全文获取类型
收费全文 | 49660篇 |
免费 | 2955篇 |
国内免费 | 2517篇 |
专业分类
化学 | 37710篇 |
晶体学 | 175篇 |
力学 | 497篇 |
综合类 | 650篇 |
数学 | 6515篇 |
物理学 | 9585篇 |
出版年
2023年 | 433篇 |
2022年 | 745篇 |
2021年 | 1752篇 |
2020年 | 1193篇 |
2019年 | 1280篇 |
2018年 | 998篇 |
2017年 | 1230篇 |
2016年 | 1538篇 |
2015年 | 1578篇 |
2014年 | 1716篇 |
2013年 | 2902篇 |
2012年 | 2386篇 |
2011年 | 2424篇 |
2010年 | 2177篇 |
2009年 | 2802篇 |
2008年 | 2706篇 |
2007年 | 3080篇 |
2006年 | 2352篇 |
2005年 | 1703篇 |
2004年 | 1565篇 |
2003年 | 1513篇 |
2002年 | 3890篇 |
2001年 | 1404篇 |
2000年 | 986篇 |
1999年 | 829篇 |
1998年 | 809篇 |
1997年 | 619篇 |
1996年 | 692篇 |
1995年 | 616篇 |
1994年 | 596篇 |
1993年 | 629篇 |
1992年 | 551篇 |
1991年 | 443篇 |
1990年 | 311篇 |
1989年 | 245篇 |
1988年 | 265篇 |
1987年 | 214篇 |
1986年 | 222篇 |
1985年 | 328篇 |
1984年 | 240篇 |
1983年 | 149篇 |
1982年 | 296篇 |
1981年 | 470篇 |
1980年 | 428篇 |
1979年 | 469篇 |
1978年 | 372篇 |
1977年 | 278篇 |
1976年 | 239篇 |
1974年 | 77篇 |
1973年 | 154篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
151.
Summary. We consider the spline collocation method for a class of parabolic pseudodifferential operators. We show optimal order convergence
results in a large scale of anisotropic Sobolev spaces. The results cover the classical boundary integral equations for the
heat equation in the general case where the spatial domain has a smooth boundary in the plane. Our proof is based on a localization
technique for which we use our recent results proved for parabolic pseudodifferential operators. For the localization we need
also some special spline approximation results in anisotropic Sobolev spaces.
Received May 17, 2001 / Revised version received February 19, 2002 / Published online April 17, 2002 相似文献
152.
用密度泛函B3LYP/ 6 3 1G(d)方法 ,对质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)弱相互作用体系进行了全自由度能量梯度优化 ,得到了该系列团簇的稳定结构及其对应的体系能量 .通过对构型的分析得出了质子化丙酮分子团簇 (CH3COCH3) nH+ (n =1~ 7)的生长规律 .计算了中性丙酮分子团簇体系的质子亲合能并总结出其变化趋势 .分析讨论了质子化团簇的红外振动光谱 ,发现质子化团簇的振动光谱普遍较中性环型团簇的振动光谱复杂 ,最强的振动峰来源于质子在溶剂壳中两个氧原子之间的振动 ,而且随着团簇尺寸的增加羰基的伸缩振动峰的数目也随之增多 相似文献
153.
A new method based on anion exchange resin separation and graphite furnace atomic absorption spectrometry (GFAAS) detection
is proposed for the determination of inorganic tin species. The result showed that Sn(IV) was quantitatively retained on the
resin when [HCl] = 9.0 mol · L−1, but Sn(II) could not be adsorbed on the resin under the same condition. Thus, a separation of Sn(II) and Sn(IV) has been
realized. When the concentration of NaOH solution was between 2.0–7.0 mol · L−1, Sn(IV) that adsorbed on the resin could be eluated from the resin completely. Meanwhile, under the atmosphere and the nitrogen
states, the translation between Sn(II) and Sn(IV) was investigated. Under the optimal conditions, the detection limit of Sn(IV)
is 0.40 μg · L−1 with RSD of 2.3% (n = 5, c = 2.0 μg · L−1). The proposed method was applied to the speciation analysis of tin in different water samples and the recovery of total
Sn was in the range of 98.7–101.7%. In order to verify the accuracy of the method, a certified reference water sample was
analyzed and the results obtained were in good agreement with the certified value. 相似文献
154.
A simple procedure for the synthesis of an important standard, isotopically enriched methylmercury, which is not commercially available, has been established successfully. The isotopically enriched standard synthesized is utilized in conventional isotope dilution mass spectrometry (IDMS), as well as in speciated IDMS (SIDMS), for determination of the true concentration of methylmercury in environmental samples. The CH3201Hg+ standard has been synthesized from commercially available 201HgO and tetramethyltin. The synthesis time required is 1 h at 60°C. The product is highly pure, yielding more than 90% as 201Hg in CH3201Hg+. Hazardous dimethylmercury does not occur during this synthesis procedure. The product synthesized was analyzed using high‐performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (ICP‐MS) and ICP‐MS alone in order to determine its concentration, isotopic composition and purity. The stability of the product was also evaluated for over 6 months and found to be stable at 4°C in the dark. The isotopically enriched methylmercury synthesized can be used in SIDMS and IDMS analyses as a standard. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
155.
156.
Yasufumi Hashimoto 《Journal of Number Theory》2007,122(2):324-335
In [P. Sarnak, Class numbers of indefinite binary quadratic forms, J. Number Theory 15 (1982) 229-247], it was proved that the Selberg zeta function for SL2(Z) is expressed in terms of the fundamental units and the class numbers of the primitive indefinite binary quadratic forms. The aim of this paper is to obtain similar arithmetic expressions of the logarithmic derivatives of the Selberg zeta functions for congruence subgroups of SL2(Z). As applications, we study the Brun-Titchmarsh type prime geodesic theorem and the asymptotic formula of the sum of the class number. 相似文献
157.
X.X. Guo 《Surface science》2004,549(3):211-216
We studied parallel conductivities of pure BaF2 films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al2O3(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF2 film and Al2O3 substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 1018/cm3 (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF2/BaF2 heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF2 [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect. 相似文献
158.
V. A. Petrosyan 《Russian Chemical Bulletin》1995,44(8):1353-1364
The results of studies on electrosynthesis involving carb- and heteroanions generated by cathodic deprotonation of acids (CDA), carried out in the laboratory headed by the author, are surveyed. These studies resulted in the elaboration of efficient electrochemical versions of the known Michaelis-Becker, Wittig-Horner, and Perkin reactions; electrochemical analogs of homolytic aromatic substitution, alkylation, heterocyclization,etc. were developed. Based on CDA, convenient and promising methods for preparing variousN-, O-, P-, S-, andC-alkylated and arylated substances have been developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1411–1422, August, 1995.The author is grateful to Professor V. A. Dorokhov, Professor V. P. Litvinov, and researchers from the laboratories of N. D. Zelinsky Institute of Organic Chemistry headed by them, who participated in joint studies.The work was carried out with financial support from the International Science Foundation (Grant No. MHYOO). 相似文献
159.
The electronic states of the Cr overlayers on TiO2(0 0 1) surfaces have been investigated using angle-resolved and resonant photoemission spectroscopy with synchrotron radiation. At lower coverages, Cr deposition on TiO2(0 0 1) creates two well separated in-gap emissions due to the formation of surface Ti3+ (3d1) ions and Cr3+ (3d3) ions. At higher coverages, the in-gap emission is developed into the 2-peak-structure emission of Cr 3d character. The corresponding state is considered to be of metallic nature from the viewpoint of the high ability of oxygen adsorption, but has no Fermi edge, indicating a possibility of forming small Cr clusters on TiO2(0 0 1) at this stage. 相似文献
160.
Alexander G. Ramm Alexandra B. Smirnova Angelo Favini 《Annali di Matematica Pura ed Applicata》2003,182(1):37-52
A nonlinear operator equation F(x)=0, F:H→H, in a Hilbert space is considered. Continuous Newton’s-type procedures based on a construction of a dynamical system with
the trajectory starting at some initial point x
0 and becoming asymptotically close to a solution of F(x)=0 as t→+∞ are discussed. Well-posed and ill-posed problems are investigated.
Received: June 29, 2001; in final form: February 26, 2002?Published online: February 20, 2003
This paper was finished when AGR was visiting Institute for Theoretical Physics, University of Giessen. The author thanks
DAAD for support 相似文献