Li(AlxCo1-x)O2晶体中Co3+电子态的变化及对结构演化的影响

研究了应用于锂二次电池正极的新型高能量密度存贮材料Li(AlxCo1-x)O2 (x=01—05)的磁性.发现Al3+的掺杂可导致Co3+中d电子自旋态发生变化，即有部分d电子进入高自旋态.伴随Co3+中电子状态的改变，材料结构演化也发生了相应变化，表现为c/a比增大明显减缓，较好地解释了材料结构对Vegard定律的正偏离.这对材料的微观结构与性能设计具有重要意义. 关键词： 锂电池材料 Li（AlxCo1-x）O2 磁性 自旋态 结构演化     

Standardization of Methods for Characterizing the Surface Geometry of Solids

Since a comprehensive survey published in 1999 [1] much work was done in standardizing measuring methods to characterize the surface geometry of dispersed and/or porous solids and to certify reference materials. The present paper is an extension of a short communication [2]. It gives a survey on existing standards and reports on new drafts and proposals.     

Convergence of Computational Methods and Stability of Self-Balanced Stresses under Shrinkage of Spherical Inclusions of a Damageable Material

Some iterative methods for calculating self-balanced stresses under shrinkage of a ball inclusion enclosed in a spherical matrix of a physically nonlinear damageable material. The stability of this system was studied using methods of catastrophe theory. It has been established that the beginning of divergence of the proposed iterative processes coincides with the moment of transition of the system to an unstable position of equilibrium.     

一个来自振动理论反问题的矩阵方程

§ 1　ＩｎｔｒｏｄｕｃｔｉｏｎＬｅｔＲｎ×ｍｄｅｎｏｔｅｔｈｅｒｅａｌｎ×ｍｍａｔｒｉｘｓｐａｃｅ ,Ｒｎ×ｍｒ ｉｔｓｓｕｂｓｅｔｗｈｏｓｅｅｌｅｍｅｎｔｓｈａｖｅｒａｎｋｒ ,ＯＲｎ×ｎｔｈｅｓｅｔｏｆａｌｌｎ×ｎｏｒｔｈｏｇｏｎａｌｍａｔｒｉｃｅｓ,ＳＲｎ×ｎ(ＳＲｎ×ｎ≥ ,ＳＲｎ×ｎ>)ｔｈｅｓｅｔｏｆａｌｌｎ×ｎｒｅａｌｓｙｍｍｅｔｒｉｃ (ｓｙｍｍｅｔｒｉｃｐｏｓｉｔｉｖｅｓｅｍｉｄｅｆｉｎｉｔｅ ,ｐｏｓｉｔｉｖｅｄｅｆｉｎｉｔｅ)ｍａｔｒｉｃｅｓ.ＴｈｅｎｏｔａｔｉｏｎＡ>0 (≥ 0 ,<0 ,≤ 0 )ｍ…     

沉积铁钝化膜的傅立叶变换表面增强拉曼光谱

利用恒电流沉积技术、傅立叶变换表面增强拉曼散射技术现场研究了0 1mol/LNaOH溶液中铁金属电极在不同电位下的表面氧化物的组成。结果表明,在电极预钝化区,表面首先生成的Fe(OH)2可由拉曼谱图中出现的550cm-1表征,证实了以往的研究结果。进入钝化区,表面二价氧化物逐步转化为高价氧化物Fe3O4及α 、δ 和γ FeOOH。在电位回扫的过程中,各氧化产物的还原以及铁表面SERS活性的逐渐消失导致谱峰强度降低。     

Positive set‐operators of low complexity

The powerset operator, ??, is compared with other operators of similar type and logical complexity. Namely we examine positive operators whose defining formula has a canonical form containing at most a string of universal quantifiers. We call them ?‐operators. The question we address in this paper is: How is the class of ?‐operators generated ? It is shown that every positive ?‐operator Γ such that Γ(??) ≠ ??, is finitely generated from ??, the identity operator Id, constant operators and certain trivial ones by composition, ∪ and ∩. This extends results of [3] concerning bounded positive operators.     

Prefiltration technique via aggregation for constructing low‐density high‐quality factorized sparse approximate inverse preconditionings

This paper considers a new approach to a priori sparsification of the sparsity pattern of the factorized approximate inverses (FSAI) preconditioner using the so‐called vector aggregation technique. The suggested approach consists in construction of the FSAI preconditioner to the aggregated matrix with a prescribed sparsity pattern. Then small entries of the computed ‘aggregated’ FSAI preconditioning matrix are dropped, and the resulting pointwise sparsity pattern is used to construct the low‐density block sparsity pattern of the FSAI preconditioning matrix to the original matrix. This approach allows to minimize (sometimes significantly) the construction costs of low‐density high‐quality FSAI preconditioners. Numerical results with sample matrices from structural mechanics and thin shell problems are presented. Copyright © 2002 John Wiley & Sons, Ltd.     

Image Formation in Low Vacuum SEM

The role of positive gaseous ions in the formation of secondary electron images in low vacuum scanning electron microscopes is discussed. This paper describes the charging processes and related effects that occur during high vacuum imaging of insulators and then discusses the influence of ions on those processes. The ions are responsible for a number of phenomena, including distortion of the electric field above and below the specimen surface due to space charge, removal of excess negative charge from the specimen, alteration of the specimen surface barrier, and scavenging/filtering of the secondary electron emission. The resulting electron-specimen-ion interactions can give rise to interesting contrast effects that are unique to this class of instruments.     

三阶非线性时滞差分方程解的渐近性

研究了一类三阶非线性变滞量差分方程解的渐近性,给出了该类方程的非振动解当n→+∞时渐近趋于零或趋于某有限数值的几个充分条件.     

Direct and inverse estimates for a new family of linear positive operators

In the present paper we introduce a new family of linear positive operators and study some direct and inverse results in simultaneous approximation.