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91.
Summary An equilibrium sandwich chamber for continuous thinlayer chromatography was used to study overloaded systems of the heptane + methylene chloride-silica type. Mixtures of two or three dyes were used as the model samples. Wide starting zones were formed using a glass distributor (frontal chromatography stage), then the movement of the zones was recorded during continuous elution. The effect of sample concentration and volume on the maximum separation yield was investigated. Band compression effects are illustrated for samples dissolved in solvents having a low eluent strength. Satisfactory analogy was found to separations in preparative column chromatography. Good separation yield was obtained for frontal + elution TLC: depending on the differences in the RF values of the components, 6–16 mg samples were completely separated on 0.5×100×75 mm layers containing ca. 1 g of silica.Presented at the Eighth International Symposium on Liquid Chromatography, Baden-Baden, 3–7 May 1983.  相似文献   
92.
Siburg and Stoimenov [12] gave a measure of mutual complete dependence of continuous variables which is different from Spearman's ρ and Kendall's τ. In this paper, a similar measure of mutual complete dependence is applied to discrete variables. Also two measures for functional relationships, which are not bijection, are investigated. For illustration of our main results, several examples are given.  相似文献   
93.
In this paper, non-linear deformation behavior of magnetostrictive materials is studied and three magnetoelastic coupling constitutive models are developed. The standard square (SS) constitutive model is developed by means of truncating the polynomial expansion of the Gibbs free energy. The hyperbolic tangent (HT) constitutive equations, which involve a hyperbolic tangent magnetic-field dependence, are proposed to model the magnetic-field-induced strain saturation of magnetostrictive materials in the region of intense magnetic fields. A new model based on density of domain switching (DDS) is established in terms of the basic truth that magnetic domain switching underlies magnetostrictive deformation. In this model, it is assumed that the relation between density of domain switching, defined by the quantity of magnetic domains switched by per unit magnetic field and magnetic field can be described by a density function with normal distribution. The moduli in these constitutive models can be determined by a material function that is proposed to describe the dependence of the peak piezomagnetic coefficient on the compressive pre-stress for one-dimensional cases based on the experimental results published. The accuracy of the non-linear constitutive relations is evaluated by comparing the theoretical values with experimental results of a Terfenol-D rod operated under both compressive pre-stress and bias magnetic field. Results indicate that the SS constitutive equations can accurately predict the experimental results under a low or moderate magnetic field while the HT model can, to some extent, reflect the trend of saturation of magnetostrictive strain under a high magnetic field. The model based on DDS, which is more effective in simulating the experimental curves, can capture the main characteristics of the mechanism of magnetoelastic coupling deformation of a Terfenol-D rod, such as the notable dependence of magnetoelastic response on external stress and the saturation of magnetostrictive strain under intense magnetic fields. In addition, the SS constitutive relation for a general three-dimensional problem is discussed and an approach to characterize the modulus tensors is proposed.  相似文献   
94.
95.
    
In the present study, the interfacial behavior of overmolded hybrid fiber reinforced polypropylene composites (hybrid composites) in the working temperature range from 23 °C to 90 °C was studied by experimental and constitutive methods. Monotonic and cycle loading-unloading single-lap-shear tests were employed to determine the interfacial properties of hybrid composites. The experimental results show that both interfacial shear strength and shear stiffness decrease with increasing working temperature. A regression function was adopted to evaluate the decaying degree of interfacial properties with increasing working temperature. The shear stress-displacement relationship under monotonic loading exhibits nonlinear behavior after an initial elastic region. The envelope lines of shear stress-displacement of hybrid composites under cyclic loading indicate that the nonlinearity in the curve is caused by the plastic deformation of polypropylene in the interphase region. A constitutive model was built to describe the nonlinear shear stress-displacement relation of hybrid composites at different working temperatures. A full suite of temperature-dependent plastic parameters in the model was obtained from cyclic loading-unloading tensile tests. The predicted shear stress–displacement curves agreed well with experimental results from different working temperatures. In addition, the failure mode of hybrid composites varied with working temperature.  相似文献   
96.
Laportea bulbifera, named Hong He Ma in Chinese, is a Chinese herbal medicine commonly used by the Miao nationality of China. In this study, 43 batches of L. bulbifera were collected from different origins in China. Ethanol, ethyl acetate and petroleum ether were used to prepare different extracts of the plant. UHPLC technique was used to establish the fingerprints, whereas DPPH assay and RAW264.7 inflammatory cell models were used to evaluate the antioxidant and anti-inflammatory activities, respectively. Moreover, the spectrum–effect relationship between relative peak area of common peaks and efficacy value was set up by multivariate statistical analysis. Furthermore, 10 batches were selected randomly for validation of those models. The results showed that ethyl acetate and petroleum ether extracts possess excellent antioxidant and anti-inflammatory activities, respectively. Peaks A6 and A7 demonstrated the greatest antioxidant activity, while peak A17 showed the strongest anti-inflammatory activity. After a verified experiment, the result was obtained and illustrated that the spectrum–effect relationship which we established could reliably infer antioxidant and anti-inflammatory compounds of the Chinese herbal medicine.  相似文献   
97.
    
This publication highlights the structure–property relationships in several thermoplastic elastomers (TPEs): one poly(ether-block-amide) and two thermoplastic polyurethane elastomers with ester and ether soft blocks. Structural changes are induced by chemical degradation from virgin samples through hydrolysis and oxidation. Molar mass measurements show an exclusive chain scission mechanism for all TPEs, regardless of the chemical modification condition. Mechanical behavior was nevertheless obtained from uniaxial tensile testing and fracture testing while considering the essential work of fracture (EWF) concept. During the macromolecular scission process, elongation at break shows a plateau followed by a drop, while stress at break decreases steadily. Once again, the trend is identical for all TPEs in all conditions considered. The βwp parameter determined using the EWF concept exhibits an interesting sensitivity to scissions (i.e., molar mas decrease). Plotting elongation at break as a function of molar mass reveals a strong correlation between these two parameters. This master curve is particularly remarkable considering the range of TPEs and chemical breakdown pathways considered (hydrolysis and oxidation at several temperatures). Relevant structure–property relationships are proposed, highlighting that molar mass is a predominant parameter for determining the mechanical properties of thermoplastic elastomers.  相似文献   
98.
    
Pillar[n]arenes constitute the most recognizable macrocyclic compounds discovered recently. So far, research has been focused on their binding properties, while the catalytic properties were poorly explored. Herein we present the study of the binding as well as the catalytic properties of pillar[5]- and pillar[6]arenes functionalized with carboxylic groups in water. We show that electrostatic stabilization is not the main driving force during the binding, however, it is crucial for catalysis. The macrocycles promote the hydrolysis of a wide variety of hydrazones, and their catalytic activity, in essence, is determined by the barrier of the passage of the substrate through the macrocyclic cavity. This opens up new perspectives for these macrocycles that could make a strong competition to traditional supramolecular catalysts such as cyclodextrins or cucurbiturils.  相似文献   
99.
    
Schiff-base–bearing new bis(thiosemicarbazone) derivatives were prepared from terephthalaldehyde and various thiosemicarbazides. FT–IR, 1H NMR, 13C NMR, and UV–Vis spectroscopic methods and elemental analysis were used to elucidate the identification of the synthesized molecules. The in vitro antioxidant activity of the synthesized compounds was analysed with the 1,1-diphenyl-2-picryl hydrazyl free-radical–trapping process. The synthesized compounds exhibited lower antioxidant activity than the standard ascorbic acid. IC50 values of the synthesized molecules measured from 3.81 ± 0.01 to 29.05 ± 0.11 μM. Among the synthesized compounds, compound 3 had the best antioxidant activity. Moreover, this study explained the structure–activity relationship of the synthesized molecules with different substituents in radical trapping reactions.  相似文献   
100.
    
Two new families of N,O-nucleoside analogues containing the anthracene moiety introduced through the nitrosocarbonyl ene reaction with allylic alcohols were prepared. The core structure is an isoxazolidine heterocycle that introduces either atom either a phenyl ring or dimethyl moiety at the C3 carbon. Different heterobases were inserted at the position 5 of the heterocyclic ring. One of the synthesized compounds demonstrated a good capacity to induce cell death and an appreciable nuclear fragmentation was evidenced in treated cells.  相似文献   
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