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91.
Hai-Rong Guo Yuan Gao Ai-Dong Li Zhong Yan Di Wu 《Journal of Sol-Gel Science and Technology》2008,45(3):315-318
Pb0.56Sr0.44Zr0.52Ti0.48O3 (PSZT) inverse opal photonic crystals (PCs) have been synthesized by a process of self-assembly in combination with a sol–gel
procedure. PSZT inverse opals show pure perovskite structure with good orders in three dimensions. The evident photonic band
gaps have been observed in the transmittance spectra with a blue-shift phenomenon due to the decrease of opal template periods.
PSZT inverse opals also exhibit the reflection peaks in basic agreement with the calculated results. This three-dimensional
(3D) ordered PSZT inverse opals have shown interesting optical characteristics and potential applications in optoelectronic
and photonic devices. 相似文献
92.
Weiqiang Mu Dae‐Kue Hwang Robert P. H. Chang John B. Ketterson 《Journal of Raman spectroscopy : JRS》2011,42(5):941-944
We have developed a new substrate for surface‐enhanced Raman scattering (SERS) measurements involving a thin silver layer deposited over an ion‐etched TiO2 inverse opal. The latter is formed by chemically infiltrating a polystyrene opal array with TiO2 followed by a thermal decomposition of the spheres. The SERS response of the these substrates is examined for several sphere sizes and lasers wavelengths; the results show that such substrates yield high enhance factors, comparable to substrates involving a silver layer deposited directly on a polystyrene opal array. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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利用自组装胶体晶体模板导向电沉积制备氧化锌反蛋白石,利用液相沉积法在室温下制备复合氧化锌/氧化钛反蛋白石. 当对氧化锌反蛋白石进行20 min的液相沉积处理时,可以获得具有非密堆积三维有序多孔结构的氧化锌/氧化钛复合反蛋白石. 当液相沉积时间达到60 min时,则得到壁厚明显增强的纯氧化钛反蛋白石(TIO-LPD60). 讨论了样品成分和拓扑形貌变化的机理. 紫外光催化性能的初步研究显示,反蛋白石膜的光催化性能同时受到来自成分和拓扑形貌两方面的显著影响. 对比纯的氧化锌或者氧化钛反蛋白石,尽管样品具有相似的反蛋白石壁厚,ZnO/TiO2复合反蛋白石被证实具有明显增强的光催化活性. 然而,当反蛋白石壁厚从约52 nm增加到约90 nm时,TIO-LPD60显示了最高的光催化活性. 相似文献
95.
Birger Lange Nadine Metz Muhammad Nawaz Tahir Friederike Fleischhaker Patrick Theato Heinz‐Christoph Schrder Werner E. G. Müller Wolfgang Tremel Rudolf Zentel 《Macromolecular rapid communications》2007,28(20):1987-1994
Colloidal photonic crystals were prepared from monodisperse core–shell particles. The shell is hereby formed from a functional monomer, such as glycidylmethacrylate or different reactive ester monomers, which can perform chemical reactions and the core from a standard monomer, which yields highly monodisperse colloids. It was possible to crystallize the core–shell particles into artificial opals with excellent optical properties. Reactions on the functional surface of the colloids were carried out, which lead to a dramatic rise in the mechanical stability or to a functionalization of His‐tagged silicatein, which acts as nanoreactor to synthesize and immobilize gold nanoparticles from auric acid onto the core–shell colloids.
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Solar energy-harvesting materials have significantly contributed to the development of energy-saving applications for several decades. We have mainly used a new concept composed of the electrophoretic deposition technique and photonic crystal structural engineering to understand the tunable light-absorption and electronic conduction properties. A hexamolybdenum cluster compound (denoted as the Mo6 cluster) was successfully functionalized on a tin pyrophosphate semiconductor integrated within an inverse opal photonic crystal. The size of the periodical pores, surface modification, and chemical composition of the infiltration material of the inverse opal film have been investigated to control the photonic bandgap in the visible range and the efficiency of the deposited Mo6 cluster. The photoactive Mo6 clusters act as a visible light harvester and generate an efficient photo-induced current upon light absorption that is enhanced by a slow photon effect occurring at the photonic stopband edges. The electron and proton are transferred in the inorganic-organic network via hydrogen bonds by a hopping mechanism to generate a rapid photoconductivity response during light irradiation. Specific attention focused on the role of humidity and temperature regarding the reproducibility of the experiments and the photosensitivity of the nanocomposite. The suitable tunable photo-induced conduction property in organic-inorganic materials opens a new opportunity for the applicability of cluster-based compounds in visible optoelectronic devices. 相似文献