Variational Derivative for Buckling Loads of Beams and Frames

The finite-difference method is a numerical technique for obtaining approximate solutions to differential equations. The main objective of the present study is to give a new aspect to the finite-difference method by using a variational derivative. By applying this formulation, accurate values of the buckling loads of beams and frames with various end supports are obtained. The performance of this formulation is verified by comparison with numerical examples in the literature __________ Published in Prikladnaya Mekhanika, Vol. 41, No. 7, pp. 139–144, July 2005.     

具有可调紫外滤光性能的富勒烯胺/壳聚糖共混膜的研究

通过溶液共混及流涎成膜法制备了一系列不同C60乙醇胺含量的壳聚糖共混膜。以及含Cu（Ⅱ）的C60乙醇胺/壳聚糖共混膜。研究表明，C60乙醇胺/壳聚糖共混膜具有优异的可调紫外滤光性能，随着C60乙醇胺含量的增加，其紫外滤光波长从200nm红移至400nm左右。在该复合体系中引入Cu（Ⅱ）能有效改善膜的紫外光学性能，同时还初步探讨了这类复合材料的紫外滤光机制。     

Letter: Differential Invariants of the Kerr Vacuum

The norms associated with the gradients of the two non-differential invariants of the Kerr vacuum are examined. Whereas both locally single out the horizons, their global behavior is more interesting. Both reflect the background angular momentum as the volume of space allowing a timelike gradient decreases with increasing angular momentum becoming zero in the degenerate and naked cases. These results extend directly to the Kerr-Newman geometry.     

Polymerization of 1,3‐dienes with functional groups. III. Free‐radical polymerization of N,N‐diethyl‐2‐methylene‐3‐butenamide

Free‐radical homo‐ and copolymerization behavior of N,N‐diethyl‐2‐methylene‐3‐butenamide (DEA) was investigated. When the monomer was heated in bulk at 60 °C for 25 h without initiator, rubbery, solid gel was formed by the thermal polymerization. No such reaction was observed when the polymerization was carried out in 2 mol/L of benzene solution with with 1 mol % of azobisisobutyronitrile (AIBN) as an initiator. The polymerization rate (R_p) equation was R_p ∝ [DEA]^1.1[AIBN]^0.51, and the overall activation energy of polymerization was calculated 84.1 kJ/mol. The microstructure of the resulting polymer was exclusively a 1,4‐structure where both 1,4‐E and 1,4‐Z structures were included. From the product analysis of the telomerization with tert‐butylmercaptan as a telogen, the modes of monomer addition were estimated to be both 1,4‐ and 4,1‐addition. The copolymerizations of this monomer with styrene and/or chloroprene as comonomers were also carried out in benzene solution at 60 °C. In the copolymerization with styrene, the monomer reactivity ratios obtained were r₁ = 5.83 and r₂ = 0.05, and the Q and e values were Q = 8.4 and e = 0.33, respectively. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 999–1007, 2004     

Second-order Nonlinear Optical Properties of a Series of Azulene Derivatives

The first hyperpolarizabilities of a series of novel azulenic-barbituric acid chromophores have been studied by using 12 excitation wavelengths, ranging from 900 to 1907 nm. The dispersion relation of the first hyperpolarizabilities of chromophores holds the same tendency as the experimental results. In addition, the static first hyperpolarizability β0 of molecules was calculated by means of the Sum-Over-States (SOS) expression and the two-level formula respectively. The results show that these molecules possess large static first hyperpolarizabilities and the, β0 value increases as the donor or acceptor strength enhances; the distorted degree of molecules has also an important influence on the β0 value.     

STRONG DERIVATIVE AND ITS CONSEQUENCES

We introduce strong derivative, the corresponding Z-integrable and other related concepts. Also, we give an improved version of the fundamental theorem of calculus.     

Sobolev-Type Classes of Functions with Values in a Metric Space. II

We prove equivalence of the definitions by the author and by Korevaar and Schoen of the Sobolev classes of mappings of a domain of an arithmetic n-dimensional space to a metric space.     

Theory and experiment of spatially and temporally partially coherent speckle shearing interferometry

The theory and experiment of spatially and temporally partially coherent speckle shearing interferometry is reported in this rapid communication for the first time. The general requirements for the surface roughness and coherence area of a diffuse object surface in spatially and temporally partially coherent speckle shearing interferometry are discussed. An experimental verification is presented and the results of theory and experiment are in good agreement.     

水力机械内鲤鱼草鱼的压力损伤模拟试验

通过试验人工模拟水力机械内压力变化过程,测量压力时间变化,观察并解剖分析不同压力变化过程对鲤鱼和草鱼造成损伤的情况。试验发现,负压状态下的压力变化过程会对鱼的生存构成直接威胁,并得到了新型环保水力机械设计中应采用的压力时变导数极限值。     

Crystal Structure of Adduct 2-Phenyl-imidazo [ 4,5-f ] 1,10-phenanthroline Methanol

The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials.