论理想气体p-V图中负斜率直线过程

本文通过对理想气体p-V图中负斜率直线过程温度及吸、放热变化的综合讨论，使我们对该过程有一个全面、清晰的认识，以开拓我们对热学过程讨论的方法及思路．     

孤立波在海滩上运动以及破碎的数值计算

对孤立波在缓坡海滩上的运动进行了数值模型，当孤立波接近海岸时，波高随水深减小迅速增大，以至波浪破碎，揭示了孤立波在不同皮下坡碎时的相对波高极值（H/h)b,，以及（H／h)b随坡度的变化情况，与合田的相对波高极值的表达式及（H/h)b随hb/L0的变化曲线比较，吻合良好。     

Improving the conversion efficiency of an organic distributed feedback laser by varying solvents of the laser gain layer

Control experiments were performed to improve the slope conversion efficiency of the organic distributed feedback laser by varying the dissolution solvents of the laser gain layer, a conjugated polymer poly(2-methoxy-5-(2?-ethyl-hexyloxy)-1,4-phenylene-vinylene) (MEH-PPV) in this work. The distributed feedback configuration of the laser was prepared by holographic photopolymerisation of the polymer/liquid crystal (HPDLC) mixture. Experimental results showed that the tetrahydrofuran (THF) solvent cast laser gain layer had a lower lasing threshold (0.28 μJ/pulse) and a higher slope conversion efficiency (7.8%) than that of the xylene solvent cast laser gain layer (0.5 μJ/pulse, 4.9%). Thin film waveguide characterisation demonstrated that the THF-cast film possessed a smaller waveguide loss (5.3 cm^?1) and larger net gain (17.1 cm^?1) than the xylene-cast film (8.3 cm^?1, 15.7 cm^?1). Absorbance and photoluminescence spectra indicated that the THF-cast film showed brighter luminescence at 620 nm and larger absorbance at 532 nm, indicating that the interchain interactions of the MEH-PPV is different, which plays the vital role in improving the optical performance of our organic DFB lasers.     

A novel potentiometric biosensor for selective L-cysteine determination using L-cysteine-desulfhydrase producing Trichosporon jirovecii yeast cells coupled with sulfide electrode

Trichosporon jirovecii yeast cells are used for the first time as a source of l-cysteine desulfhydrase enzyme (EC 4.4.1.1) and incorporated in a biosensor for determining l-cysteine. The cells are grown under cadmium stress conditions to increase the expression level of the enzyme. The intact cells are immobilized on the membrane of a solid-state Ag₂S electrode to provide a simple l-cysteine responsive biosensor. Upon immersion of the sensor in l-cysteine containing solutions, l-cysteine undergoes enzymatic hydrolysis into pyruvate, ammonia and sulfide ion. The rate of sulfide ion formation is potentiometrically measured as a function of l-cysteine concentration. Under optimized conditions (phosphate buffer pH 7, temperature 37 ± 1 °C and actual weight of immobilized yeast cells 100 mg), a linear relationship between l-cysteine concentration and the initial rate of sulfide liberation (dE/dt) is obtained. The sensor response covers the concentration range of 0.2-150 mg L⁻¹ (1.7-1250 μmol L⁻¹) l-cysteine. Validation of the assay method according to the quality control/quality assurance standards (precision, accuracy, between-day variability, within-day reproducibility, range of measurements and lower limit of detection) reveals remarkable performance characteristics of the proposed biosensor. The sensor is satisfactorily utilized for determination of l-cysteine in some pharmaceutical formulations. The lower limit of detection is ∼1 μmol L⁻¹ and the accuracy and precision of the method are 97.5% and ±1.1%, respectively. Structurally similar sulfur containing compounds such as glutathione, cystine, methionine, and d-cysteine do no interfere.     

MODIFIED SUBSTITUTION METHOD FOR CIRCULAR SLIDING SLOPE STABILITY ANALYSIST UNDER STEADY-STATE SEEPAGE

容重代替法是土坡稳定分析的常用方法. 首先研究了作用在圆弧滑动土坡上的水载荷作为孔隙水压力或作为渗流体载荷之间的关系,然后基于作用在滑块上的水载荷分别作为面载荷和作为体载荷的等效关系,给出了一种较简洁的基于代替法的稳定渗流对圆弧滑动土坡稳定影响的改进分析方法.     

水平层状岩体边坡动力响应中的结构面效应研究

根据应力波传播原理分析了水平层状岩体边坡中应力波传播特征,建立了应力波在该类边坡中传播的模型。利用离散元软件UDEC分析了不同频率垂向压缩应力波作用下边坡动力响应规律中的结构面效应。结果表明:边坡中的水平层面对坡顶的动力响应有明显影响。低频应力波作用下,水平层状岩体边坡坡顶的垂向峰值速度较均质坡体相同部位的峰值速度的增加值随坡高增加而增大。较高频率应力波作用时,边坡顶部靠近坡面的垂向峰值速度高于无结构面边坡相同部位的峰值速度,远离坡面时情况相反; 坡顶垂向峰值速度大小呈周期性变化,输入应力波频率越大该变化频次越高。研究结果将有助于进一步揭示各种不同岩体结构类型边坡在动力荷载作用下损伤机理及破坏模式。     

气孔对透明陶瓷激光输出性能的影响

定量分析气孔大小和气孔率对陶瓷激光输出性能的影响,建立了气孔分布模型并结合Mie散射和固体激光技术相关理论,讨论气孔散射对陶瓷激光透过率和输出性能的影响。结果表明,气孔率对激光陶瓷的透过率和斜率效率有着决定性的影响。在给定的气孔尺寸分布下,气孔率越高,陶瓷透过率和激光斜率效率越低;在给定的气孔率下,气孔中心尺寸越大,陶瓷样品的透过率和激光斜率效率越低。减小气孔尺寸至0.3 m以下能有效提高激光斜率效率。气孔越大,激光阈值随气孔率增大而上升越快,越不利于实现激光输出。在实际工作中,改进和控制工艺减小气孔尺寸对提高陶瓷的输出性能同样有着重要意义。     

激光雷达数据应用于海气界面气体传输速率的估算

选取2007年1、4、7、10月4个月夜间无云的云-气溶胶激光雷达和红外探测者观测卫星(CALIPSO)星载激光雷达Version 3.01数据,提取532nm激光海面后向散射系数并计算海面波浪均方斜率。同时选用准同步AMSR-E海面风速数据,利用Wanninkhof等于2009年提出的包含线性、平方、立方项的海面风速与气体传输速率混合关系模型计算海水施密特数为660时的海气界面气体传输速率k660。通过回归分析,得到由星载激光雷达数据反演k660的关系模型。将激光雷达数据反演结果与采用4种典型海面风速关系模型的计算结果进行比较,给出由星载激光雷达数据反演的4个月平均的海气界面气体传输速率全球分布图和纬度分布图。研究表明,CALIPSO星载激光雷达532nm单脉冲测量数据可用于反演海气界面气体传输速率。     

哈特曼波前传感器中采样点数的分析

随着哈特曼传感器测量口径的增大,采样点数对被测波前的空间分辨率、测量精度及动态范围的影响也随之增大,因此通过计算机仿真波前径向斜率拟合过程,分析出采样点数和斜率探测误差对测量精度和测量范围的影响。计算机仿真的波前斜率拟合所用泽尼克多项式达到121项,测量口径2m,测量精度要求λ/50,径向(半径)和切向最少采样点数分别为10点和21点。当径向和切向采样点数分别为40点和250点,斜率测量误差为0.045″时,所测波前的P-V值范围是0-4λ。