全文获取类型
收费全文 | 43659篇 |
免费 | 4741篇 |
国内免费 | 4167篇 |
专业分类
化学 | 39309篇 |
晶体学 | 648篇 |
力学 | 1975篇 |
综合类 | 271篇 |
数学 | 1073篇 |
物理学 | 9291篇 |
出版年
2024年 | 80篇 |
2023年 | 465篇 |
2022年 | 970篇 |
2021年 | 1070篇 |
2020年 | 1421篇 |
2019年 | 1336篇 |
2018年 | 1370篇 |
2017年 | 1839篇 |
2016年 | 2223篇 |
2015年 | 1891篇 |
2014年 | 1989篇 |
2013年 | 4109篇 |
2012年 | 2994篇 |
2011年 | 2668篇 |
2010年 | 2267篇 |
2009年 | 2691篇 |
2008年 | 2326篇 |
2007年 | 2614篇 |
2006年 | 2271篇 |
2005年 | 1990篇 |
2004年 | 1790篇 |
2003年 | 1511篇 |
2002年 | 1325篇 |
2001年 | 1020篇 |
2000年 | 1028篇 |
1999年 | 908篇 |
1998年 | 820篇 |
1997年 | 715篇 |
1996年 | 704篇 |
1995年 | 654篇 |
1994年 | 542篇 |
1993年 | 462篇 |
1992年 | 401篇 |
1991年 | 378篇 |
1990年 | 277篇 |
1989年 | 235篇 |
1988年 | 256篇 |
1987年 | 228篇 |
1986年 | 156篇 |
1985年 | 120篇 |
1984年 | 129篇 |
1983年 | 42篇 |
1982年 | 89篇 |
1981年 | 54篇 |
1980年 | 31篇 |
1979年 | 35篇 |
1978年 | 13篇 |
1977年 | 9篇 |
1976年 | 8篇 |
1973年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
101.
本文给出了对高功率横流CO_2激光器脉冲预电离过程的理论和实验研究.表明了预电离过程中光电离的重要作用.实验结果表明,脉冲预电离可增大高功率横流CO_2.激光器的pd值(p为放电气压、d为放电间隔),增大放电区注入功率密度.对于提高此类型激光器的放电稳定性和输出激光功率是一种技术简单而有效的手段. 相似文献
102.
Ralf Jäger Anatolij I. Saprykin J. Sabine Becker Hans -Joachim Dietze José A. C. Broekaert 《Mikrochimica acta》1997,125(1-4):41-44
The analytical capabilities of a high-resolution mass spectrometer in combination with a 13.56 MHz glow discharge ion source for the analysis of semiconducting materials (silicon carbide and gallium arsenide) were studied. It was shown that single positively charged ions of sample material have about 10 eV higher average energy than the ions of the discharge and residual gas. Therefore effective energy separation of the ions of analyte from the ions of the discharge and residual gas was achieved by adjusting the ion transfer optics (breadth and position of energy slit), which improves the analytical capabilities of the developed method.Some analytical applications are presented to illustrate the performance of r.f. GDMS for the bulk analysis of semiconducting materials. The results of the trace element analysis of gallium arsenide and silicon carbide samples are compared with data of independent methods (LIMS, ICP-AES, SIMS).Dedicated to Professor Dr. rer. nat. Dr. h.c. Hubertus Nickel on the occasion of his 65th birthdayOn leave from the Institute of Inorganic Chemistry, 630090 Novosibirsk, Russia 相似文献
103.
A. S. Lobach B. P. Tarasov Yu. M. Shul'ga A. A. Perov A. N. Stepanov 《Russian Chemical Bulletin》1996,45(2):464-465
Fullerene deuteride was obtained by the reaction of deuterium with solid palladium fulleride C60Pd4.9 under fairly mild conditions. The compound was identified by FD-MS, UV-Vis and IR spectroscopies, and TLC.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 483–484, February, 1996 相似文献
104.
The stability of Ochratoxin A during its extraction using different extraction techniques has been evaluated. Microwave-assisted extraction and pressurised liquid extraction, in addition to two other reference methods of extraction, i.e. ultrasound-assisted and magnetic stirring-assisted extraction, were evaluated. The effect of extraction temperature using the cited techniques was checked.The results show that Ochratoxin A can be extracted using microwave-assisted extraction at temperatures up to 150 °C without degradation. Pressurised liquid extraction can be used at temperatures up to 100 °C, for extraction times of less than 30 min. Further, both ultrasound-assisted extraction and magnetic stirring extraction can be applied at temperatures up to 65 °C.High-performance liquid chromatography combined with fluorescence detection using a Chromolith RP-18e column at a flow rate of 5 mL min−1 was used to quantify the Ochratoxin A. The retention time for the Ochratoxin A was 1.3 min. The limits of detection (LOD) and of quantification (LOQ) were 0.03 and 0.10 μg L−1, respectively. 相似文献
105.
HPLC-MS/MS技术在中华绒螯蟹硝基呋喃类代谢物残留量检测中的应用 总被引:3,自引:0,他引:3
建立了中华绒螯蟹中硝基呋喃类代谢物残留量的液相色谱-串联质谱检测方法.取均质后的中华绒螯蟹可食部分样品,用盐酸水解组织中蛋白结合代谢物,经2-硝基苯甲醛37℃过夜衍生化,调节pH值至约7.0~7.4后,用乙酸乙酯提取,正己烷净化.选用电喷雾离子源,在正离子、多反应监测方式模式下进行定性,以同位素内标法进行定量.方法的检出限为0.5 μg·kg-1,工作曲线的线性范围为1.25~50.0 μg·L-1.在添加浓度为0.5~10.0 μg·kg-1的范围内,AMOZ、SEM、AHD和AOZ的回收率分别在92.8%~106%、84.5%~94.6%、80.6%~98.6%和88.4%~105%之间,相对标准偏差均小于10%. 相似文献
106.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
107.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献
108.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
109.
110.