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61.
R. V. Golovnya 《Chromatographia》1979,12(8):533-538
Summary Equations modifying Rohrschneider's relationship between I and thermodynamical characteristics values are derived. Polarity in chromatography is discussed as a possibility of stationary phases or absorbents to enter into intermolecular interactions and is determined on the basis of the partial molar free energies of solution (G) of six test substances. A simple method for the calculation of stationary phase polarity in terms of G from retention indices and McReynolds constants is given. Equations are presented for the calculation of stationary phase selectivity utilizing G data tabulated for selected test substances. The thermodynamical basis of selecting a reference phase for a unified system expressing the selectivity of stationary phases which can also be applied for adsorbents is suggested. The energy equivalent to an index unit, Gi.u., is discussed. 相似文献
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64.
Mechanical behaviour of biodegradable agricultural films under real field conditions 总被引:6,自引:0,他引:6
D. Briassoulis 《Polymer Degradation and Stability》2006,91(6):1256-1272
The mechanical behaviour of various types of biodegradable materials depends on their chemical composition and additives, the processing characteristics and the application conditions. The environmental conditions during storage and usage of these materials strongly influence their mechanical properties and behaviour. Ageing and degradation during the useful lifetime of biodegradable agricultural films causes losses in the mechanical performance of the material, as measured by monitoring the evolution of some of the critical mechanical properties. Such losses may be comparable to the corresponding losses of the conventional polyethylene agricultural films due to ageing, or they may be more drastic. In the present paper, the overall mechanical and ageing/degradation behaviour of experimental specially designed and manufactured low-tunnel and mulching biodegradable films, exposed to full-scale field conditions is analysed. Selected critical mechanical properties of these films manufactured with different grades of Mater-Bi material and additives, different thickness and processing schemes and exposed to real cultivation conditions in four different locations in Europe are investigated in the laboratory and compared against the corresponding behaviour of conventional agricultural films at various stages of their exposure time. 相似文献
65.
With the accelerated accumulation of genomic sequence data, there is a pressing need to develop computational methods and advanced bioinformatics infrastructure for reliable and large-scale protein annotation and biological knowledge discovery. The Protein Information Resource (PIR) provides an integrated public resource of protein informatics to support genomic and proteomic research. PIR produces the Protein Sequence Database of functionally annotated protein sequences. The annotation problems are addressed by a classification-driven and rule-based method with evidence attribution, coupled with an integrated knowledge base system being developed. The approach allows sensitive identification, consistent and rich annotation, and systematic detection of annotation errors, as well as distinction of experimentally verified and computationally predicted features. The knowledge base consists of two new databases, sequence analysis tools, and graphical interfaces. PIR-NREF, a non-redundant reference database, provides a timely and comprehensive collection of all protein sequences, totaling more than 1,000,000 entries. iProClass, an integrated database of protein family, function, and structure information, provides extensive value-added features for about 830,000 proteins with rich links to over 50 molecular databases. This paper describes our approach to protein functional annotation with case studies and examines common identification errors. It also illustrates that data integration in PIR supports exploration of protein relationships and may reveal protein functional associations beyond sequence homology. 相似文献
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We investigate the convergence of sequences of Padé approximants for power series
相似文献
68.
K. Mørken 《Constructive Approximation》1991,7(1):195-208
In this paper it is shown how the algebraic product of two spline functions, each represented in terms of B-splines, can again be represented as a linear combination of suitable B-splines. As a corollary to this result we obtain an explicit representation of a given B-spline function in terms of B-splines of some arbitrary higher degree. This generalizes some known results for raising the degree by one. Recurrence relations for both products and degree raising are established that may be useful for computation.Communicated by Larry L. Schumaker. 相似文献
69.
The left-definite Legendre type boundary problem concerns the study of a fourth-order singular differential expressionM
k
[–] in a weighted Sobolev spaceH generated by a Dirichlet inner product. The fourth-order differential equation
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