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991.
Summary Human ceruloplasmin contains several intrinsic copper ions, some of them being paramagnetic. The presence of two classes of
paramagnetic Cu2+ ions (type I and type II) has been suggested, the two types having significantly different spectroscopic features. However,
there are conflicting reports both on the ratio of the number of type-I to type-II Cu2+ and on their EPR spectroscopic parameters. By using a Monte Carlo method we obtained the best fit of the experimental spectrum
with a synthesized composite spectrum generated by two type-I Cu2+ (type I
a
and type I
b
, possessing slightly different spin Hamiltonian parameters) and by one type-II Cu2+. Correspondingly, the EPR spectroscopic parameter (viz. theg-tensors, hyperfine couplings, line widths and molar fractions) together with their accuracies were determined.
Riassunto La ceruloplasmina umana contiene diversi ioni Cu2+ alcuni dei quali sono paramagnetici. Di questi ne sono stati ipotizzati due tipi (tipo I e tipo II), ognuno dei quali con caratteristiche spettroscopiche diverse. Tuttavia esistono nei lavori precedenti discordanze sia sul numero di ioni Cu2+ che sui loro parametri EPR. Si è usato il metodo Montecarlo per ottenere il best fit dello spettro EPR della ceruloplasmina. Lo spettro simulato è risultato la somma di tre spettri, 2 di tipo I (tipo I a e tipo I b ) e 1 di tipo II. Sono stati così determinati i parametri relativi all'hamiltoniana di spin del sistema e le loro deviazioni standard.
Резюме Человеческий церулоплазмин содержит несколяко собственных ионов меди, некоторые из которых являются парамгнитными. Предполагается наличие двух классов парамгнитных Cu2+ ионов (тип I и тип II). Эти два типа имеют существенно различные спектроскопические свойства. Однако имеются противо-речивые публикации об отношении числа ионов Cu2+ типа I к числу ионов Cu2+ типа II и об их ЭПР спектроскопических параметрах. Исполязуя метод Монте-Карло, мы получаем наилучшее согласие экспериментального спектра с синтесированным составным спектром, образованным спектрами Cu2+ типа I (тип I a и тип I b имеющие слегка различные параметры спинового Гамилятониана) и одного спектра Cu2+ типа II. Определяются ЭПР спектроскопические параметы (а именно:g-тензоры, сверхтонкие связи, ширины линий и молярные доли).相似文献
992.
993.
Walter Schempp 《Acta Appl Math》1997,48(2):185-234
Due to its unequalled advantages, the magnetic resonance imaging (MRI) modality has truly revolutionized the diagnosis and evaluation of pathology. Because many morphological anatomic details that may not be visualized by other high tech imaging methods can now be readily shown by diagnostic MRI, it has already become the standard modality by which all other clinical imaging techniques are measured. The unique quantum physical basis of the MRI modality combined with the imaging capabilities of current computer technology has made this imaging modality a target of interdisciplinary interest for clinicians, physicists, biologists, engineers, and mathematicians. Due to the fact that MRI scanners perform corticomorphic processing, this modality is by far more complex than all the other high tech clinical imaging techniques. The purpose of this paper is to outline a phase coherent wavelet approach to Fourier transform MRI. It is based on distributional harmonic analysis on the Heisenberg nilpotent Lie group G and the associated symplectically invariant symbol calculus of pseudodifferential operators. The contour and contrast resolution of MRI scans which is controlled by symplectic filter bank processing gives the noninvasive MRI modality superiority over X-ray computed tomography (CT) in soft tissue differentiation. 相似文献
994.
995.
A.V. Prokofiev F. Büllesfeld W. Assmus H. Schwenk D. Wichert U. Löw B. Lüthi 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):313-316
Experimental results on magnetic resonance (ESR) and magnetic susceptibility are given for single crystalline (VO)2P2O7. The crystal growth procedure is briefly discussed. The susceptibility is interpreted numerically using a model with alternating
spin chains. We determine J
=51 K and . Furthermore we find a spin gap of meV from our ESR measurements. Using elastic constants no indication of a phase transition forcing the dimerization is seen
below 300 K.
Received: 22 December 1997 / Accepted: 17 March 1998 相似文献
996.
设计和建造大型磁体系统(包括常温和低温超导磁体)是目前核聚变工程中重要的问题之一。而磁体研制的核心问题都与强大机械力的存在有关。因此开展对磁体及结构材料应力的研究工作就显得特别重要。 近年来开始应用声学方法研究磁体中与力有关的问题(例如用声发射技术探测超导磁体的工作情况),已取得了有希望的结果。我们对低温与超导磁体中常用结构材料进行过声发射实验研究,也对目前尚存在争论的“磁体猝灭的声发射预测”问题进行了实验研 相似文献
997.
A characterisation by 14N NMR of the binary nitrides AlN and BN is presented. Both the static and magic angle spinning (MAS) lineshapes have been investigated in order to determine, or set upper limits on, the nuclear quadrupole coupling (Cq) at the nitrogen site. Additional data are given for the Cq values at the Al and B sites. A comparison is made with other similar (mainly wurtzite) binary compounds for which Cq is known at each atomic site. 相似文献
998.
V. V. Berdyugin P. P. Shorygin K. Ya. Burshtein Yu. V. Korshak M. A. Tlenkopachev A. V. Orlov 《Russian Chemical Bulletin》1996,45(8):1912-1916
Specific features of the excitation spectra of resonance Raman (RR) lines in multimode systems were characterized. Based on this, the spectra, the structure, and the composition of polyacetylene (PA) synthesized by polymerization of cycloocta-1,3,5,7-tetraene in the presence of metathesis catalysts were investigated. A dependence of frequencies and intensities of the C-C and C=C stretching lines on the exciting light wavelength was found and explained by broad distribution of defect-free conjugated polymer segments in the PA samples studied on the number of double bonds incorporated in them. A procedure for the calculation of the distribution functions and of the shapes of RR lines was proposed. These functions are bimodal. A reversiblecis-trans-transition was discovered in the PA samples not subjected to heat treatment, which was attributed to the presence of macrocyclic polyene structures.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2016–2020, August, 1996. 相似文献
999.
The resonance condition for triple-barrier structures with arbitrary potential is studied systematically. The quasisymmetrical triple-barrier (QST) resonance mode and the quasi-asymmetrical double-barrier (QAD) resonance mode may both exist in asymmetric triple-barrier structures. The QST consists of two submodes: a normal mode (doublet) and a degenerate mode (singlet). The critical condition for distinguishing the two modes is examined. It is confirmed that there are both unity resonant transmission and below-unit resonant transmission in the asymmetrical triple-barrier structure. Furthermore, the wavefunctions of an electron at resonance level are calculated and the confining phenomenon is studied. 相似文献
1000.