NaY分子筛的改性及吸附脱氮性能

采用离子交换法用NH⁺₄、Zn²⁺、Cu²⁺、Cr³⁺阳离子改性NaY分子筛,并利用XRD、FT-IR和低温N₂吸附-脱附等方法对改性的分子筛进行了表征。XRD 和FT-IR表征结果表明,改性后的分子筛骨架完好。Cr改性Y分子筛(CrY)的比表面积、孔体积及平均孔径均较小,但存在部分介孔。研究了改性分子筛对含喹啉模拟燃料的吸附脱氮,喹啉分子尺寸的模拟结果为0.711 6 nm×0.500 2 nm,说明其并不易进入Y型分子筛0.74 nm的微孔。吸附脱氮结果表明,CrY的脱氮效果最好,CuY和ZnY次之,NH₄Y效果最差,改性分子筛的吸附脱氮性能与金属离子的价态有关,同价金属离子改性后的分子筛,吸附时间对其影响趋势相同,且金属离子价态越高,改性分子筛的吸附脱氮性能越好。吸附温度对CrY和NH₄Y分子筛吸附脱除喹啉的影响不大,可在室温下使用,但高温有利于CuY和ZnY吸附脱氮。XRD表征结果表明,焙烧后CrY分子筛骨架已完全塌陷失去了绝大部分吸附脱氮性能。     

氧气对胜利褐煤水蒸气气化半焦结构及反应性的影响

为了研究氧气对半焦的结构变化和反应性的影响,采用不锈钢模拟气流床反应器,在8种不同气氛,800和900 ℃条件下,进行了胜利褐煤水蒸气气化实验。利用拉曼光谱和热重分析仪分别表征了半焦的结构和本征反应性。结果表明,在800和900 ℃条件下,添加的氧气对半焦结构变化的影响方式不同;半焦结构的变化是影响碱金属和碱土金属(AAEM)挥发的主要因素。在不同温度下,添加的氧气对Na挥发的影响和对结构的作用类似,H₂O/O₂混合气氛促使气化所得半焦的反应性进一步降低。半焦的反应活性指数与拉曼光谱谱带比值 I (G_R+V_L+V_R)/I_D具有很好的相关性。     

Simultaneous detection of ultraviolet B-induced DNA damage using capillary electrophoresis with laser-induced fluorescence

An immunoassay based on CE–LIF was developed for the simultaneous detection of cyclobutane pyrimidine dimers (CPDs) and pyrimidine 6-4 pyrimidone photoproducts (6-4PPs) in genomic DNA irradiated with UVB or natural sunlight. Human cells were first exposed to varying amounts of UVB or natural sunlight to induce DNA damage. Genomic DNA was extracted and incubated with anti-CPD and anti-6-4PP primary antibodies attached to secondary antibodies with a fluorescent quantum dot (QD) reporter that emitted either red or yellow fluorescence. CE was used to separate the unbound antibodies from those bound to the photoproducts, and LIF with appropriate optical filters was used to separate the fluorescence signals from each QD to individual photomultiplier tubes for simultaneous photoproduct detection. Using this strategy, photoproducts were detected from ∼6 ng (200 ng μL⁻¹) of DNA under a low UVB fluence of 65 J m⁻² for CPDs or 195 J m⁻² for 6-4PPs. This assay was also the first to demonstrate the detection of CPDs in human cells after only 15 min of irradiation under natural sunlight.     

金字塔栅格夹心夹层板动力响应分析

本文将金字塔形栅格夹心夹层板假设成均匀夹心夹层板，应用Reissner夹层板理论，对其自振频率以及在简谐荷载下的强迫振动进行了研究，并以简支板为例，得到其解析解，通过与有限元分析进行比较，两者结果吻合良好。并把金字塔形栅格夹层板与同质量实体板进行比较，得出金字塔形栅格夹层板具有更好动力性能。     

Hybrid of Two Heuristic Optimizations with LSSVM to Predict Refractive Index as Asphaltene Stability Identifier

Asphaltene precipitation is a big challenge in the petroleum industry. This motivated us to develop a reliable model between refractive index and SARA fraction as a tool for the diagnosis of asphaltene stability. Least-square support vector machine (LSSVM), due to its several unique advantages, has been successfully verified as a predicting method in recent years. However, the success of LSSVMs depends on the adequate choice of the kernel and regularization parameters. We proposed the combination of two search algorithms to deal with the problem of support vector machine parameter selection. On this basis, we combined coupled simulated annealing (CSA) and the Nelder and Mead Simplex method to optimize the parameters. In this hybrid optimization, first, CSA finds suitable starting values and these are passed to the simplex method in order to tune the result. The LSSVM results are promising and accurate, and outperform both neural network and empirical models existing in literature.      

路面结构模量反算的遗传-模拟退火混合算法

路面结构层模量反算是路面结构无损检测与评价的基础。本文针对遗传算法和模拟退火算法各自的特点，在传统遗传算法的搜索过程中引入模拟退火算法的Metropolis接受准则，以增强算法的全局搜索能力。在此基础上，将遗传-模拟退火混合算法应用于路面结构层材料模量的反算分析。文中分别对理论数据和实测数据进行了计算，并与目前国内外已有的路面反算软件的分析结果进行了分析比较。数值结果表明，该方法具有较强的全局收敛性，数值结果稳定可靠。     

METHODS FOR IDENTIFYING SUB-REGIONAL MATERIAL PARAMETERS OF CONCRETE DAMS USING MODAL DATA

Methods for identifying sub-regional material parameters of concrete dams using in-complete modal data are presented.With the measurements of the first frequency and incompletemode shape,identification methods were built by both the output error approach and the minimumdeviation approach.The minimum deviation approach was introduced as physical constraints tothe output error approach,allowing the output error-minimum deviation coupled approach to bedeveloped.The simulated annealing-simplex shape algorithm was applied to solve the identifi-cation models.Numerical simulations were carried out with noisy incomplete measurements toillustrate the robustness of the methods.     

大尺度分层介质电特性参数的反演方法研究

针对大尺度分层介质电磁场散射回波数据, 提出了一种用于分层介质特性参数反演的新方法, 实现了分层介质的介电常数、电导率和介质厚度的同时反演. 方法首先将这些参数的反演转化为最优化问题进行求解, 然后应用模拟退火算法搜索最优解, 充分利用算法的全局寻优能力, 同时改善了算法的搜索控制策略, 使算法在最优解的搜索过程中可以自适应地调整搜索步长, 提高了算法的搜索效率. 结果表明, 本文方法可以实现大尺度分层介质特性参数的准确反演, 且具有较强的抗噪声能力. 该方法可以应用于火星/月球 雷达探测回波数据的反演以及地下分层结构特性的分析. 关键词： 电磁散射 分层介质 模拟退火算法 最优化     

土壤模型对地表电位影响及合理选取土壤模型方法研究

首次利用物理意义明确的模拟镜像法推导出三维复合分层土壤模型格林函数, 基于特定土壤模型, 分析了不同土壤配置下土壤模型对地表电位的影响. 结果表明, 在一定条件下土壤模型变化仅改变地表电位绝对值, 基本不改变地表电位差, 从理论上阐明了土壤参数变化对地表电位影响的物理机理. 针对如何选取合适土壤模型来准确计算流过变压器中性点的直流量难题, 提出了合理选取土壤模型的判据及其阈值, 避免了土壤模型选取的随意性和盲目性, 为准确评估流过变压器中性点直流量和直流接地极附近变电站选址提供理论依据. 关键词： 格林函数 模拟镜像法 直流偏磁 土壤模型