Fabrication of well‐aligned electrospun nanofibrous membrane based on fluorinated polyimide

We have fabricated novel nanofibrous fluorinated polyimide membranes on a specially designed collector, which is composed of conductive aluminum plates and glass insulator materials and can be removed from the apparatus, using an electrospinning method. We describe the structure and water flux properties of the nanofibrous fluorinated polyimide membranes. The electrospun nanofibers were deposited across the plates and uniaxially aligned to the collector. In addition, the multi‐layer stacked nanofibrous membranes, consisting of three‐dimensionally ordered nanopores, were produced. The pure water fluxes for the stacked membranes were measured, using a stirred dead‐end filtration cell, and were linearly decreased with an increasing deposition time, indicating that the nanopores formed in the nanofibrous membrane were further narrowed due to the regularly accumulated nanofibers. Copyright © 2009 John Wiley & Sons, Ltd.     

垂直水声通信中的伪随机序列精确定时算法*

针对垂直水声通信中时变多普勒引起的定时偏差问题,研究一种基于伪随机序列的迭代定时估计及补偿算法。该方法利用伪随机序列作为同步信号,分三步估计时变多普勒：采用低复杂度的模糊函数法粗补偿接收信号内的平均多普勒;通过迭代插值法实现残留时变多普勒的精确估计及补偿;利用基于信道相关函数的相位信息,纠正均衡后信号的偏转相位。为实现高阶海试数据的有效解调,采用基于伪随机序列均方误差的多通道加权合并方式,获得空间分集增益。仿真及海试数据处理结果证明所提方法具有良好的时变多普勒估计及补偿性能,同时对30个通道内的1024QAM数据进行合并处理,在500 m的通信距离下,误码率为0.04,信道容量达到7.6 bits/symbol。与传统数据帧结构相比,无需使用线性调频信号,可以提高有效数据传输率。     

Anisotropic shearlet transforms for L2

In this paper, we present a new anisotropic generalization of the continuous shearlet transformation. This is achieved by means of an explicit construction of a family of reproducing Lie subgroups of the symplectic group. We study the properties of this new family of anisotropic shearlet transformations. In particular, we provide an analog of the Calderón admissibility condition for anisotropic shearlet reproducing functions.     

Leader‐following consensus problem of heterogeneous multi‐agent systems with nonlinear dynamics using fuzzy disturbance observer

This article considers the leader‐following consensus problem of heterogeneous multi‐agent systems. The proposed multi‐agent system is consisted of heterogeneous agents where each agents have their own nonlinear dynamic behavior. To overcome difficulty from heterogeneous nonlinear intrinsic dynamics of agents, a fuzzy disturbance observer is adopted. In addition, based on the Lyapunov stability theory, an adaptive control method is used to compensate the observation error caused by the difference between the unknown factor and estimated values. Two numerical examples are given to illustrate the effectiveness of the proposed method. © 2013 Wiley Periodicals, Inc. Complexity 19: 20–31, 2014     

A hybrid FVM–LBM method for single and multi‐fluid compressible flow problems

The lattice Boltzmann method (LBM) has established itself as an alternative approach to solve the fluid flow equations. In this work we combine LBM with the conventional finite volume method (FVM), and propose a non‐iterative hybrid method for the simulation of compressible flows. LBM is used to calculate the inter‐cell face fluxes and FVM is used to calculate the node parameters. The hybrid method is benchmarked for several one‐dimensional and two‐dimensional test cases. The results obtained by the hybrid method show a steeper and more accurate shock profile as compared with the results obtained by the widely used Godunov scheme or by a representative flux vector splitting scheme. Additional features of the proposed scheme are that it can be implemented on a non‐uniform grid, study of multi‐fluid problems is possible, and it is easily extendable to multi‐dimensions. These features have been demonstrated in this work. The proposed method is therefore robust and can possibly be applied to a variety of compressible flow situations. Copyright © 2009 John Wiley & Sons, Ltd.     

Polyimides as cathodic materials in lithium batteries: Effect of the chemical structure of the diamine monomer

Polyimides are being investigated as alternative, environmentally friendly and safe organic electrode materials for lithium and sodium batteries. However, further improvements need the proper chemical design of these polymers. In this paper, the effect of chemical structure of polyimides on their performance as cathodic materials in lithium batteries was investigated in detail. More in particular, we studied polyimides based on seven different diamine monomers in combination with best performing naphthalenic dianhydride monomer. The first set included the so‐called cardo diamines possessing additional redox‐active carbonyl group with the goal to enhance the theoretical capacity of the polymer. Second, several aromatic diamines including additional functionalities such as cyclic amides, anthrone, or quinolidinium groups were investigated. Finally, aliphatic diamines, containing oxyethylene moieties and thus capable to increase the ionic conductivity of the resulting polymer system, were explored. Among the different polyimides, the “cardo” one based on naphthalenic dianhydride and aromatic aniline phthalein with an additional carbonyl group showed the best results in terms of battery performance. Such polyimide was capable to deliver up to 130 mAhg⁻¹ specific capacity (87% of the theoretical value) at 25 °C and at a current density of 250 mAg⁻¹ during 100 charge/discharge cycles. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 714–723     

Multi‐commutated Flow‐through Multi‐optosensing: A Tool for Environmental Analysis

Abstract

Multi‐commutation, which refers to the use of solenoid valves to construct the flow network, has been widely used for providing automation in flow injection analysis. In this paper, the coupling of multi‐commutation and multi‐optosensing is developed for the analysis of two pesticides in environmental water samples, fuberidazole and o‐phenylphenol. In optosensing, the use of the solid support allows the discrimination between the analytes and other compounds that, if measuring in solution, would interfere in the analysis; in addition, the sensitivity needed when facing environmental samples is obtained. The two analytes are separated by using C₁₈ silica gel as solid support, taking into account their different kinetics of sorption/desorption when interacting with the solid support microbeads; the separation is performed in the same flow‐cell where the sensing detection is carried out (by using an additional amount of solid support in the cell itself above the irradiated microzone), so both separation and determination are integrated in the cell. The native fluorescence of fuberidazole and o‐phenylphenol was simultaneously measured at 314/356 and 250/345 nm, respectively. The detection limits obtained were 0.18 and 6.1 ng mL^?1 for fuberidazole and o‐phenylphenol respectively, with a sampling frequency of about 12 samples per hour. A recovery study was performed in waters obtained for wells and rivers, with satisfactory results.     

Some considerations for high‐order ‘incremental remap’‐based transport schemes: edges,reconstructions, and area integration

The problem of two‐dimensional tracer advection on the sphere is extremely important in modeling of geophysical fluids and has been tackled using a variety of approaches. A class of popular approaches for tracer advection include ‘incremental remap’ or cell‐integrated semi‐Lagrangian‐type schemes. These schemes achieve high‐order accuracy without the need for multistage integration in time, are capable of large time steps, and tend to be more efficient than other high‐order transport schemes when applied to a large number of tracers over a single velocity field. In this paper, the simplified flux‐form implementation of the Conservative Semi‐LAgrangian Multi‐tracer scheme (CSLAM) is reformulated using quadratic curves to approximate the upstream flux volumes and Gaussian quadrature for integrating the edge flux. The high‐order treatment of edge fluxes is motivated because of poor accuracy of the CSLAM scheme in the presence of strong nonlinear shear, such as one might observe in the midlatitudes near an atmospheric jet. Without the quadratic treatment of upstream edges, we observe at most second‐order accuracy under convergence of grid resolution, which is returned to third‐order accuracy under the improved treatment. A shallow‐water barotropic instability also reveals clear evidence of grid imprinting without the quadratic correction. Consequently, these tests reveal a problem that might arise in tracer transport near nonlinearly sheared regions of the real atmosphere, particularly near cubed‐sphere panel edges. Although CSLAM is used as the foundation for this analysis, the conclusions of this paper are applicable to the general class of incremental remap schemes. Copyright © 2012 John Wiley & Sons, Ltd.     

On accuracy and efficiency of constrained reinitialization

The reinitialization, which is required to regularize the level set function, can be computationally expensive and hence is a determining factor for the overall efficiency of a level set method. However, it often has a significantly adverse impact on the accuracy of the level set solution. This short note is meant to shed light on the efficiency and accuracy issues of the reinitialization process. Using just one clearly defined level set propagation test case with an analytical solution the solutions obtained using a recently proposed efficient lower‐order constrained reinitialization (CR) scheme and standard low‐ and high‐order reinitialization schemes are juxtaposed to evidence the superiority of the novel CR formulation. It is shown that maintaining the location of the zero level set during the reinitialization is crucial for the accuracy and that the displacement caused by standard high‐order reinitialization schemes clearly outweighs the benefit of the high‐order smoothing of the level set function. Finally, results of a three‐dimensional problem are concisely reported to demonstrate the general applicability of the CR scheme. Copyright © 2009 John Wiley & Sons, Ltd.