全文获取类型
收费全文 | 4638篇 |
免费 | 234篇 |
国内免费 | 913篇 |
专业分类
化学 | 3655篇 |
晶体学 | 116篇 |
力学 | 321篇 |
综合类 | 33篇 |
数学 | 300篇 |
物理学 | 1360篇 |
出版年
2024年 | 12篇 |
2023年 | 63篇 |
2022年 | 140篇 |
2021年 | 148篇 |
2020年 | 181篇 |
2019年 | 106篇 |
2018年 | 99篇 |
2017年 | 179篇 |
2016年 | 208篇 |
2015年 | 185篇 |
2014年 | 204篇 |
2013年 | 376篇 |
2012年 | 242篇 |
2011年 | 317篇 |
2010年 | 255篇 |
2009年 | 309篇 |
2008年 | 278篇 |
2007年 | 336篇 |
2006年 | 332篇 |
2005年 | 249篇 |
2004年 | 219篇 |
2003年 | 197篇 |
2002年 | 162篇 |
2001年 | 130篇 |
2000年 | 141篇 |
1999年 | 116篇 |
1998年 | 95篇 |
1997年 | 85篇 |
1996年 | 56篇 |
1995年 | 65篇 |
1994年 | 72篇 |
1993年 | 51篇 |
1992年 | 49篇 |
1991年 | 20篇 |
1990年 | 23篇 |
1989年 | 11篇 |
1988年 | 11篇 |
1987年 | 10篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有5785条查询结果,搜索用时 15 毫秒
81.
Abstract A review is presented of a very general aspect of the response of all metals subjected to displacive irradiation. This aspect is referred to as «persistence» and describes the tendency of both radiation-induced microstructural evolution and the associated changes in material properties or dimensional stability to evolve to saturation states that resist further change upon continued irradiation. It is shown that new persistent states can develop on a longer time frame associated with the late-term loss of existing microstructural components or the gain of new components, especially when transmutation and/or segregation occurs. The persistent states are often dependent on the irradiation conditions, and if these are changed, the material usually adjusts to form the persistent state characteristic of the new conditions, with the memory of the former state often lost, and sometimes leaving no visible record of the former state in the new microstructure. Depending on the microstructural components involved, the transition toward the new persistent state can occur quickly or very slowly. 相似文献
82.
K. Ganesan S. Ilango Mariyappan Shanmugam M. Farrokh Baroughi M. Kamruddin A.K. Tyagi 《Current Applied Physics》2013,13(9):1865-1869
The loss of local dielectric integrity in ultrathin Al2O3 films grown by atomic layer deposition is investigated using conducting atomic force microscopy. I–V spectra acquired at different regions of the samples by constant and ramping voltage stress are analyzed for their pre- and post-breakdown signatures. Based on these observations, the thickness dependent dielectric reliability and failure mechanism are discussed. Our results show that remarkable enhancement in breakdown electric field as high as 130 MV/cm is observed for ultrathin films of thickness less than 1 nm. 相似文献
83.
We report on the novel application of nanoscratch characterization to provide insight into the plasticity mechanisms responsible for the behaviour of composites. Accordingly, we conduct deformation characterization with nanoscratch testing (DCNT) to study the deformation behaviour of two B4C reinforced ultrafine grained Al alloy tri-modal composites with average B4C particle sizes of ~1–6?μm and ~500?nm, respectively. To highlight the type of mechanistic information revealed in a DCNT study of composites, we concentrate on the influence of B4C particle size on deformation mechanisms. 相似文献
84.
YBCO线圈的交流损耗直接关系到YBCO设备的运行成本及稳定性。实现对YBCO线圈交流损耗的快速、准确测量,对于开展YBCO涂层导体的应用研究具有重要的意义。文中采用电测量法,在77K、零场和不同频率条件下,对YBCO线圈通以不同运行电流时产生的交流传输损耗进行测量。构建了YBCO线圈交流损耗的数值计算模型,对YBCO线圈交流损耗进行理论研究,最后将实验数据与理论计算结果进行比较,两者结果基本一致。可以发现,YBCO线圈在频率低于75Hz时,交流传输损耗随频率的增大而减小,当频率从75Hz增加到195Hz时,交流传输损耗随频率的增大而增加。 相似文献
85.
S. Loridant G. LucazeauT. Le Bihan 《Journal of Physics and Chemistry of Solids》2002,63(11):1983-1992
A high-pressure structural study of SrCeO3 has been performed at room temperature by Raman spectroscopy and X-ray diffraction up to 32 and 45 GPa, respectively. A first-order reversible phase transition is observed at about 12 GPa in both techniques. A second weak structural change, taking place between 18 and 25 GPa, can be suspected from Raman data. The increase in the number of Raman bands and diffraction lines is an indication that the symmetry is lowered and the compound does not evolve towards the ideal cubic perovskite structure. A Rietveld analysis of X-ray data was performed for the low-pressure phase and the atomic positions and the cell lattice parameters variations are reported in this paper. The volume compressibility derived from Raman modes (5.6×10−12 Pa−1), involving mainly bond-stretching for each type of polyhedron, is found to be close to the one obtained from volume cell variations measured by X-ray diffraction (7.9×10−12 Pa−1). 相似文献
86.
Rafael Dias do Espírito Santo Rosineide Costa Simas Alviclér Magalhães Vanessa Gonçalves dos Santos Thais Regiani Ana Cristina Isler Natiza Graziele Martins Marcos Nogueira Eberlin Eduardo René Pérez González 《Journal of Physical Organic Chemistry》2013,26(4):315-321
Molecules containing the guanidinic nuclei possess several pharmacological applications, and knowing the preferred isomers of a potential drug is important to understand the way it operates pharmacologically. Benzoylguanidines were synthesized in satisfactory to good yields and characterized by NMR, Electrospray Ionization Mass Spectrometry (ESI‐MS) and Fourrier Transform InfraRed Spectroscopy techniques (FTIR). E/Z isomerism of the guanidines was studied and confirmed by NMR analysis in solution (1H‐13C Heteronuclear Single Quantum Coherence (HSQC) and Heteronuclear Multiple‐Bond Correlation (HMBC), 1H‐15N HMBC, 1H‐1H Correlation Spectroscopy (COSY) and Nuclear Overhauser Effect Spectroscopy (NOESY) experiments) at low temperatures. Compounds with p‐Cl and p‐Br aniline moiety exist mainly as Z isomer with a small proportion of E isomer, whereas compounds with p‐NO2 moiety showed a decrease in proportion of isomer Z. The results are important for the application of these molecules as enzymatic inhibitors. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
87.
Masao Sumita Hibeki Abe Hiroyuki Kayaki Keizo Miyasaka 《Journal of Macromolecular Science: Physics》2013,52(1-2):171-184
The electrical conductivities of carbon-black-filled low-density polyethylene (LDPE), poly(methyl methacrylate) (PMMA), and poly(vinyl chloride)-vinyl acetate (PVC/ VAc) copolymer were measured as functions of carbon content and melt viscosity of the matrix at the temperatures at which the composites were prepared. Sharp breaks in the relationship between the carbon filler content and the conductivity of composites were observed in all specimens at some content of the carbon filler. The conductivity jumps as much as 10 orders of magnitude at the break point. This phenomenon has been known as the “percolation threshold”. The critical carbon content corresponding to the break point 相似文献
88.
89.
I.IntroductionCurrent1ythemajorityofcommcrcialultrasonicscannersutilizeon1ytheamplitudcinformationcarriedbytheechoesbackscatteredfrombiologicaltissuestoproduccandriageintimedomain.Potentia1lyusefulinformationinfrequencyd0maincontainedbytheechoesiscomp1ete1ydiscarded.Theu1trasonicspectrumanalysistechnique,whichcancompensatethislack,canpresentsomeusefulparametcrsinfrcqucncydomainusedinultrasonictissuecharacterization.Onthisbackgroud,asericsofworksonthisficldhavcbeendoneduringthepastdecadell-5l.… 相似文献
90.
The 3, 4, 9, 10-perylenetetracarboxylic dianhydride (PTCDA) doped polymer films were prepared with Polypyrrole (PPy) and Polyvinyl alcohol (PVA) polymers by solution-casting. The change in structure and chemical composition of samples was identified by XRD and FTIR respectively. The UV–visible spectroscopy demonstrates the optical characteristics and band gap properties of sample. The homogeneous morphology of sample for higher wt% of PTCDA was examined by atomic force microscopy (AFM). The differential scanning calorimetry (DSC) results demonstrate the decrease in melting temperature (Tm) and degree of crystallinity (χc%) of polymeric organic semiconductor. The mechanical property demonstrates the high tensile strength and improved plasticity nature. Impedance spectroscopy was evaluated to determine the conductivity response of polymeric organic semiconductor. The highest DC conductivity (2.08×10−3 S/m) was obtained for 10 wt% of PTCDA at 140 °C. The decrease in activation energy (Ea) represents the non-Debye process and was evaluated from the slope of ln σdc vs. 103/T plot. 相似文献