 0.01, 0.05, 0.1, 1.0, 2.0, 4.0 and 6.0 mol%) were prepared and characterized their optical properties. Crystal-field (CF) analysis revealed a relatively weak CF strength around Eu³⁺ ions in the Ba based fluorophosphate glasses. The Judd-Ofelt parameters have been estimated from the oscillator strengths of ⁷F₀ → ⁵D₂, ⁷F₀ → ⁵D₄ and ⁷F₀ → ⁵L₆ absorption transitions of Eu³⁺ ions and were used to evaluate the radiative properties of the ⁵D₀ → ⁷F_J (J = 0-4) transitions. Considerable variation has been observed in the relative intensity ratio of ⁵D₀ → ⁷F₂ to ⁵D₀ → ⁷F₁ transitions of Eu³⁺ ions due to change in the alkaline earth metal ions. The decay of the ⁵D₀ level shows single exponential and less sensitive to Eu³⁺ ions concentration as well as MgO/SrO/BaO modifiers.     

方解石棱镜分束角高度对称性的设计

研究ｏ、ｅ双输出棱镜分束角的对称性。指出经特殊设计的双渥拉斯顿棱镜产生的ｏ、ｅ光的分束角具有高度的对称性。