Effect of the alkyl chloride-to-aluminum molar ratio in the catalysts of dec-1-ene oligomerization on the product distribution and the chlorine content in the products

Dec-1-ene oligomerization in the presence of an aluminum—1-dodecyl chloride system was studied. A mixture of low-molecular-weight oligodecenes containing 25–40 wt.% dimers and 30–52 wt.% dec-1-ene trimers is formed at the molar ratios RCl/A1 = 0.5–1.5. The oligomerization was assumed to occur under the action of cationic active sites, which are formed during the reaction of 1-chlorodedecane with aluminum. At temperatures of 120–130°C and molar ratios RCl/A1 = 0.5–1.5 metallic aluminum completely dechlorinates 1-chlorododecane in a dec-1-ene medium. The character of the effect of highly dispersed Al and the RCl/A1 molar rato on the fractional composition and chlorine content in oligodecenes was revealed. The latter are formed by an aluminum—tert-butyl chloride system used in the industrial oligomerization of dec-1-ene. A mechanism of Al dissolution by alkyl chlorides with the simultaneous dechlorination of alkyl chloride and formation of cationic active sites in A1-RCl systems was proposed to explain the results obtained. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 661–665, March, 2008.     

射电偏振仪PПy—1的结构及其工作原理

本文介绍了射电偏振仪ＰПｙ—１的结构及其工作原理。该仪器是利用发射偏振的超高频无线电磁波透射复合材料构件，对接收到的信号进行分析来确定构件在工作状态下的应力应变值。本文还通过测试实例说明了仪器的使用及各种参数的确定方法。     

干涉型光纤传感器信号检测技术的研究

光纤传感器是一种高灵敏度传感器，而信号检测技术是它的关键技术之一。介绍了干涉型光纤传感器的信号检测方法。首先简单分析了干涉型光纤传感器相位衰落现象产生的物理机制，然后分别介绍了各种抗相位衰落信号检测方法的基本工作原理和特点，着重讨论了其中几种主要的方法，详细分析了它们的优缺点、应用场合以及技术难点。最后对各种检测方法的主要性能进行了比较，并对它们的发展前景做了展望。     

常规综合鉴别函数的改进

针对常规综合鉴别函数制作的复合匹配滤波器，对不同旋转角度的训练样本输出的相关峰值波动性较大，不便于后续探测和处理等问题，对常规综合鉴别函数到编码匹配滤波器的编码转化过程进行分析，找到导致相关峰值波动的原因，提出改进方法，即在计算综合鉴别函数的线性组合系数时将编码运算也考虑进去，并根据滤波器对各训练样本相关峰值的倒数来确定线性组合系数。计算机仿真结果表明：改进后的方法降低了复合滤波器对不同旋转角度样本输出相关峰值的波动性，提高了相关峰自动判别的准确性。     

IPy2BF4-mediated rearrangements of 1,2-difunctionalized compounds and olefins

Acetal derivatives are easily obtained from 1,2-difunctionalized compounds by a new reaction mediated by IPy2BF4 with a mechanism based on a 1,2-migration of aryl or alkyl groups. A new oxidative rearrangement reaction of olefins is also described. Moreover, when this metal-free protocol is applied to cyclic olefins, interesting ring-contraction reactions are observed. The new methodologies described here are a clean and efficient alternative to known strategies that make use of potentially toxic metallic complexes.     

The structure of hormaomycin and one of its all-peptide aza-analogues in solution: syntheses and biological activities of new hormaomycin analogues

Four new aza-analogues of hormaomycin 1, a secondary metabolite with interesting biological activities produced by Streptomyces griseoflavus, were synthesized and subjected to preliminary tests of their antibiotic activity to provide new insights into the structure-activity relationship studies of this class of compounds. The solution structures of hormaomycin 1 and its aza-analogue 2 a were determined by NMR spectroscopy. The data exhibited a reasonably rigid conformation for both molecules, stabilized by stacking interactions between the aromatic moieties attached to the ring and the side chain. According to NMR-spectral data the aza-analogue epi-2 a has a rather different conformation and indeed shows no antibacterial activity whatsoever.