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131.
132.
Paolo Melchiorre Dr. 《Angewandte Chemie (International ed. in English)》2009,48(8):1360-1363
Following the light: Photoredox catalysis along with aminocatalysis have proved to be the right combination for one of the most challenging asymmetric transformation in organic synthesis: the direct intermolecular α‐alkylation of aldehydes.
133.
Vasiliy M. Muzalevskiy Alexander Yu. Rulev Igor A. Ushakov Aleksey V. Shastin 《Tetrahedron》2009,65(34):6991-7000
Unprecedented selective reactions of β-halo-β-trifluoromethylstyrenes with secondary amines under different conditions were discovered. Depending on the electronic properties of the starting styrenes and the reaction parameters, two pathways were found. With neat secondary amines a series of α-trifluoromethyl-β-aryl enamines were prepared in high yields. In contrast, the reactions of the mentioned styrenes with the same amines in polar solvents by substitution of all halogen atoms gave vinylogous guanidinium salts. Possible reaction mechanisms are discussed. 相似文献
134.
1,3,3,3-Tetrafluoro-2-methoxycarbonylpropenesulfenyl chloride readily reacts with enamines (derivatives of -oxo acids) to give sulfenylation products. The reactions with N-aryl-substituted enamines are accompanied by cyclization to form N-aryl-2-(2,2,2-trifluoro-1-methoxycarbonylethylidene)-2,3-dihydrothiazoles. 相似文献
135.
136.
《中国化学》2018,36(8):712-715
Herein, two efficient palladium‐catalyzed intermolecular oxidative coupling reactions of (Z)‐enamines with isocyanides via selective β‐C(sp2)‐H and/or C=C bond cleavage have been developed, leading to controllable chemodivergent and stereoselective construction of a wide range of (E)‐β‐carbamoylenamine derivatives containing strong intramolecular hydrogen bonds. Furthermore, possible reaction pathways for these transformations are proposed on the basis of preliminary mechanism studies. 相似文献
137.
138.
Alexandr N KostyukYurii V Svyaschenko Dmitriy M VolochnyukNikolai V Lysenko Andrei A TolmachevAlexandr M Pinchuk 《Tetrahedron letters》2003,44(34):6487-6491
The reaction of ‘push-pull’ enamines—derivatives of β-aminocrotonic acid with diphenylchlorophosphine has been investigated. Structural sensitivity of the reaction was found and is discussed. 相似文献
139.
140.
N. N. Polygalova A. G. Mikhailovskii E. V. Vikhareva M. I. Vakhrin 《Chemistry of Heterocyclic Compounds》2007,43(7):900-905
It has been shown that the Chichibabin reaction of enamines of the 1,2,3,4-tetrahydroisoquinoline series and 1,2,3,4-tetrahydrobenzo[f]isoquinoline
series with p-bromophenacyl bromide leads to pyrrolo[2,1-a]isoquinoline derivatives. The same heterocyclic system is obtained
on interaction of 1-alkyl-3,4-dihydroisoquinolines or their benzo[f]-analogs with oxalyl chloride. The obtained dioxopyrrolines
form derivatives of benzo[g]quinoxalino[2,3-b]indolizine on condensation with o-phenylenediamine.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1068–1074, July, 2007. 相似文献