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991.
A new method for the analysis of thermal desorption spectra is presented, based on the experimental peak maximum functions
for temperatureT
m(β) and pressureP
m(β) and a rigorous mathematical treatment. The resonant heating rate βr is determined, satisfyingT
m(βr)=T
r, whereT
r is the resonant temperature defined byA exp(−E
d/(RT
r))=1. Desorption energyE
d and frequency factorA can be determined simultaneously with relatively high robustness towards statistical experimental errors as demonstrated
by computer-simulated thermal desorption spectra. 相似文献
992.
The thermal dehydration of copper(II) acetate hydrate has been studied between 353 and 406 K, over a range of humidities.
The dehydration is controlled by nucleation-and-growth kinetics at low temperatures, with an activation energy of 154 kJ·mol−1, which changes to contracting-disc kinetics at higher temperatures with a lower activation energy of 76 kJ·mol−1. Frequency factors have also been derived; the value for the high temperature process is low (107s−1) and that for the low temperature step is high (1017s−1). Optical microscopy has been used to clarify the bulk kinetics; there is evidence for a reactive layer at the surface of
the decomposing solid.
In celebration of the 60th birthday of Dr Andrew K. Galwey 相似文献
993.
Mixtures composed of amides and electrolytes exhibit interesting properties such as viscoelastic behaviour and a megavalue of the dielectric constant. In order to improve the dielectric properties, the authors are investigating a large number of molten mixtures of CF3COONa with different types of amides, including the ternary system sodium trifluoroacetate-chloroacetamide-acetamide. The experimental measurements showed that the ternary mixtures are thermally unstable. A yellow oily product is formed; this was purified and tested by means of IR and NMR techniques. The formula and the kinetic mechanism are proposed. 相似文献
994.
Z. D. Zivkovic 《Journal of Thermal Analysis and Calorimetry》1994,41(1):99-104
The results of comparative thermal analysis (TG-DTG-DTA-DSC) of the thermal decomposition of hexamminecobalt(III) chloride in air atmosphere are reported. The kinetics and mechanism of the thermal decomposition, the process enthalpy and the variation in specific thermal capacity of the solid product reaction with temperature were determined. 相似文献
995.
Polypropylenes of differing morphologies were examined by differential thermal analysis. The problems of reordering during
the programmed heating are discussed. Four potential procedures by which the reordering could be inhibited are considered,
and three of these are experimentally assessed. Their advantages and deficiencies are identified. Two pretreatments, an etching
and a crosslinking, are recognised as able to qualitatively characterise the initial morphology, with a preference for the
former. A test to identify the occurrence of reordering is identified.
In celebration of the 60th birthday of Dr. Andrew K. Galwey 相似文献
996.
Simultaneous DSC-TG and DTA-TG were used to investigate the calatytic effect of the metal on the thermal decomposition of
a cellulose matrix containing small copper particles. The techniques were also used to demonstrate the effect of the metal
particles on the subsequent activation of the carbon matrix, a process which develops the pore structure necessary to expose
the metal particles to the gas phase. Temperature programmed desorption was used to study the initial mass loss found on activation.
To quantify the catalytic effect of the copper particles on the activation process an estimate was made of the activation
energy of the catalysed and uncatalysed reactions. The work gives valuable information on the processes involved in the preparation
of a new range of metal-carbon catalysts.
In celebration of the 60th birthday of Dr. Andrew K. Galwey 相似文献
997.
高抗冲聚丙烯序列结构的综合表征 总被引:3,自引:0,他引:3
用高分辨^13C NMR、FTIR等手段获得了高抗冲聚丙烯的组成和序列分布等链结构方面的信息。用DSC、WAXD等方法研究了它们的结晶行为、熔融转变及晶体结构,多种方法相结合有效地表征了高抗冲聚丙烯的序列结构。 相似文献
998.
999.
1000.
Automorphisms of groups acting faithfully on rooted trees are studied. We find conditions under which every automorphism of such a group is induced by a conjugation from the full automorphism group of the rooted tree. These results are applied to known examples such as Grigorchuk groups, Gupta–Sidki group, etc. 相似文献