基于圆盘加载波导的THz分布作用振荡器的数值模拟

 提出了一种新的基于真空电子学的THz源——基于圆盘加载波导的THz分布作用振荡器（EIO）,它由圆盘加载波导输入谐振腔、漂移管和输出腔构成。利用2.5维电磁仿真软件UNIPIC对其进行了模拟研究,结果表明慢波结构的长度、漂移管的长度和输出腔的半径对输出功率和频率产生显著影响。经过最优化设计,在注电压为24.85 kV、电流为20 mA的条件下,仿真得出其中心频率为755.5 GHz、峰值功率为1.322 5 W的THz波。     

压力对硫醇分子膜电输运性质的影响

利用密度泛函理论和弹性散射格林函数方法,对硫醇分子膜的电学特性进行了理论模拟,计算结果表明,分子结的导电能力随着压力增加而增加,对单分子构成的分子结来说,电流的增加主要是由于电极距离的变化导致单个分子与电极的耦合增强,对于由多个分子构成的分子膜来说,由于外加压力的变化,导致分子结的链内隧穿和链间隧穿几率增大,从而导致导...     

Electron Transfer around a Molecular Corner

The distance dependence of electron transfer (ET) is commonly investigated in linear rigid rod‐like compounds, but studies of molecular wires with integrated corners imposing 90° angles are very rare. By using spirobifluorene as a key bridging element and by substituting it at different positions, two isomeric series of donor‐bridge‐acceptor compounds with either nearly linear or angled geometries were obtained. Photoinduced ET in both series is dominated by rapid through‐bond hole hopping across oligofluorene bridges over distances of up to 70 Å. Despite considerable conformational flexibility, direct through‐space and through‐solvent ET is negligible even in the angled series. The independence of the ET rate constant on the total number of fluorene units in the angled series is attributed to a rate‐limiting tunneling step through the spirobifluorene corner. This finding is relevant for multidimensional ET systems and grids in which individual molecular wires are interlinked at 90° angles.     

Die Korrektur des Bildes der Anger-Kamera (Teil II)

Ausgehend von der im ersten Teil begründeten Notwendigkeit, die mit der Szintillationskamera Impulsverteilung korrigieren zu müssen, wird in der vorliegenden Arbeit der Programmablanfplan für diese Korrekturrechnung mit Hilfe der elektronischen Datenverarbeitung (R 300) erläutert. Im gegenwärtigen Stadium der Entwicklung eines umfangreichen Konzepts zum Einsatz der EDV für die Szintigraphie – an der alle Nuklearmedizinischen Abteilungen der DDR beteiligt sind – erfolgt bei den Autoren die Ein- und ausgabe der Daten über Lochstreifen. Die Wirkung der Korrekturrechnung wird am homogenen Phantom selbst und an einer Pankreasunfersuchung demonstriert.     

Dicarboxylic imide‐substituted poly(p‐phenylene vinylenes) with high electron affinity

Synthesis of n‐type organic semiconductors with high electron mobilities, good environmental stability, and good processability is an urgent task in current organic electronics. This is because most of π‐conjugated materials are p‐type and prefer to transport positive hole carriers. In this article, a series of new dicarboxylic imide‐substituted poly(p‐phenylene vinylenes) (DI‐PPVs) were first synthesized. They exhibited a high electron affinity of 3.60 eV and thus are able to transport electrons. The polymers showed tunable solubility in common organic solvents and high chemical and thermal stability. They remain rigidity of the PPV backbone, and strong interchain π‐stacking was observed in thin films by X‐ray diffraction measurement. All these suggested that these polymers could serve as good candidates as n‐type semiconductors in organic electronic devices such as n‐channel field‐effect transistors and all polymer‐based solar cells. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 186–194, 2010     

Decoherence in elastic and polaronic transport via discrete quantum states

In this work we study the effect of decoherence on elastic and polaronic transport via discrete quantum states. Calculations are performed with the help of a nonperturbative computational scheme, based on Green’s function theory within the framework of polaron transformation (GFT-PT), where the many-body electron-phonon interaction problem is mapped exactly into a single-electron multi-channel scattering problem. In particular, the influence of dephasing and relaxation processes on the shape of the electrical current and shot noise curves is discussed in detail under linear and nonlinear transport conditions.