全文获取类型
收费全文 | 1066篇 |
免费 | 11篇 |
国内免费 | 47篇 |
专业分类
化学 | 197篇 |
晶体学 | 4篇 |
力学 | 264篇 |
综合类 | 1篇 |
数学 | 346篇 |
物理学 | 312篇 |
出版年
2024年 | 4篇 |
2023年 | 16篇 |
2022年 | 11篇 |
2021年 | 12篇 |
2020年 | 16篇 |
2019年 | 17篇 |
2018年 | 15篇 |
2017年 | 25篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 43篇 |
2013年 | 86篇 |
2012年 | 48篇 |
2011年 | 63篇 |
2010年 | 76篇 |
2009年 | 74篇 |
2008年 | 66篇 |
2007年 | 61篇 |
2006年 | 54篇 |
2005年 | 37篇 |
2004年 | 34篇 |
2003年 | 31篇 |
2002年 | 21篇 |
2001年 | 20篇 |
2000年 | 21篇 |
1999年 | 23篇 |
1998年 | 21篇 |
1997年 | 13篇 |
1996年 | 18篇 |
1995年 | 13篇 |
1994年 | 19篇 |
1993年 | 15篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1988年 | 9篇 |
1987年 | 13篇 |
1986年 | 5篇 |
1985年 | 17篇 |
1984年 | 10篇 |
1983年 | 8篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有1124条查询结果,搜索用时 15 毫秒
51.
在化学专业英语的学习过程中,学生最早接触的是元素周期表。本文对一些元素的英文名称采用解读式的教学方法,通过将元素的英文名称同著名科学家、特定地理名称、太阳系中的星球以及神话中的人物相关联,使元素的英文名称不再枯燥乏味,而变得生动形象,这一过程可以使学生更好地体验学习的乐趣。 相似文献
52.
The bulk of the analytical data of a long period was used for estimation of RSD values of the CHNS analysis results obtained by EuroVector EA-3000 in the single-reactor mode. It is shown that the accident error level is conducted with the sample preparation procedure as well as with the properties of the certain analyzed samples. It is established that the experimental obtained CHNS analysis error levels significantly differ from those given in the technical specifications. In case of analysis of sample with the unknown composition the accidental errors of determination of each element are comparable with the standard sample ones. 相似文献
53.
本文以分析变深度螺旋槽止推轴承为例介绍了边界元法在润滑力学研究领域中的应用,以及相应的边界条件的处理方法,同时还讨论了轴承的尺寸参数对其性能参数的影响。 相似文献
54.
T. K. Kwei Kalle Levon Giuliana Tesoro Frank Liu Abraham Mey-Marom Surya Munukutla 《先进技术聚合物》1993,4(9):537-547
The synthesis of molecular composites where rigid polymer molecules are reinforcing elements in a thermoset bisimide matrix has been investigated. The approach has been designed to avoid phase separation by selecting systems where reaction of amine-terminated rigid and semiflexible oligomers with maleimide unsaturation occurs prior to crosslinking of the thermoset. This objective has been met for some compositions. The concentration and molecular weight of the rigid oligomers have been varied. The structure of the reinforcing polymer, the reactivity of the maleimide and the conditions for composite synthesis are variables of critical importance, and further work must determine the promise and limitations of this approach. 相似文献
55.
56.
Sodium deoxycholate (NaDOC) can induce 1-bromo-4-(bromoacetyl)naphthalene (BBAN) to undergo strong room temperature phosphorescence (RTP) without the removal of dissolved oxygen from the solution. RTP spectra, phosphorescence polarization and 13C NMR results, along with the molecular modeling calculations, supported the conclusion that BBAN molecule was combined in a sandwich with two NaDOC molecules by a “back-to-back” hydrophobic interaction arising from the apolar faces of the NaDOC molecules, which provided BBAN with a rigid enough microenvironment to produce RTP. 相似文献
57.
The role of rigid unit modes in negative thermal expansion 总被引:1,自引:0,他引:1
J.Z Tao 《Journal of solid state chemistry》2003,173(2):442-448
The rigid unit mode (RUM) model provides a valuable computational method to investigate correlations of transverse thermal motions of atoms important in negative thermal expansion (NTE) materials. We report here detailed RUM calculations of ten framework oxide structures that have been studied for their negative (or ultra low) thermal expansion properties. The results negate any simple and direct correlation between presence or absence of RUMs in a structure and its NTE property. All the structures considered can be viewed as networks of polyhedral connected by corners only. All evidence supports the importance the transverse motion of the atoms at the corners, but NTE does not correlate well with the presence RUMs for the polyhedra. 相似文献
58.
In the time order, the author proposes that the discovery and development of the periodic table of chemical elements are divided into four stages:point→1D→2D→3D. This article cites the main historical facts and documents available to unscramble the above four stages, which will facilitate the teaching and scientific research of the periodic table. 相似文献
59.
Ca3MgNi14, Nd1.5Ca1.5MgNi14, Gd1.5Ca1.5MgNi14 and Er1.5Ca1.5MgNi14 alloys were prepared by high frequency induction melting and sintering. Characterization and analysis were performed by X-ray diffraction/Rietveld full-spectrum fitting, gaseous P-C-T hydrogen storage test and electrochemical properties tests. It can be found that all alloys consist of Gd2Co7-type 3R phase and Ce2Ni7-type 2H phase. Although the hydrogen storage capacities of Nd1.5Ca1.5MgNi14, Gd1.5Ca1.5MgNi14 and Er1.5Ca1.5MgNi14 decrease to some extent compared to that of Ca3MgNi14, their equilibrium pressures for absorption and desorption increase markedly. Moreover, R1.5Ca1.5MgNi14 alloys have better cycling stabilities and high-rate discharge(HRD) properties as compared to Ca3MgNi14. The hydrogen diffusion in alloy electrodes is the main factor to influence the HRD performance. 相似文献
60.
The syntheses of two rigid organic molecular rods bearing a nitronyl-nitroxide radical and a terminal nitrogen-based functionality like a pyridine or a cyano group are reported. Both new paramagnetic molecules are fully characterized, including crystal structure analysis. Furthermore their magnetic behaviours in the crystalline state are investigated and their spin concentration corroborate their excellent purity. While the pyridine functionalized rod is synthesized by converting the corresponding benzaldehyde to the phenyl-nitronyl-nitroxide radical, the synthesis of the cyano functionalized rod demonstrates the accessibility of highly sophisticated spin-labelled molecules via cross-coupling reaction with a meta-iodo-phenyl-nitronyl-nitroxide moiety. 相似文献