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51.
通常主链液晶高分子在受到剪切作用时 ,分子微纤呈周期性锯齿状排列 ,其光学效应表现为在偏光显微镜下可观察到相互平行且与剪切方向垂直的条带织构 [1] .而厚度适中的主链液晶聚合物薄膜经过热处理 ,即使没有受到剪切取向的作用 ,介晶微区的尺寸发展到一定大小时也会形成条带织构 ,即所谓结晶诱导[2 ] 和固化诱导 [3,4 ] 的条带织构 .在所报道的条带织构中 (包括剪切和非剪切 ) ,分子链均平行于膜平面 .本文研究发现 ,热致液晶氯代聚芳醚酮的薄膜样品在其高有序液晶温区经热处理 ,可形成结晶诱导的单晶状条带织构 ,其分子链垂直于膜平面 .…  相似文献   
52.
The banded texture in films prepared from nematic poly (1,4-benzamide) (PBA)/H_2SO_4 solution by shearing and without shearing has been studied by using microscopy techniques. The kinetic parameters of banded texture formation γ_c and τ_b were measured for nematic solution of PBA by using parallel-plate shearing apparatus. The banded texture was also observed in randomly packed domains for nematic solution of PBA on standing without shearing. The properties of banded texture show no difference between the two samples with or without shearing.  相似文献   
53.
从一种聚芳酯B-N得到了丝状(包括细丝和粗丝)、纹影状和大理石纹状等与小分子向列液晶相似的多种织构。由于样品淬火后晶片装饰在织构上而不影响分子取向矢的分布,因而可以用化学刻蚀和电镜技术揭示其向错和取向矢图。电镜和光学显微镜的结果相互补充,表明了细丝和粗丝状织构的分子取向矢分布很不相同,是两种不同的织构,而粗化始于第二熔融降温。在这些向列织构中分别发现了S=±(1/2)和s=+1的向错的例子和平面内微区转向壁的证据。  相似文献   
54.
The presented study is aimed at analyzing the surface texture of amorphous hydrogenated carbon layers containing nickel nanoparticles (Ni‐NPs@a‐C:H) within their structure, which were deposited by Radio Frequency (RF) sputtering and RF‐Plasma Enhanced Chemical Vapor Deposition (RF‐PECVD) methods on glass substrates. Prepared films were then used as research material following their annealing at two different temperatures of 250 °C and 350 °C in an inert argon atmosphere. Series of height samples were taken with the help of atomic force microscopy (AFM) operating in a non‐contact mode and examined in order to determine their fractal characteristics. Raw AFM data were first plane‐fitted to remove the surface bow exhibiting the so‐called residual surface, and then numerically processed to calculate the Areal Autocorrelation Function (AACF), which was later used to compute the Structure Function (SF). The log–log plots of the latter served for calculation of fractal properties of surfaces under investigation, including fractal dimension D, and pseudo‐topothesy K. The analysis of 3‐D surface texture helps to understand their essential characteristics and their implications as well as graphical models and their implementation in computer simulation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
55.
《高分子学报》1996,(2):172-177
采用条带织构装饰新技术研究了含T─型液晶基元的热致性聚芳酯液晶态的向错形态.经过培养的液晶样品无需剪切,淬火后便可呈现出围绕向错点取向排列的条带织构,而条带织构长轴的垂直方向正代表了液晶基元的指向矢方向,这样,在普通偏光显微镜下就能直接观察到这些条带织构装饰的强度S=±1/2和S=±1的向错,并观察到S=-3/2的高强度向错和闭环状的反转壁.  相似文献   
56.
Several binary copolycarbonates were prepared by polycondensation of 2,5‐bis(4‐hydroxybenzylidene)cyclopentanone, BHBC, with methylhydroquinone, MHQ, hydroquinone 4‐hydroxybenzoate, HQHB, or isosorbide. Furthermore, five ternary copolycarbonates were prepared based on the aforementioned monomers. All polycondensations were conducted in pyridine with trichloromethyl chloroformate as condensing agent. All polycarbonates were characterized by elemental analyses, viscosity and DSC measurements, IR and 1H‐ and 13C‐NMR spectroscopy, optical microscopy, and the WAXS powder pattern. All isosorbides containing binary and ternary copolycarbonates were found to form a cholesteric melt, but only three of them were capable to form a stable Grandjean texture upon shearing. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1125–1133, 1999  相似文献   
57.
SiO2–Al2O3 aerogels and xerogels with a Si to Al molar ratio r Si/Al varying from 0.25 to 20, were made by sol-gel process in acidic conditions at pH 2 and respectively dried by the CO2 supercritical method and by solvent evaporation. The Al precursor was also chelated with ethylacetoacetate, which made it possible to study the structure and texture of such gels in conditions favorable to the formation of mixed Al–O–Si bonds. Nitrogen adsorption isotherms according to the Brunauer, Emmett and Teller method (BET), 27Al magic angle spinning nuclear magnetic resonance (27Al MAS-NMR), Fourier Transformed Infrared Spectroscopy (FTIR) and Infrared absorbance spectra after Temperature Programmed Desorption (TPD) of pyridine, showed that the Si–O infrared asymmetric stretching vibration and the Bronsted acidity relative to the Lewis acidity, depended on the ratio of AlIV to Si atoms.  相似文献   
58.
The runoff of the Huanghe contains a great amount of suspended load and forms the high-density underflows (hyperpycnal currents) at the river mouth. The sediments over the subaqneous delta are mainly transported by the underflow. The sediment texture gradually get fining seawards, which relates to the attenuation of the hyperpycnal currents and hypopycnal plumes. Being hydraulically equivalent to the medlum-silt-sized quartz, which is the dominant component in the sediments, the clastic mica concentrates on the delta. The maximum thickness of the subaqueous delta is about 16m and the period of accumulation lasted from 12 to 16 years, therefore its sedimentary rate ranges from 110 to 130 cm/a.  相似文献   
59.
基于移动Agent技术的医学图像检索方法   总被引:1,自引:0,他引:1  
针对现有医学图像检索方法中,检索算法速度较慢、准确性较低以及远程检索时占用大量带宽等问题,设计并实现了一种基于移动Agent技术的医学图像检索方法,重点讨论了该方法实现的关键技术,包括提升框架下的M带整数小波变换和提取多通道纹理特征的检索算法.模拟实验结果表明,该方法实时性较强,占用网络带宽较少,采用的算法运算速度提高近10倍、运算复杂度降低约50%,提取的纹理特征能充分表达图像内容,较好地满足了医学图像的检索要求,实现了对医学图像库快速较准确的检索.  相似文献   
60.
人群异常事件检测是智能视频监控领域的重要研究内容, 文章提出了一种融合速度强度熵VMME与纹理特征的人群异常行为检测算法. 该算法采用LBPCM算法提取图像纹理特征, 在视频帧计算光流基础上, 获得特征点速度强度图, 并以其熵VMME作为场景运动特征, 将场景纹理特征和运动特征送入支持向量机训练分类. 实验表明, 新算法可实现对人群异常行为的检测, 且有较高准确率.  相似文献   
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