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91.
HPLC-MS/MS技术在中华绒螯蟹硝基呋喃类代谢物残留量检测中的应用 总被引:3,自引:0,他引:3
建立了中华绒螯蟹中硝基呋喃类代谢物残留量的液相色谱-串联质谱检测方法.取均质后的中华绒螯蟹可食部分样品,用盐酸水解组织中蛋白结合代谢物,经2-硝基苯甲醛37℃过夜衍生化,调节pH值至约7.0~7.4后,用乙酸乙酯提取,正己烷净化.选用电喷雾离子源,在正离子、多反应监测方式模式下进行定性,以同位素内标法进行定量.方法的检出限为0.5 μg·kg-1,工作曲线的线性范围为1.25~50.0 μg·L-1.在添加浓度为0.5~10.0 μg·kg-1的范围内,AMOZ、SEM、AHD和AOZ的回收率分别在92.8%~106%、84.5%~94.6%、80.6%~98.6%和88.4%~105%之间,相对标准偏差均小于10%. 相似文献
92.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
93.
Longlan Cui Hong Xu Ping He Keiko Sumitomo Yoshinori Yamaguchi Hongchen Gu 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5285-5295
A hybrid emulsion polymerization was formulated for synthesizing Fe3O4/polystyrene composite latex. This system, containing binary droplets that are magnetic (Mag)‐droplets with a diameter of 100–200 nm and styrene (St)‐droplets with a diameter of 3–4 μm, was obtained by mixing Mag‐miniemulsion and St‐macroemulsion. With extremely low surfactants concentration (?critical micelle concentration, CMC), the nucleated loci are selectively controlled in the Mag‐droplets, as the result of smaller droplet size and larger surface ratio. Both water‐soluble potassium persulfate (KPS) and oil‐soluble 2,2′‐azobis(2‐isobutyronitrile) was adopted to initiate the polymerization. In the presence of KPS, magnetic polystyrene latices with particles size of 60–200 nm, narrow size distribution, and high magnetite content (86 wt % measured by TGA) were attained successfully. The synthesized magnetic Fe3O4/polystyrene latices assembled into well‐ordered hexagonal structure in the surface of a carbon supported copper grid. The influence of various parameters on various aspects of the as‐synthesized Fe3O4/polystyrene was investigated in detail: type of initiator on composite morphology, feed ratio of Mag‐miniemulsion and St‐macroemulsion on magnetite content, and hydrophobic agent or amount of surfactant on size and size distribution. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5285–5295, 2007 相似文献
94.
On‐line coupling of LC and ICP‐MS has been used for fractionation and detection of species of Cu, Fe, I, Se and Zn in human serum. It has been shown that anion exchange chromatography provided better separation capability (both intra‐ and inter‐element) than size‐exclusion chromatography. The mobile phases for ion exchange chromatography consisted of Tris–HNO3 buffer and ammonium salt (nitrate, acetate or formate). Formate was found to be the best mobile phase counter ion, enabling good chromatographic separation, and is acceptable for mass spectrometry too. The quantitative evaluation of element concentrations adhering to individual fractions was performed by the peak area normalization method. The repeatability of results ranged from 3 to 15% (depending on the element concentration level) and represented the main part of the result uncertainty. The accuracy of Cu and Zn fraction determinations was confirmed by comparison with the isotope dilution technique. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
95.
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97.
简析"静止液体内部压强公式验证"实验的设计策略 总被引:1,自引:1,他引:0
“静止液体内部压强公式验证”在现行教材中有两种实验方法。通过分析实验的设计策略,说明其作用、效果及操作上的困难,指出合理的与不合理诸因素,从而提出改进实验的方法,化难为易,提高实验教学效果。 相似文献
98.
1 Introduction Inrecentyears,boththetheoreticalandexperimentalinvestigationsonlasercoolingandtrappinghavebecomeoneofthemajorfieldsinatomic,molecularandoptical physics[1~ 8] .Thedevelopmentoflasercoolingandtrappingtechnologyisimportantfortheapplicationssu… 相似文献
99.
用波导本征模展开方法对用于高功率微波发射系统的方角锥高斯馈源口面场进行分析,提出结合馈源远场辐射特性和避免高功率击穿折衷选定相应的高斯模注腰半径,进而确定多个波导模幅值,从而为运用模匹配或耦合波理论设计高斯馈源提供依据。 相似文献
100.
The stationary and the time-dependent homogeneous ordered states in convection may both become unstable against localized perturbations. Defects are then created and they may contribute to the disorganization of the homogeneous state. We present an experimental study of defects in some homogeneous stationary structures as well as in the traveling-wave states of convection of a nematic liquid crystal. We show that the core of the defects is a germ of the unstable state and it can become unstable under the external stress. Then, either fully homogeneous states with the symmetry of the core, or complex disordered states can develop from the local instability of defects in processes quite similar to displacive transitions in solids. Some of the main features are qualitatively similar to numerical simulations of an appropriate Landau-Ginzburg equation. 相似文献