Synthesis,characterization, and curing of well-defined allyl ether-maleate functional ester oligomers: Linear versus nonlinear structures

A series of allyl ether-maleate functional star-shaped esters with from one to four arms has been synthesized. The structures that have been made are an analogous series with increasing molecular weight and functionality where the increase in molecular weight has been made nonlinear, i.e., star-shaped. The resins are monodisperse in the sense that each arm has a well-defined structure and that, within a certain sample, only one type of molecule exists. The viscosity and rheological behavior of the resins have been studied. The curing kinetics of the star-shaped (branched) resins and the properties of the films formed have also been studied. These properties have been related to differences in functionality and to differences in the molecular architecture of the resins. © 1992 John Wiley & Sons, Inc.     

Synthesis and Structural Characterization of a Polyoxomolybdate HNa7[Mo36O112(H2O)16]·47H2O

A new polyoxomolybdate complex HNa7[Mo36O112(H2O)16]·47H2O 1 has been prepared in the beaker solution and characterized by single-crystal X-ray diffraction and elemental analyses. Crystal data: H127Mo36Na7O175, Mr = 6542.79, monoclinic, C2/c, a = 40.891(6), b =17.900(3), c = 25.580(4) (A), β = 125.673(2)°, V = 15210(4)(A)3, Z = 4, Dc = 2.857 g/cm3, F(000) =12464, μ = 3.013 mm-1, R = 0.0633 and wR = 0.1654 (I＞ 2σ(Ⅰ)). With the bridging sodium cations,the [Mo36O112(H2O)16]8- units in compound 1 are linked to form a one-dimensional structure, on the basis of which a three-dimensional architecture is further constructed via other sodium cations and complicated hydrogen bonds.     

问题与主义的联想

通过对中国传统建筑体系的再认识和反思,认清中国建筑的现状,走出认识的误区,思索中国现代建筑的发展方向.     

Spectral and energy efficiency for uplink massive MIMO systems with mixed-ADC architecture

In this paper, we introduce a mixed- analog-to-digital converter (ADC) architecture for massive multiple-input multiple-output (MIMO) systems and study the system’s performance mainly includes the achievable spectral efficiency and energy efficiency. In principle, the mixed-ADC architecture permits the one part of antennas at the base station (BS) are connected to speed and expensive full-resolution ADCs and the remaining part of the antennas are connected to the cheap low-resolution ADCs. By applying the general maximum-ratio combining detector, a tractable approximate expression for the achievable SE is obtained. Leveraging on the derived results, the effects of the number of BS antennas and the percent of the full-resolution ADCs on the achievable SE are investigated. Results show that the achievable SE increases with the percent of the full-resolution ADCs and the number of BS antennas. Based on a realistic power consumption model, we evaluate the energy efficiency for the considered mixed-ADC architecture. Moreover, under the certain achievable SE constraint, we maximize the energy efficiency by adjusting the number of low-resolution ADCs and the resolution bits of the corresponding ADC device. Numerical results showcase that the energy efficiency can be improved by enhancing the average transmitted power, and there exists an optimal number of resolution bits and the number of antennas to maximize the energy efficiency, which indicates that the application of mixed-ADC architecture has a great potential in future mobile communication system.     

"2018流固耦合力学在船舶与海洋新能源中的应用研究领域科学家论坛"学术综述

简要介绍了 2018年1月召开的"2018流固耦合力学在船舶与海洋新能源中的应用研究领域科学家论坛"的基本情况,对邀请报告进行了分专题学 术综述,对专家们在自由发言和集中研讨中针对流固耦合力学在船舶与海洋新能源领域的应用提出的前瞻性关键科学问题及未来研究方 向的观点进行了归纳总结.      

下一代自动测试系统体系结构研究进展

以下一代自动测试系统为研究对象,介绍了它的研制背景,分析了自动测试系统体系结构的开放性要求。简述了关键单元的筛选标准和发展过程,指出了基于关键单元建立的开放式体系结构的意义。研究了硬件结构组成及测试程序集的开发和运行的技术模型,说明了敏捷快速全球作战保障演示验证项目和关键单元的标准制定情况,为我军发展下一代自动测试系统提供参考。     

复杂产品虚拟试验支撑框架

VITA支撑框架作为虚拟试验验证的共性技术支撑平台,主要用于解决复杂航天产品研制试验过程中的异构性、实时性、互联互通等问题。本文提出了一套完整的VITA虚拟试验体系框架,讨论了它的研究背景及体系结构,研究了VITA运行中间件的技术架构,并进行了性能测试,介绍了基于中间件的扩展服务,介绍了VITA目前的应用情况,初步应用表明,VITA支撑框架为复杂产品研发过程提供了有力的虚拟试验技术支持,可在航空、航天等多个行业的复杂产品研发中进行应用。     

A novel one‐dimensional metal–organic framework with a μ‐cyanido‐argentate group: catena‐poly[[(5,5′‐dimethyl‐2,2′‐bipyridyl‐κ2N,N′)silver(I)]‐μ‐cyanido‐κ2N:C]

The design and synthesis of metal coordination and supramolecular frameworks containing N‐donor ligands and dicyanidoargentate units is of interest due to their potential applications in the fields of molecular magnetism, catalysis, nonlinear optics and luminescence. In the design and synthesis of extended frameworks, supramolecular interactions, such as hydrogen bonding, π–π stacking and van der Waals interactions, have been exploited for molecular recognition associated with biological activity and for the engineering of molecular solids.The title compound, [Ag(CN)(C₁₂H₁₂N₂)]_n, crystallizes with the Ag^I cation on a twofold axis, half a cyanide ligand disordered about a centre of inversion and half a twofold‐symmetric 5,5′‐dimethyl‐2,2′‐bipyridine (5,5′‐dmbpy) ligand in the asymmetric unit. Each Ag^I cation exhibits a distorted tetrahedral geometry; the coordination environment comprises one C(N) atom and one N(C) atom from substitutionally disordered cyanide bridging ligands, and two N atoms from a bidentate chelating 5,5′‐dmbpy ligand. The cyanide ligand links adjacent Ag^I cations to generate a one‐dimensional zigzag chain. These chains are linked together via weak nonclassical intermolecular interactions, generating a two‐dimensional supramolecular network.     

Two Zinc Architectures: A Mononuclear Complex and a 2D Wave-like Organic-inorganic Hybrid Layer

Self-assembly of Zn(NO3)2·6H2O and 2,3,5,6-tetrabromoterephthalic acid(H2TBTA) gave rise to two new zinc metal-organic frameworks,Zn(HTBTA)2(phen)2·H2O(1) and Zn(TBTA)1/2(μ2-OH)(H2O)·0.25EtOH(2).Complex 1 is a mononuclear molecule.The hydrogen bonding interactions further connect the mononuclear molecules to generate a 2D supramolecular architecture.Complex 2 is a 2D organic-inorganic hybrid layer framework constructed from 1D rod-shaped secondary building units.     

Effect of the molecular weight and architecture on the size and glass transition of arborescent polyisobutylenes

This article discusses the characterization of arborescent (hyperbranched) polyisobutylenes (arb‐PIBs) by size exclusion chromatography and differential scanning calorimetry, in comparison with linear PIB standards. The radius of gyration (〈r〉^1/2 = R_z), measured from the angle dependence of light scattering of high‐molecular‐weight arb‐PIBs, was significantly larger than the hydrodynamic radius (R_h) from size exclusion chromatography/viscometry, and the R_h values were significantly smaller than R_h of linear PIBs. The glass‐transition temperature of arb‐PIBs having a branch molecular weight higher than the critical entanglement molecular weight was dependent on both the total number‐average molecular weight and BR up to BR ～ 15. A modified Fox–Flory equation is proposed to describe the effect of architecture on the thermal transition. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1770–1776, 2006