全文获取类型
收费全文 | 7501篇 |
免费 | 1013篇 |
国内免费 | 651篇 |
专业分类
化学 | 3086篇 |
晶体学 | 1157篇 |
力学 | 576篇 |
综合类 | 135篇 |
数学 | 1874篇 |
物理学 | 2337篇 |
出版年
2024年 | 7篇 |
2023年 | 75篇 |
2022年 | 139篇 |
2021年 | 213篇 |
2020年 | 222篇 |
2019年 | 186篇 |
2018年 | 145篇 |
2017年 | 224篇 |
2016年 | 329篇 |
2015年 | 255篇 |
2014年 | 414篇 |
2013年 | 548篇 |
2012年 | 407篇 |
2011年 | 549篇 |
2010年 | 494篇 |
2009年 | 501篇 |
2008年 | 520篇 |
2007年 | 542篇 |
2006年 | 504篇 |
2005年 | 407篇 |
2004年 | 393篇 |
2003年 | 324篇 |
2002年 | 245篇 |
2001年 | 199篇 |
2000年 | 220篇 |
1999年 | 176篇 |
1998年 | 167篇 |
1997年 | 144篇 |
1996年 | 99篇 |
1995年 | 77篇 |
1994年 | 78篇 |
1993年 | 55篇 |
1992年 | 54篇 |
1991年 | 52篇 |
1990年 | 38篇 |
1989年 | 33篇 |
1988年 | 28篇 |
1987年 | 16篇 |
1986年 | 14篇 |
1985年 | 20篇 |
1984年 | 13篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1973年 | 2篇 |
1959年 | 3篇 |
排序方式: 共有9165条查询结果,搜索用时 31 毫秒
91.
表面能与晶体生长/溶解动力学研究的新动向 总被引:3,自引:0,他引:3
界面现象使物质在结晶过程中出现了临界现象.但最近的研究指出在物质溶解过程中,在表面能量的控制下也存在着临界现象以及尺寸效应.实验发现,当晶体自身小到一 定的程度时(通常在纳米尺度上并和临界蚀坑的大小相近),在溶解过程中其速度会自发降 低,反应被抑制乃至停止.尽管在热力学上表面能的因素可以赋予小颗粒晶体较大的溶解度 ,但表面能却也能通过对临界条件的控制而使这些微粒在动力学上不被溶解.这个发现不仅 解决了纳米颗粒在水溶液中稳定性的问题,而且还从动力学的角度解释了生物矿物选择纳米 尺度作为其基本构成单元的原因.由于表面能和晶体生长/溶解的动力学有着密切的关系, 我们可以通过对表面能的调节来修改它们的动力学速度和晶体的形貌.反过来,也可以用动力学的方法来测定表面能及表面吸附/脱附常数等.相对于常规的界面研究手段,通过生 长和溶解动力学途径所得的数据有着很好的可靠性及重复性.我们认为,晶体生长和溶解的 动力学和表面能的研究相结合,不仅为界面研究提供了新的思路和方法,而且也会推动晶体生长和材料科学的发展. 相似文献
92.
用自动凯氏定氮仪测定水中氨氮 总被引:1,自引:0,他引:1
用MgO控制预蒸馏水中的pH值,以硼酸溶液为吸收液,用稀硫酸进行中和滴定,用自动凯氏定氮仪测试水中的氨氮,检测下限为1mg/L,相对标准偏差在0.32%~1.04%范围内,加标回收率为96%~104%,并将该法与纳氏试剂比色法和离子色谱法进行了比较。 相似文献
93.
大肠杆菌有限生长的微量热及非线性动力学研究 总被引:2,自引:0,他引:2
The finite growth of Escherichia coli was studied by using a LKB 2277 BioActivity Mollitor. We found that the finite growth is a nonliear dynamic process. The nonlinear dynamic behaviour in the finite growth process and the nonlinear dynamic models describing the process were discovered and established. The curve of logistic map corresponding to the finite growth thermogram of Escherichia coli was obtained and the nonlinear dynamic parameters were calculated by means of a computer. Moreover, we also discussed the nonlinear dynamic characters of Escherichia colt in its finite growth process. 相似文献
94.
Svilen Bobev Paul H. Tobash Joe D. Thompson John L. Sarrao 《Journal of solid state chemistry》2005,178(6):2091-2103
A number of rare-earth alumo-silicides (R-Al-Si) have been synthesized from the corresponding elements by high-temperature reactions, carried out in excess of aluminum to serve as a flux. Under these experimental conditions, large single crystals of all R-Al-Si ternary phases were readily produced. The crystal structures these ternaries adopt were studied by means of powder and single-crystal X-ray diffraction and were classified as follows: (1) the early rare-earths (R=La, Ce, Pr, Nd, Sm, Gd) yield RAlxSi2−x, x∼1, non-stoichiometric ternary derivatives of the body-centered α-ThSi2-type; (2) the late rare-earths (R=Tb, Dy, Ho, Er, Tm) form stoichiometric R2Al3Si2 compounds that crystallize in the C-centered monoclinic Y2Al3Si2-type; (3) the divalent Eu and Yb produce EuAl2Si2 and YbAl2Si2 with the trigonal CaAl2Si2-type, whereas the last lanthanide element, Lu, forms LuAlSi with C-centered orthorhombic YAlGe-type. These structural trends are reviewed, and the evolution of the basic physical properties such as magnetism, heat capacity and electrical resistivity when moving across the series is described in detail. 相似文献
95.
LIN Zhou-Bin HU Zu-Shu ZHANG Li-Zhen WANG Guo-Fu 《结构化学》2002,21(6):637-639
<正>The crystal of Nd0.06Y0.94Sr6Sc(BO3)6 with the dimensions up to 35 mm × 28 mm × 13 mm was grown by a top-seeded solution growth method from Li6B4O9 flux. The grown crystal was characterized by X-ray powder diffraction. The optical absorption of the crystal shows that it has a strong absorption band at 8070 A, and the absorption coefficient is 2.17cm-1 with a FWHM of 41 A, which can match with the wavelength of the diode-laser (LD) and is suitable for the LD pumping. Based on the Judd-Ofelt theory, the three parameters of line oscillator strength Ω(λ) (λ = 2, 4 and 6) of the Nd3+ion in the crystal were calculated as follows: Ω2= 1.194 × 10-20, Ω4= 4.186 × 10-20 and Ω6 = 3.351 × 10-20cm2, which are relatively larger. The results indicate that the crystal Nd0.06Y0.94Sr6Sc(BO3)6 may be a kind of high-efficient laser material for diode-pumped. 相似文献
96.
Preparation of Mn3O4 nanocrystallites by low-temperature solvothermal treatment of γ-MnOOH nanowires
The preparation of trimanganese tetroxide (Mn3O4) nanocrystallites from γ-MnOOH nanowires under mild conditions has been achieved by two steps: first, γ-MnOOH nanowires with a mean diameter of about 12 nm and lengths of up to several micrometers were directly prepared via hydrothermal reaction between KMnO4 and toluene in water at 180°C for 24 h; then, pure Mn3O4 nanocrystallites could be obtained by solvothermal treatment of the γ-MnOOH nanowires in ethylenediamine (EDA) and ethylene glycol (EG) at 150°C for 24 h. It was found that the Mn3O4 product obtained in EDA comprised well-defined nanocrystallites with the size in the range of 15-35 nm, while the one obtained in EG consisted of aggregated nanoparticles with the size of less than 18 nm.The possible formation mechanism of nanocrystalline Mn3O4 in EDA and EG and reasons for the different effects of various solvents on the products were also proposed. 相似文献
97.
M. SAADIOUI Z. ASFARI J. VICENS N. REYNIER J. F. DOZOL 《Journal of inclusion phenomena and macrocyclic chemistry》1997,28(3):223-244
This article describes the synthesis, structure andUV properties of azocalixcrowns in which the photoresponsivetrans-cis azo benzene unit has been introduced in the glycolicchains of the calix[4]crowns. The synthesis proceeded via the selective-1,3O-dialkylation of calix[4]arene with glycolic chains terminated bynitrophenyl residues. After reduction of thenitro groups into amino functions,intramolecular oxidative coupling produced thecapping of the calixarene. Thesynthetic approaches and the cis-transstructure of these new ligandsare discussed and full details on synthesesand structural data are given. Apreliminary example of cesium complexation byone of the ligands is proposed. 相似文献
98.
Tian-Fu LiuHua-Kuan Lin Shou-Rong ZhuZhong-Ming Wang Hong-gen WangHong-Wei Sun Xue-Bing LengYun-Ti Chen 《Journal of Molecular Structure》2002,605(1):117-122
The Mn(II) and Zn(II) complexes of N,N′-diisopropyl-1,10-phenanthroline-2,9-dimethanamine have been synthesised, and the structure of the two complexes have been studied by X-ray crystallography. 相似文献
99.
T.?L.?Shanker Rao K.?N.?Lad A.?PratapEmail author 《Journal of Thermal Analysis and Calorimetry》2004,78(3):769-774
The crystallization kinetics of amorphous Cu50Ti50 has been studied using differential scanning calorimetry (DSC) under non-isothermal conditions. The curves at different linear heating rates (2, 4, 8 and 16 K min–1) show sharp crystallization peaks. The crystallization peak shifts to higher temperatures with increasing heating rate. The Kissingers method of analysis of the shift in the transformation peak is applied to evaluate the activation energy (E
c). The KJMA formalism, which is basically developed for isothermal experiments, is also used to obtain E
c and the Avrami parameter (n).The DSC data have been analysed in terms of kinetic parameters, viz. activation energy (E
c), Avrami exponent (n) and frequency factor K
0 using three different theoretical models. It is observed that the activation energy values derived from KJMA approach and modified Kissinger equation agree fairly well with each other. The activation energy values obtained from normal Kissinger method, and Gao and Wang expression underestimate the activation energy.The financial support provided by All India Council for Technical Education (AICTE), New Delhi (Govt. of India) is gratefully acknowledged. 相似文献
100.
Ge JP Wang J Zhang HX Wang X Peng Q Li YD 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(6):1889-1894
Three-dimensional, orthogonal lead sulfide (PbS) nanowire arrays and networks have been prepared by using a simple, atmospheric pressure chemical vapor deposition (APCVD) method. These uniform nanowires (average diameter 30 nm) grow epitaxially from the surface of the initial PbS crystal seeds and form orthogonal arrays and networks in space. The growth mechanism has been explored, and the process was classified as homogeneous, epitaxial growth in the 200 directions. Furthermore, Raman spectra of PbS nanowires are reported here, and their characteristic Raman peak (190 cm(-1), no shoulder) could be used as a unique probe for the study of PbS nanomaterials. 相似文献