全文获取类型
收费全文 | 9144篇 |
免费 | 1125篇 |
国内免费 | 389篇 |
专业分类
化学 | 5769篇 |
晶体学 | 49篇 |
力学 | 624篇 |
综合类 | 106篇 |
数学 | 602篇 |
物理学 | 3508篇 |
出版年
2024年 | 13篇 |
2023年 | 96篇 |
2022年 | 146篇 |
2021年 | 310篇 |
2020年 | 276篇 |
2019年 | 301篇 |
2018年 | 243篇 |
2017年 | 264篇 |
2016年 | 394篇 |
2015年 | 335篇 |
2014年 | 418篇 |
2013年 | 798篇 |
2012年 | 534篇 |
2011年 | 483篇 |
2010年 | 385篇 |
2009年 | 523篇 |
2008年 | 536篇 |
2007年 | 589篇 |
2006年 | 523篇 |
2005年 | 379篇 |
2004年 | 374篇 |
2003年 | 364篇 |
2002年 | 287篇 |
2001年 | 246篇 |
2000年 | 259篇 |
1999年 | 205篇 |
1998年 | 237篇 |
1997年 | 129篇 |
1996年 | 125篇 |
1995年 | 101篇 |
1994年 | 114篇 |
1993年 | 76篇 |
1992年 | 73篇 |
1991年 | 67篇 |
1990年 | 39篇 |
1989年 | 65篇 |
1988年 | 49篇 |
1987年 | 33篇 |
1986年 | 32篇 |
1985年 | 24篇 |
1984年 | 45篇 |
1983年 | 16篇 |
1982年 | 28篇 |
1981年 | 20篇 |
1980年 | 17篇 |
1979年 | 21篇 |
1978年 | 16篇 |
1977年 | 8篇 |
1976年 | 14篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
11.
E. C. Ferreira J. A. P. da Costa J. A. K. Freire G. A. Farias V. N. Freire 《Applied Surface Science》2002,190(1-4):191-194
Confined excitons in non-abrupt GaAs/AlxGa1−xAs single quantum wells are studied. The graded interfaces are described taking into account fluctuations in their thickness a and positioning with respect to the abrupt interface picture. Numerical results for confined (0,0),(1,1) and (0,2) excitons in GaAs/Al0.3Ga0.7As quantum wells show that while the interfacial fluctuations produce small changes (<0.5 meV) in the exciton binding energies, the confined exciton energies can be red- or blue-shifted as much as 25 meV for wells with mean width of 50 Å and 2 ML wide interfaces. 相似文献
12.
13.
G. S. Asanov 《Foundations of Physics Letters》2002,15(2):199-207
Granted the post-Lorentzian relativistic kinematic transformations are described in the Finslerian framework, the uniformity between the actual light-velocity anisotropy change and the anisotropic deformation of measuring rods can be the reason proper for the null results of the Michelson-Morley-type experiments at the first-order level. 相似文献
14.
F. F. Maia Jr. J. A. K. Freire G. A. Farias V. N. Freire E. F. da Silva Jr. 《Applied Surface Science》2002,190(1-4):247-251
The excitonic properties of a ZnSe/ZnSxSe1−x strained quantum well (QW) are calculated taking into account interface effects. Numerical results obtained with ZnS0.18Se0.82/ZnSe QWs show that graded interfaces can be responsible for a strong broadening of excitonic spectra. 相似文献
15.
X-ray diffraction patterns of nanocrystalline Fe-Cu-Nb-Si-B (FINEMET) alloys reveal that bcc α-Fe/α-FeSi crystallites with
the average grain size of 20(5) nm are dispersed in amorphous matrix. Enhanced electron—electron interaction (EEI) and quantum
interference (QI) effects as well as electron-magnon (and/or electron-spin fluctuation) scattering turn out to be the main
mechanisms that govern the temperature dependence of resistivity. Of all the inelastic scattering processes, inelastic electron-phonon
scattering is the most effective mechanism to destroy phase coherence of electron wave functions. The diffusion constant,
density of states at the Fermi level and the inelastic scattering time have been estimated, for the first time, for the alloys
in question
Article presented at the International Symposium on Advances in Superconductivity and Magnetism: Materials, Mechanisms and
Devices, ASMM2D-2001, 25–28 September 2001, Mangalore, India. 相似文献
16.
B.I. Sturman A.S. Gorkunova K.H. Ringhofer 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(2):291-297
We investigate analytically and numerically the influence of the type of the photorefractive nonlinear response on the periodic
states (attractors) which occur during feedback controlled 2W-coupling and correspond to almost 100% diffraction efficiency
of the dynamic index grating. In addition to the case of the local response typical, for example, for LiNbO3 crystals we consider the cases of nonlocal (diffusive) response (BaTiO3, SBN) and resonant response (DC-biased BSO, BTO, and BGO crystals). It is shown that the conditions for the transition to
the periodic states and their apparent characteristics are strongly different for the two limiting cases above.
Received 16 July 2002 / Received in final form 29 October 2002 Published online 4 March 2003 相似文献
17.
3-Hydroxy-4-hydroxymethyl pyrrolidin-2-ones, easily prepared from the Baylis–Hillman adduct 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate, are useful intermediates in the synthesis of bioactive compounds. In order to understand the mechanism involved in this reaction, vibrational and Montecarlo molecular mechanics conformational analysis on 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate were carried out, confirming the existence of a low energy intramolecular H-bonded five-member ring. 相似文献
18.
Morey Timothy E. Varshney Manoj Flint Jason A. Seubert Christoph N. Smith W. Brit Bjoraker David G. Shah Dinesh O. Dennis Donn M. 《Journal of nanoparticle research》2004,6(2):159-170
Background: Although microemulsion-based nanoparticles (MEs) may be useful for drug delivery or scavenging, these benefits must be balanced against potential nanotoxicological effects in biological tissue (bio-nano interface). We investigated the actions of assembled MEs and their individual components at the bio-nano interface of thrombosis and hemolysis in human blood.
Methods: Oil-in-water MEs were synthesized using ethylbutyrate, sodium caprylate, and pluronic F-68 (ME4) or F-127 (ME6) in 0.9% NaClw/v. The effects of MEs or components on thrombosis were determined using thrombo-elastography, platelet contractile force, clot elastic modulus, and platelet counting. For hemolysis, ME or components were incubated with erythrocytes, centrifuged, and washed for measurement of free hemoglobin by spectroscopy.
Results and conclusions: The mean particle diameters (polydispersity index) for ME6 and ME4 were 23.6 ± 2.5 nm (0.362) and 14.0 ± 1.0 nm (0.008), respectively. MEs (0, 0.03, 0.3, 3 mM) markedly reduced the thromboelastograph maximal amplitude in a concentration-dependent manner (49.0 ± 4.2, 39.0 ± 5.6, 15.0 ± 8.7, 3.8 ± 1.3 mm, respectively), an effect highly correlated (r2 = 0.94) with similar changes caused by pluronic surfactants (48.7 ± 10.9, 30.7 ± 15.8, 20.0 ± 11.3, 2.0 ± 0.5) alone. Neither oil nor sodium caprylate alone affected the thromboelastograph. The clot contractile force was reduced by ME (27.3 ± 11.1–6.7 ± 3.4 kdynes/cm2, P = 0.02, n = 5) whereas the platelet population not affected (175 ± 28–182 ± 23 106/ml, P = 0.12, n = 6). This data suggests that MEs reduced platelet activity due to associated pluronic surfactants, but caused minimal changes in protein function necessary for coagulation. Although pharmacological concentrations of sodium caprylate caused hemolysis (EC50 = 213 mM), MEs and pluronic surfactants did not disrupt erythrocytes. Knowledge of nanoparticle activity and potential associated nanotoxicity at this bio-nano interface enables rational ME design for in vivo applications. 相似文献
19.
The Raman shifts of nanocrystalline GaSb excited by an Ar^ ion laser at wavelengths 514.5, 496.5, 488.0, 476.5,and 457.9nm are studied by an SPEX-1403 laser Raman spectrometer respectively, and they are explained by phonon confinement, tensile stress, resonant Raman scattering and quantum size effects. The Stokes and anti-Stokes Raman spectra of GaSb nanocrystals strongly support the Raman feature of GaSb nanocrystals. The calculated optical spectra compare well with experimental data on Raman scattering GaSb nanocrystals. 相似文献
20.
O. Castaños 《Journal of Molecular Spectroscopy》2007,241(1):51-60
A simple algebraic approach to calculate general Franck-Condon overlaps is extended to evaluate non-Condon factors for two one-dimensional harmonic oscillators. The method is based on the use of eigenstates of the harmonic oscillator annihilation operator which allows to obtain in terms of a multi-dimensional Hermite polynomial the overlap of harmonic oscillator functions associated with different Born-Oppenheimer potentials. The presented approach is self-contained, only basic concepts of quantum mechanics associated with the harmonic oscillator system are needed. The obtained expression for the Franck-Condon overlaps is similar to the Ansbacher’s formula and equivalent to the one calculated by Malkin and Man’ko. However our final expression has the advantages that only real numbers are involved and it is straightforward to get the limit case of equal frequencies. Concerning the non-Condon factors two approaches leading to different formulas are considered, both of which reduce to triple sums of products of three Hermite polynomials. 相似文献