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51.
We make a high-precision Monte Carlo study of two- and three-dimensional self-avoiding walks (SAWs) of length up to 80,000 steps, using the pivot algorithm and the Karp-Luby algorithm. We study the critical exponentsv and 2
4 – as well as several universal amplitude ratios; in particular, we make an extremely sensitive test of the hyperscaling relationdv = 2
4 –. In two dimensions, we confirm the predicted exponentv=3/4 and the hyperscaling relation; we estimate the universal ratios <R
g
2
>/<R
e
2
>=0.14026±0.00007, <R
m
2
>/<R
e
2
>=0.43961±0.00034, and *=0.66296±0.00043 (68% confidence limits). In three dimensions, we estimatev=0.5877±0.0006 with a correctionto-scaling exponent
1=0.56±0.03 (subjective 68% confidence limits). This value forv agrees excellently with the field-theoretic renormalization-group prediction, but there is some discrepancy for
1. Earlier Monte Carlo estimates ofv, which were 0.592, are now seen to be biased by corrections to scaling. We estimate the universal ratios <R
g
2
>/<R
e
2
>=0.1599±0.0002 and *=0.2471±0.0003; since *>0, hyperscaling holds. The approach to * is from above, contrary to the prediction of the two-parameter renormalization-group theory. We critically reexamine this theory, and explain where the error lies. In an appendix, we prove rigorously (modulo some standard scaling assumptions) the hyperscaling relationdv = 2
4 – for two-dimensional SAWs. 相似文献
52.
In the present paper, the behavior of a single polymer chain under various solvent conditions was modeled by self-avoiding walks (SAW) with nearest neighbors attraction Δε on a simple cubic lattice. Determination of the θ-condition wasbased on the numerical results of the mean square radius of gyration and end-to-end distance. It was found that at the θtemperatue Δε/kT equals -0.27. The exponents a in the Mark-Houwink equation with different interaction parameters areconsistent with the results of experiments: under θ-condition, a = 0.5, and for a good solvent α= 0.74-0.84, respectively. 相似文献
53.
This paper addresses the problem of stabilizing an uncertain linear system. The uncertaintyq(·) which enters the dynamics is nonstistical in nature. That is, noa priori statistics forq(·) are assumed; only boundsQ on the admissible variations ofq(·) are taken as given. The results given here applied to so-called matched systems differ from previous results in two ways. Firstly, the stabilizing control in this paper is linear; for this same class of problems, many of the existing results would require a nonlinear control. Furthermore, those results which do in fact yield linear controls are only valid when a certain matrix (q) (formed using the given data) is negative definite for allq Q. In contrast, the theory given here only requires compactness of the bounding setQ. Secondly, we show that the so-called matching conditions (used in earlier work) can be generalized so as to encompass a larger class of dynamical systems.This research was supported by the US Department of Energy under Contract No. ET-78-S-01-3390. 相似文献
54.
A. I. Ermakov A. E. Merkulov A. A. Svechnikova V. V. Belousov 《Journal of Structural Chemistry》2004,45(6):923-928
Orbital relaxation (OR) amounts to variation of the orbital exponents in hydrogen molecules and ions relative to the exponents of the isolated atom; it is represented as the sum of the one- and two-center contributions depending on the effective atomic charge and on the presence of other atoms in the molecule. The procedure for isolating the contributions of the exponent includes treatment of the OR of hydrogen in a special set of neutral and charged atoms and molecules with certain multiplicities of their electronic states. Within the framework of the spin-unrestricted Hartree-Fock method, we found and discussed the optimal values of the exponents of the basis orbitals of hydrogen atoms and molecules using the minimal split valence-shell basis set, the basis set that includes the polarization function, and the expanded set of grouped natural orbitals. A simple energy model is suggested for OR. Expressions are derived for evaluating the exponents of the relaxed orbitals in hydrogen-containing systems.Original Russian Text Copyright © 2004 by A. I. Ermakov, A. E. Merkulov, A. A. Svechnikova, and V. V. Belousov__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 6, pp. 973–978, November–December, 2004. 相似文献
55.
The lithium chloride/1,3-dimethyl-2-imidazolidinone (LiCl/DMI) solvent system for cellulose was adopted as a mobile phase of size-exclusion chromatographic (SEC) analysis of cellulose, and the applicability of this system was examined using multi-angle laser light scattering and 13C-NMR analysis. The results indicate that 8% (w/v) LiCl/DMI ID a true solvent for cellulose, and that cellulose molecules dissolving ID 1% (w/v) LiCl/DMI are separated orderly depending on their molecular mass (MM) or root-mean-square (RMS) radius by the SEC system. Practically, no aggregates were detected ID the dilute cellulose/LiCl/DMI solutions. Furthermore, high stability of cellulose/LiCl/DMI solutions has been demonstrated; only a few percent of decline ID average MM was observed even after storage for 6 months at room temperature. Relationships between RMS radius and MM for hardwood bleached kraft pulp ID 1% LiCl/DMI was estimated as the following equation: g0.59, corresponding to a Mark–Houwink–Sakurada exponent of 0.77. 相似文献
56.
The cluster density function of independent percolation in ad-dimensional lattice is considered. For eachn, it is shown that(p) has finitenth leftderivative at critical probabilityp
c ifd is sufficiently large. This result agrees with the Bethe lattice approximation, where thenth one-sided derivative of(p) is bounded atp
c for alln. 相似文献
57.
Plant diseases have caused tremendous crop losses and have massive impacts on food security and environment. Modeling the spread of plant diseases and understanding the dynamics of the resulting plant disease models may provide practical insights on designing effective control measures. In this paper, by incorporating cultural strategies and economic threshold policy, we present a Filippov-type plant disease model. The resulting model has state dependent discontinuous right-hand side and thus non-smooth analysis and generalized Lyapunov approach are employed for model analysis. We show that the model exhibits the phenomena of stable equilibrium, unstable pseudoequilibrium as well as sliding-mode heteroclinic orbit. Biological implications of our results in implementing control strategies for plant diseases are also discussed. 相似文献
58.
Controlled discrete–time stochastic processes axe studied using the convex–analytic approach. Some new properties of strategic measures spaces are established, particular Markov models are considered. The meaningful example is presented. 相似文献
59.
《随机分析与应用》2013,31(2):375-388
The statistical properties of the Lyapunov exponent of the chaotic generalized skew tent map is studied. Expressions of the mean and the variance of this Lyapunov exponent at each discrete time index are obtained. A sufficient condition for weakly mixing of the chaotic generalized skew tent map is derived, and the asymptotic distribution of its Lyapunov exponent is provided. 相似文献
60.
We provide criteria for the strong ergodicity of regime-switching diffusion processes. Our conditions are imposed on the coefficients of the processes. Particularly, we show that for regime-switching diffusions on the half line, if the corresponding diffusion on each fixed environment is strongly ergodic, then the regime-switching diffusion is strongly ergodic as well, which does not depend on the changing rate of the environment. Moreover, the converse is not always true, which is shown by an example. For transience, recurrence and positive recurrence, there is no such good consistency [R. Pinsky and M. Scheutzow, Some remarks and examples concerning the transience and recurrence of random diffusions, Ann. Inst. Henri. Poincaré 28 (1992) 519–536]. 相似文献