首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   18059篇
  免费   2077篇
  国内免费   2702篇
化学   14801篇
晶体学   182篇
力学   844篇
综合类   277篇
数学   2181篇
物理学   4553篇
  2024年   50篇
  2023年   190篇
  2022年   411篇
  2021年   650篇
  2020年   652篇
  2019年   595篇
  2018年   518篇
  2017年   815篇
  2016年   926篇
  2015年   763篇
  2014年   1015篇
  2013年   1639篇
  2012年   1317篇
  2011年   1113篇
  2010年   968篇
  2009年   1048篇
  2008年   1039篇
  2007年   1082篇
  2006年   970篇
  2005年   865篇
  2004年   806篇
  2003年   674篇
  2002年   596篇
  2001年   518篇
  2000年   526篇
  1999年   475篇
  1998年   430篇
  1997年   374篇
  1996年   342篇
  1995年   276篇
  1994年   284篇
  1993年   252篇
  1992年   151篇
  1991年   95篇
  1990年   85篇
  1989年   53篇
  1988年   51篇
  1987年   27篇
  1986年   39篇
  1985年   40篇
  1984年   33篇
  1983年   13篇
  1982年   30篇
  1981年   18篇
  1980年   4篇
  1979年   6篇
  1977年   5篇
  1969年   1篇
  1967年   1篇
  1959年   4篇
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
91.
Abdullah Bal   《Optik》2004,115(7):295-300
A new type of optoelectronic cellular neural network has been developed by providing the capability of coefficients adjusment of cellular neural network (CNN) using Widrow based perceptron learning algorithm. The new supervised cellular neural network is called Widrow-CNN. Despite the unsupervised CNN, the proposed learning algorithm allows to use the Widrow-CNN for various image processing applications easily. Also, the capability of CNN for image processing and feature extraction has been improved using basic joint transform correlation architecture. This hardware application presents high speed processing capability compared to digital applications. The optoelectronic Widrow-CNN has been tested for classic CNN feature extraction problems. It yields the best results even in case of hard feature extraction problems such as diagonal line detection and vertical line determination.  相似文献   
92.
Gel polymer electrolyte (GPE) films comprising of poly(vinylidenefluoride), propylene carbonate, ethylene carbonate and zinc trifluoromethane sulfonate are prepared and characterized. The composition of GPE is optimized to contain minimum liquid components with a maximum specific conductivity of 3.94×10−3 S cm−1 at (25±1) °C. A detailed investigation on the properties such as ionic conductivity, transport number, electrochemical stability window, reversibility of Zn/Zn2+ couple and Zn/gel electrolyte interfacial stability have been carried out. The ionic conductivity follows a VTF behaviour with an activation energy of about 0.0014 eV. Cationic transport number varies from 0.51 at 25 °C to 0.18 at 70 °C. Several cells have been assembled with GPE as the electrolyte, zinc as the anode, γ-MnO2 as the cathode and their charge–discharge behaviour followed. Capacity values of 105, 82, 64 and 37 mAh/g of MnO2 have been achieved at 10, 50, 100 and 200 μA/cm2 discharge current densities, respectively. The discharge capacity values are almost constant for about 55 cycles for all values of current densities. Cyclic voltammetric study of MnO2 electrode in Zn/GPE/MnO2 cell clearly shows intercalation/deintercalation of Zn2+.  相似文献   
93.
The effects of the blend ratio and initiating system on the viscoelastic properties of nanostructured natural rubber/polystyrene‐based interpenetrating polymer networks (IPNs) were investigated in the temperature range of ?80 to 150 °C. The studies were carried out at different frequencies (100, 50, 10, 1, and 0.1 Hz), and their effects on the damping and storage and loss moduli were analyzed. In all cases, tan δ and the storage and loss moduli showed two distinct transitions corresponding to natural rubber and polystyrene phases, which indicated that the system was not miscible on the molecular level. However, a slight inward shift was observed in the IPNs, with respect to the glass‐transition temperatures (Tg's) of the virgin polymers, showing a certain degree of miscibility or intermixing between the two phases. When the frequency increased from 0.1 to 100 Hz, the Tg values showed a positive shift in all cases. In a comparison of the three initiating systems (dicumyl peroxide, benzoyl peroxide, and azobisisobutyronitrile), the dicumyl peroxide system showed the highest modulus. The morphology of the IPNs was analyzed with transmission electron microscopy. The micrographs indicated that the system was nanostructured. An attempt was made to relate the viscoelastic behavior to the morphology of the IPNs. Various models, such as the series, parallel, Halpin–Tsai, Kerner, Coran, Takayanagi, and Davies models, were used to model the viscoelastic data. The area under the linear loss modulus curve was larger than that obtained by group contribution analysis; this showed that the damping was influenced by the phase morphology, dual‐phase continuity, and crosslinking of the phases. Finally, the homogeneity of the system was further evaluated with Cole–Cole analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1680–1696, 2003  相似文献   
94.
介绍一种采用环烯烃聚合物镀膜的中空光纤结构,阐述其传输特性,说明其使用特点,指出它在工业和医疗等领域中的应用前景。  相似文献   
95.
In this paper, we report the conducting and electrochemical properties of a homogeneous V2O5-SiO2 xerogel composite obtained from the simultaneous polymerization in both inorganic components (Si-O and V-O based polymers) forming an interpenetrating polymer network, where a mutual “solubility” due to cross-links and entanglements was observed. The presence of V2O5 inside the silica matrix has a strong effect on electrical conductivity; measurements showed room temperature conductivity almost 1000 times higher than what is found in the literature. In addition, the electrochemical behavior is quite similar to that found in V2O5 xerogel. Moreover, the effects of thermal treatment on the conducting and electrochemical properties were investigated. It was found that both properties were improved with no significant effect on V2O5 xerogel layered structure.  相似文献   
96.
毛细管放电X光激光装置中的预脉冲电源   总被引:2,自引:2,他引:0       下载免费PDF全文
 针对目前毛细管放电X 光激光装置产生的预脉冲电流幅值过大、持续时间较短的问题,提出了增加预脉冲开关抑制原有预脉冲,再外加由脉冲成形网络组成的预脉冲发生器,产生所需预脉冲的改造方案。可在主脉冲来临之前产生幅度10~50A,持续时间约17μs的方波预脉冲电流,来满足毛细管放电泵浦类氖氩X光激光实验的需要。  相似文献   
97.
Mesoporous polymer microspheres with gold (Au) nanoparticles inside their pores were prepared considering their surface functionality and porosity. The Au/polymer composite microspheres prepared were characterized by transmission electron microscope (TEM), X‐ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) techniques. The results showed that the adsorption of Au nanoparticles could be increased by imparting the pore structure and surface‐functional groups into the supporting polymer microspheres (in this study, poly (ethylene glycol dimethacrylate‐co‐acrylonitrile) and poly (EGDMA‐co‐AN) system). Above all, from this study, it was established that the porosity of the polymer microspheres is the most important factor that determines the distribution and adsorption amount of face‐centered cubic (fcc) Au nanoparticles in the final products. Our study showed that the continuous adsorption of Au nanoparticles with the aid of the large surface area and surface interaction sites formed more favorably the Au/polymer composite microspheres. The BET measurements of Au/poly(EGDMA‐co‐AN) composite microspheres reveals that the adsorption of Au nanoparticles into the pores kept the pore structure intact and made it more porous. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5627–5635, 2004  相似文献   
98.
本文在分析光纤主干网和本地接入服务市场上电信运营商的供给行为的基础上,首先证明了拥有主干网的运营商愿意租出自己的部分光纤,接着分析证明了上述两市场上使投资更倾向于过度的乘数效应,并进一步证明网络外部性使乘数效应更加明显.旨在对我国电信运营市场发展给出一些参考意见.  相似文献   
99.
从大型复杂武器装备系统的具体特点出发,运用基于神经网络的评价方法,构建了大型复杂武器装备质量综合评价模型。实证分析的结果表明该方法得出的结果与实际情况相符。  相似文献   
100.
四种多变量校准方法在FTIR多组分分析中的性能比较   总被引:1,自引:0,他引:1  
本文对四种多变量校准方法--经典最小二乘法(CLS),偏最小二乘法(PLS),卡尔曼滤波法(KFM)以及人工神经网络法(ANN)--在多组分浓度分析方面的性能进行了比较。选择五种红外谱图严重混叠的大气有机毒物--1,3-丁二烯,苯,邻二甲苯,氯苯和丙烯醛--作为分析对象。分别计算各种方法对该5组分体系的平均预测误差MPE和平均相对误差MRE进行比较。结果表明,偏最小二乘法在处理这类问题中是最稳健的方法。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号