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71.
I. B. Sivaev V. I. Bragin V. I. Bregadze N. A. Votinova S. Sjoberg 《Russian Chemical Bulletin》2004,53(9):2092-2095
Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]– with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]– (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corresponding benzylamino derivatives [1-B10H9NH2CH2Ar]–.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2004–2007, September, 2004. 相似文献
72.
Komuraiah Buduma Niranjana Kumar A Satya Srinivas KVN Kotesh Kumar J Srinivas Chinde Anand Kumar Domatti Yogesh Kumar Paramjit Grover Ashok Tiwari Feroz Khan 《Journal of heterocyclic chemistry》2021,58(11):2078-2089
Design, synthesis, and bioactivity evaluation of novel mannich bases ( 2a-2j ) and triazole-chalcone derivatives ( 7a-7k ) of Eugenol 1 were reported. Among all the derivatives tested for antiproliferative activity, di-amine manich derivative 2b (32.92 μM), and 4-methoxy chalcone triazole derivative 7d (33.05 μM) significantly inhibited HepG2 cell lines when compared to the standard doxorubicin (37.29 μM). Whereas most of the compounds such as diethylamine 2a (17.75 μM), (aminomethyl) methane diamine 2b (17.02 μM), and bis (chloromethyl) amine 2c (20.12 μM) showed moderate to better inhibition towards MCF-7 cell lines. The synthesized analogues were also tested for antidiabetic and antiobesity potentials. Compounds 2f (55.50%), 2c (54.34%), 7g (55.5%), and 2a (55.5%) have shown moderate inhibitory potentials toward intestinal α-glucosidase enzyme when compared to the standard Acarbose (72.86%). Likewise, compounds 7d (82.95%), 7f (76.19%), 7g (74.81%), 7e (74.81%), and 2g (72.50%) have shown significant to moderate inhibitory potentials toward Pancreatic lipase enzyme when compared to the standard orlistat (91.10%). ROS induces life-threatening diseases like diabetes, cancer, etc., and antioxidants play a major role in controlling their production. Compounds 2c (99.81%), 2i (99.80%), 2d (99.26%), 2g (98.79%), and 2f (98.42%) have shown significant antioxidant profiles in ABTS assay when compared to the standard Trolox (99.07%). Further, In silico Molecular docking and pharmacokinetic screening of the eugenol derivatives complemented the in vitro results indicating the drug likeness of the obtained active compounds. 相似文献
73.
New metal based triazoles (1–12) have been synthesized by the interaction of novel Schiff base ligands (L1–L3) with the Co(II), Ni(II), Cu(II) and Zn(II) metal ions. The Schiff base ligands and their all metal(II) complexes have been thoroughly characterized using various physical, analytical and spectroscopic techniques. In vitro bacterial and fungal inhibition studies were carried out to examine the antibacterial and antifungal profile of the Schiff bases in comparison to their metal(II) complexes against two Gram‐positive, four Gram‐negative and six fungal strains. The bioactivity data showed the metal(II) complexes to have more potent antibacterial and antifungal activity than their uncomplexed parent Schiff bases against one or more bacterial and fungal species. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
74.
Infra-Red spectra of a series of substituted salicylaldehyde and 2-hydroxy-naphthaldehyde Schiff bases were used to investigate enol-keto tautomeric equilibrium. Two model compounds, namely, salicylidinaniline and naphthylidinequinolineamine Schiff bases were used to represent the enol and keto forms, respectively. From the IR spectra of the model compounds it was possible to assign the IR absorption for the C=O and the C=N groups in both the keto and the enol form. It was also possible to assign other absorptions which were either specific to the keto or the enol forms. Specific pattern were observed for all the studied compounds. 相似文献
75.
The polymeric coordination compounds have been synthesized using the dipotassium salt of N,N′‐di(carboxymethylene)terephthalaldehydediimine (K2SB1) or N,N′‐di(carboxyethylene)terephthalaldehydediimine (K2SB2) with manganese(II), cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II). The ligands have been characterized by 1H‐NMR, and 13C‐NMR spectra. The polychelates have been characterized by elemental analyses, magnetic measurements, thermogravimetric analyses, electronic spectra and infrared spectra. The coordination compounds are colored, and the central metal ions are octahedrally coordinated with two water molecules and the Schiff bases. The Schiff bases act as di‐negative tetradentate ligands, in which bonding occurs through two oxygen and two nitrogen atoms. The polymers are insoluble in all common organic solvents such as acetone, methanol, ethanol, N,N‐dimethylformamide and dimethylsulfoxide. 相似文献
76.
77.
In this paper we study an instance of projective Reed–Muller type codes, i.e., codes obtained by the evaluation of homogeneous polynomials of a fixed degree in the points of a projective variety. In our case the variety is an important example of a determinantal variety, namely the projective surface known as rational normal scroll, defined over a finite field, which is the basic underlining algebraic structure of this work. We determine the dimension and a lower bound for the minimum distance of the codes, and in many cases we also find the exact value of the minimum distance. To obtain the results we use some methods from Gröbner bases theory. 相似文献
78.
General acid‐catalyzed reaction can be enhanced by the addition of base. Self‐catalyzed esterification of benzoic acid and octan‐1‐ol was enhanced by the addition of certain base such as imidazole. The rate of the esterification was accelerated as the concentration of imidazole increased. Trans‐esterification of 4‐nitrophenyl acetate was promoted in chloroform by the mixture of benzoic acid and imidazole, but not by benzoic acid or imidazole alone. 相似文献
79.
α,β-unsaturated ester coupled with isocyanates or isothiocyanates to give the corresponding thioamides or amides in good yields by SmI2 in the presence of HMPA and t-BuOH in THF at-78°C within a few min. 相似文献
80.
I. Kraicheva P. Finocchiaro S. Failla 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2345-2354
The synthesis of three novel 5-methylfuryl-containing Schiff bases: N,N′-bis(5-methylfurfurylidene)-4,4′-diaminodiphenylmethane, N,N′-bis(5-methylfurfurylidene)-1,4-phenylenediamine, and N,N′-bis(5methylfurfurylidene)benzidine and the corresponding bis(aminophosphonates) derived from them, 4,4′-bis{N-methyl(diethoxyphosphonyl)-1-[(5-methyl)-2-furyl]} diaminodiphenylmethane, 1,4-bis { N-methyl(diethoxyphosphonyl)-1-[(5-methyl)-2-furyl]} diaminobenzene, and bis{N-methyl(diethoxyphosphonyl)-1-[(5-methyl)-2-furyl]}- benzidine, is reported. The compounds have been characterized by elemental analysis, TLC, IR, and NMR ( 1 H, 13 C, and 31 P) spectra. For comparison, new 13 C and 31 P NMR data of three furyl-containing analogues of the above bis(aminophosphonates) are also regarded. The NMR studies of the two series of bis(aminophosphonates) reveal the presence of one diastereomer (meso or racemic form). 相似文献