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991.
Jing Sun Jian‐Gong Cheng Wen‐Qing Zhu Shi‐Jie Ren Hong‐Liang Zhong Dan‐Li Zeng Jun‐Ping Du Er‐Jian Xu Ying‐Chun Liu Qiang Fang 《Journal of polymer science. Part A, Polymer chemistry》2008,46(16):5616-5625
A new X‐shaped π‐conjugated monomer comprising of fluorene units and anthracene units was synthesized, and it was used to fabricate the new X‐shaped π‐conjugated polymers and investigate the properties of the new polymers. Using different molar ratios between such monomer and a fluorene monomer gave three polymers that showed higher absolute PL quantum yields than the linear polyfluorene (PF) in the solid state. After thermal annealing at 200 °C for 4 h, the linear PF showed an additional bathochromic emission at about 550 nm, whereas such red‐shifted emission was fully eliminated for the X‐shaped polymers. The electroluminescent devices based on the X‐shaped polymers with a configuration of ITO/PEDOT:PSS/polymer/LiF/Ca/Al displayed blue emission with low turn‐on voltage and high brightness. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5616–5625, 2008 相似文献
992.
K. R. Grigoryan M. G. Aznauryan N. A. Bagramyan L. G. Gevorkyan Sh. A. Markaryan 《Journal of Applied Spectroscopy》2008,75(4):593-596
We have used electronic absorption and fluorescence spectroscopy to study binding between a platinum(II) dimethylsulfoxide
complex (cis-[Pt(DMSO)2Cl2]) and human serum albumin (HSA), and the effect of complexation on the structure of the protein. We have calculated the binding
parameters for binding between cis-[Pt(DMSO)2Cl2] and HSA. We have determined the binding constant KB = (1.2 ± 0.1)·103 M−1 and the Hill coefficient h = 1.03 ± 0.1. We have determined that binding between cis-[Pt(DMSO)2Cl2] and the protein leads to a change in the internal packing of the macromolecule.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 4, pp. 573–576, July–August, 2008. 相似文献
993.
994.
Yaqin Fu Minghao Sun Yonggang Wu Zhishan Bo Dongge Ma 《Journal of polymer science. Part A, Polymer chemistry》2008,46(4):1349-1356
Conjugated polymers containing electron‐transporting, hole‐transporting, and blue light‐emitting units were synthesized by Suzuki polycondensation. These copolymers exhibited excellent thermal and optical stability. Optical investigation indicated that the incorporation of the spirobifluorene units in the polymer main chain could markedly increase the effective conjugation length of polymers. Electrochemical studies showed that the incorporation of spirobifluorene unit could raise the electrochemical stability and improve the electron‐ and hole‐injecting abilities. The electroluminescent results also showed that the introducing of spirobifluorene units could significantly improve the device performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1349–1356, 2008 相似文献
995.
Denis A. Svechkarev Ilya V. Bukatich Andrey O. Doroshenko 《Journal of photochemistry and photobiology. A, Chemistry》2008,200(2-3):426-431
Two novel 1,3,5-triphenyl-2-pyrazoline moiety containing derivatives of 3-hydroxychromone were synthesized and studied by 1H NMR, absorption and fluorescence spectroscopy. The prospects of practical application of these compounds exhibiting high solvatofluorochromism into analytical chemistry and biophysics as effective ratiometric polarity probes were discussed proceeding from the data on their fluorescent properties. 相似文献
996.
997.
Lifetime-based spectral decomposition using a frequency-domain phase/modulation technique has been developed on our UV confocal microspectrofluorimeter prototype. Examples of such an application are first given in the case of complex mixtures of three overlapping fluorescent components in solution. Preliminary results concerning cellular potential application are also reported in the case of Snarf-1 pH sensor. Limits and perspectives of such an approach at the subcellular level are discussed in view of future improvement. 相似文献
998.
Soo Kyung Bae Min‐Jung Kim Eon‐Jeong Shim Doo‐Yeoun Cho Ji‐Hong Shon Kwang‐Hyeon Liu Eun‐Young Kim Jae‐Gook Shin 《Biomedical chromatography : BMC》2009,23(6):568-572
A simple and rapid HPLC method using fluorescence detection was developed for determination of irbesartan in human plasma. Sample preparation was accomplished through a simple deproteinization procedure with 0.4 mL of acetonitrile containing 800 ng/mL of losartan (internal standard), and to a 0.1 mL plasma sample. Chromatographic separation was performed on a Zorbax Xclipse XDB C18 column (150 × 4.6 mm, i.d., 5 µm) at 40°C. An isocratic mobile phase, acetonitrile:0.1% formic acid (37:63, v/v), was run at a flow‐rate of 1.0 mL/min, and the column eluent was monitored using a fluorescence detector set at excitation and emission wavelengths of 250 and 370 nm, respectively. The retention times of irbesartan and losartan were 4.4 and 5.9 min, respectively. This assay was linear over a concentration range of 10–5000 ng/mL with a lower limit of quantification of 10 ng/mL. The coefficient of variation for this assay precision was less than 8.48%, and the accuracy exceeded 94.4%. The mean relative recoveries of irbesartan and losartan were 98.4 and 99.1%, respectively. This method was successfully applied for pharmacokinetic study after oral administration of irbesartan (300 mg) to 23 Korean healthy male volunteers. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
999.
1000.